4 Tehnologie cu spumă polimerică

Xiao Hu: School of Materials Science & Engineering, Nanyang Technological University, Singapore
Erwin Merijn Wouterson: School of Mechanical and Aeronautical Engineering, Singapore Polytechnic, Singapore
Ming Liu: Temasek Laboratories@NTU, Nanyang Technological University, Singapore

4.1 Introduction 

4.2 Classification of Polymer Foams

4.3 Blowing Agents
Chemical Blowing Agents
Physical Blowing Agents
General Consideration on BA Selection 

4.4 Foaming Processing
Injection Molding Process
Reaction Injection Molding (RIM)
Expandable Polymer Pellets
Extrusion Foaming Process 

4.5 Nanocomposite Foams
Processing of Nanocomposite Foams
Foam Properties 

4.6 Microcellular Foams 

4.7 Processing of Microcellular Foams
Foam Properties 

4.8 High-Performance Polymeric Foams
Polyimide Foams
Phthalonitrile Foams

4.9 Syntactic Foam
Processing of Syntactic Foam
Mechanical Behavior of Syntactic Foam Versus Filler Volume Fraction 

4.10 Summary and Future Research Directions, References

Abstract

This chapter covers two major classes of polymer foams, the conventional foams formed by foaming agents and syntactic foams. The first part presents the basics of polymer foaming through the use of blowing agents including a brief introduction on blowing agents and the common foaming methods used by both laboratories and industries. Current technologies used for specialty foam fabrication are included in the discussion. The multiple roles played by nanoparticles during foam formation and the effects on the foam properties are addressed in detail for nanocomposite foams. The various factors affecting the formation ofmicrocellular foams and the properties of microcellular foams are then discussed. Two detailed examples for high-performance polymer foams are highlighted in the article. An exceptional section is devoted to syntactic foams, covering both the processing and the mechanical behaviors. It starts with general preparation of syntactic foam in a laboratory-based environment. The discussion highlights the typical mechanical behavior as well as the change in mechanical behavior observed when the content of microspheres is changed. Details on how the content of microspheres affects the mechanical and fracture properties of syntactic foams are presented. Besides looking at various content of microspheres, the existence of various toughening mechanisms in syntactic foams and the kind of toughening strategies can be used to improve the toughness of syntactic foams are also included in the section. Finally, some of the issues concerning polymeric foams and the latest developments in the field including future trends are addressed.