pH (potential of Hydrogen) is defined as the decimal logarithm of the reciprocal of the hydrogen ion concentration in a solution.
H+ refers to the Hydrogen Ion Centration.
High pH ⇔ Low concentration of H+
A pH value less than 7 is considered acidic (High concentration of Hydrogen ions), pH value of 7 is considered neutral and a pH value greater than 7 is considered alkaline (Low concentration of Hydrogen ions)
Use the applet below to explore the relationship between Hydrogen Ion Concentration and pH Value.
Why use a Logarithmic Scale?
From the graph above, you should notice that the concentration of H+ are ridiculously small numbers (Eg. 0.000 001 mol/dm3 vs 0.000 000 01 mol/dm3) which make them hard to tell apart just like that GREEN point seems to stick to the y-axis. A logarithmic scale allows the reader to focus on the exponent and use the exponent to gauge the concentration level.
Water is able to self-ionize. A H2O molecule can lose a proton to become a hydoxide ion (OH−) while that rouge proton (H+) will protonate another H2O molecule to form hydronium (H3O+).
This reaction constantly occurs and reverses almost instantly. At any point of time, only a small fraction of these water molecules are ionized and this fraction is a special constant known as the water disassociation constant, Kw ≈ 1.006 × 10−14. For water,
Kw = [Concentration of OH−] ✕ [Concentration of H3O+]
At 25 °C, the concentrations of the hydronium ion and the hydroxide ion are equal.
∴ Concentration of OH− = Concentration of H3O+ ≈ 1.0×10−7
Therefore the neutral pH Value ≈ −lg(1.0×10−7) = 7.