The showing of a Bond movie on UK television used to a 'Big Event' when exclusively shown by ITV ( terrestrial tv ).
Of course when available earlier on other media ( video, dvd, blu-ray & satellite ), each movie did not attract the same mega audience but 007 remains popular in the ratings.
Listed below past showings on their digital freeview channels ...
Last shown on ITV:
Last shown on ITV2:
Last shown on ITV4: