METHOD 1
In Revit simply save the rendered image as a .png file.
METHOD 2
Turn the background into alpha channel.
In PHOTOSHOP:
Export Revit render as TIF
Open in Photoshop
Isolate the Alpha channel
Use Magic Wand to pick everything that is 'white'
Turn the color channels back on
Invert the Selection
Convert the background to a true layer
Edit - Cut
New Layer
Edit - Paste
Done!
In GIMP:
Export Revit render as TIF
Open in Gimp
Set Gimp background colour to match images background colour (usually white)
Menu Colors > Color to Alpha...
Done!