The working properties, common uses and environmental impact of the following:
– thermoplastics ○ acrylic (PMMA) ○ nylon ○ polyvinyl chloride (PVC) ○ polystyrene (PS) ○ polypropylene (PP) ○ high and low density polyethylene (HDPE) (LDPE) ○ high impact polystyrene (HIPS) ○ polycarbonate (PC) ○ acrylonitrile butadiene styrene (ABS) ○ polyethylene terephthalate (PET)
– thermosetting plastics ○ polyester resin ○ melamine formaldehyde (MF) ○ urea formaldehyde (UF) ○ epoxy resin – elastomers ○ neoprene ○ silicone ○ thermoplastic elastomer (TPE).
Polymers that can be reheated / formed
PET, PS, PP, PMMA
Polymers that cannot be reheated / recycled
Formaldehyde, Resin
Soft, flexible polymers with elastic properties
Rubber, Elastic, TPE
Polymers are made up of long chain molecules containing carbon, hydrogen and oxygen atoms, along with other chemicals such as chlorine and fluorine.
Polymers occur naturally in nature and can be derived from plant and animal sources.
They include:
Casein (derived from milk) which is still used to make buttons,
Horn,
Resin (from trees)
Cellulose from plants - In the case of Cellulose it is mixed with acetic acid to make Cellulose acetate which is still used today for OHP slides.
These could be classed as natural polymers as they possess a similar molecular structure to those polymers commercially used today.
Synthetic polymers are gained through a process of thermal cracking. As they are derived from fossil fuels (particularly oil) they are carbon based and account for the majority of plastics used today.
In order for it to be useful to us, crude oil is broken down in oil refineries into its component parts, known as fractions, and these can then be used for many different purposes.
A plastic that can be repeatedly reheated and remoulded.
A chemical reaction takes place at the point where they are formed which prevents them from being reheated or reshaped.
These are polymers with good elasticity i.e. they can be distorted under pressure but will return to their original shape.
Polymers have some unique properties which make them particularly useful for modern day applications.
They are good electrical and thermal insulators
They have a good strength to weight ratio. This does not mean they are strong in the same way as steel but that they have good strength compared to their weight.
They generally have good atmospheric and chemical resistance.
They have fairly low melting temperatures (Thermoplastics only)
They are lightweight
They can be self coloured, opaque or transparent and are self finishing.
They are quite hygienic and are water resistant.
They can be enhanced with the addition of fillers, plasticisers and stabilisers to make them more flame retardant or anti-static etc.
The chart on the right shows the commonly recycled polymers (plastic materials). The order generally signifies how commonly used the material is. For instance PET is used for drinks bottles so many units are sold and disposed of each day in Thailand.
In the UK only the top three are easily recycled.
Water bottles
Comes in two forms: High Density (HDPE) for buckets and Low Density (LDPE) for carrier bags.
Windows and hosepipes.
Plastic chairs.
This can come in three forms: Rigid (food packaging), High Impact (HIPS) (fridge door) and expanded (foam) for packaging.
Better known as Nylon and used for washers bearings, hair combs.
Better known as Acrylic and used for car headlights.
used for safety glasses
the only thermoplastic that does not begin with ‘poly’. It is a relatively modern plastic used for electrical casings on computers and phones etc.
Thermosetting plastics are polymers that cannot be reheated and reshaped. When the plastic is formed cross linking takes place across the long chain molecules which cannot be broken down by heat. While this means these types of plastic are good for situations where they will be subjected to heat and electricity, these types of plastics cannot be recycled.
Brittle but strong with fibres such as glass or carbon. Used to make boat hulls and car body parts.
High strength when combined with fibres. Also used as a two part adhesive glue (Araldite).
Used for white electrical fittings.
Used for worktops surfaces.
Elastomers have links between the monomers which are flexible even when the Thermoplastic has cooled down. This allows the plastic to have rubber-like properties.
Elastomers can generally be recycled.
Thermoplastic Elastomers (TPE’s) can be processed using conventional moulding equipment i.e. injection moulding and have the advantage of quicker production times compared to natural or synthetic rubbers.
Another advantage is that all waste and scrap material can be recycled.
TPE’s are commonly used for wire and cable coatings, for seals and hoses in the automotive industry as well as over mouldings of grips onto power tools casings, toothbrushes, pens and utensils etc...
wire and cable coatings
over moulded grips on power tools casings
over moulded grips on toothbrush
over moulded grips on pens
Liquid Silicon Rubber (LSR) is a thermosetting elastomer made up of two components, of which one is a catalyst.
These can be made using injection moulding techniques and the main advantage of this material is its ability to withstand temperatures ranging from -50C to +250C.
This makes it ideal for use in the automotive industry, for teats on baby bottles and for cooking and medical applications