pH Value

pH Value

pH (potential of Hydrogen) is defined as the decimal logarithm of the reciprocal of the hydrogen ion concentration in a solution.

pH Value = −lg⁡(H+)

H+ refers to the Hydrogen Ion Centration.

High pH ⇔ Low concentration of H+

A pH value less than 7 is considered acidic (High concentration of Hydrogen ions), pH value of 7 is considered neutral and a pH value greater than 7 is considered alkaline (Low concentration of Hydrogen ions)

Explore!

Use the applet below to explore the relationship between Hydrogen Ion Concentration and pH Value.

Why use a Logarithmic Scale?

From the graph above, you should notice that the concentration of H+ are ridiculously small numbers (Eg. 0.000 001 mol/dm3 vs 0.000 000 01 mol/dm3) which make them hard to tell apart just like that GREEN point seems to stick to the y-axis. A logarithmic scale allows the reader to focus on the exponent and use the exponent to gauge the concentration level.

Why pH 7 is neutral?

Water is able to self-ionize. A H2O molecule can lose a proton to become a hydoxide ion (OH) while that rouge proton (H+) will protonate another H2O molecule to form hydronium (H3O+).

2H2O ⇆ OH+ H3O+

This reaction constantly occurs and reverses almost instantly. At any point of time, only a small fraction of these water molecules are ionized and this fraction is a special constant known as the water disassociation constant, Kw 1.006 × 10−14. For water,

Kw = [Concentration of OH] [Concentration of H3O+]

At 25 °C, the concentrations of the hydronium ion and the hydroxide ion are equal.

Concentration of OH= Concentration of H3O+ 1.0×10−7

Therefore the neutral pH Value ≈ −lg⁡(1.0×10−7) = 7.