Maximize Crystal Formation (Paul Neumann)

Title: Maximize Crystal Formation

Principle(s) Investigated: How time and temperature will affect formation of crystals

Standards :

MS-PS 1-4. Develop a model that predicts and describes changes in particle motion, temperature, and a state of a pure substance when thermal energy is added or removed.

Materials:

For Chocolate samples:

One set of bits of untempered chocolate and another set of bits that are tempered

For Bismuth crystals: 2 lbs. Bismuth – available on Ebay. As close to 99.9 percent pure.

safety glasses

2 pans to heat the material

A propane tank and torch, a lighter

A cooling pad and another to keep pan warmer longer.

For Alum crystals:

As many egg shell halves for students with some extras for breakage. Explain process on how to blow out eggs.

2-5 lbs Alum (must be aluminum potassium sulfate or won’t make crystals!) Available on-line from Talas.com

School glue, small brushes, water and paper towels to clean up

A way to heat water in measuring cups, a vessel to put shells and saturated alum solution for a day.

Procedure:

For creating alum crystal out of egg shells (will look like an opened geode)

Blow out egg shells

Let them air dry

carefully cut them with a dull knife against your fingers, write student names on bottom

Have students paint them with Elmer's glue

Dust with alum and shake off excess. Let dry

Prepare enough boiling water to cover eggs.

Little by little add capfuls of alum till saturated. (till granules won't dissolve)

Add coloring (even glow highlighter liquid to make them fluoresce)

To make a contrast between the crystals that will cool faster and those slower, put one container into a bath of ice water.

Remove one day later and compare results.

For making bismuth crystals:

For the bismuth, heat the slugs in a pan just to the melting point and keep warm so the crystals may form slowly. Just when the liquid starts to harden, gently shake the liquid molten bismuth and when crystals are evident pour out the remainder (they will still be forming) and let the crystals cool before removing them out of pan. For a second batch, bring to melting point but place pan on something cool to let material quickly harden. Then pour out molten just when edges appear hardened. Compare then the difference between the quality and size of the crystals. Bismuth is brittle, so you can isolate the pieces of crystal you like and re-melt the rest.Materials to heat large pieces of bismuth into mold on bottom of empty soda cans (will burst if full!)

Student prior knowledge: Students should be aware that crystals are on our kitchen tables in the form of salt and sugar, in their parents' wedding rings. They are not just for beauty but also have application in industry. Watches and cell phones for example. This experiment incorporates using a paint brush to spread glue and glitter with alum powder as a seed starter for larger crystals to grow. Students may need help if they are awkward using a paint brush.

Explanation: Crystals are compact orderly arrangements of molecular compounds or elements. They result from a variety of means, from heat and compaction to form tight bonds and geometric arrangements or as a result of "sedimentation" as minerals precipitate from richly saturated liquids. Certain conditions will produce larger or smaller crystals or no crystals at all. Crystals will form in a tremendous number of geometric repeating patterns. Water crystals or snowflakes will form in small or large six sided flakes depending on certain conditions. In the case of Gibeon meteorites, that fell in Namibia, the crystals formed over billions of years (older than the earth) creating the fascinating Widmanstattin patterns. These crystals cannot be duplicated in a laboratory. They are very dense, with molecules so close that the iron won’t rust. Compare these to Pallasite meteorites, also made of iron and nickel but have no such pattern but still have an interesting attribute; they hardened with trapped mineral filled gases that formed olivine crystals (peridot-August birthstone). These Pallasite meteorites cooled much faster. In a small way this experiment will explore how the difference in cooling times will affect crystal growth.

Here is a sophisticated explanation and formula from Wikipedia:

"Primary nucleation (both homogeneous and heterogeneous) has been modelled with the following:[1]

B=\dfrac{dN}{dt} = k_n(c-c^*)^n
  • B is the number of nuclei formed per unit volume per unit time.
  • N is the number of nuclei per unit volume.
  • kn is a rate constant.
  • c is the instantaneous solute concentration.
  • c* is the solute concentration at saturation.
  • (c–c*) is also known as supersaturation.
  • n is an empirical exponent that can be as large as 10, but generally ranges between 3 and 4."

Secondary nucleation occurs when there is enough of a "seed" the molecules will attach to as they crash into it.

Questions & Answers: Opening question: Turn to your neighbors and ask one another, what do watches, cell phones and fine chocolate have in common? You don't eat cell phones, watches and cell phones are both electronic... They all have crystals.

Watches have quartz crystals that resonate with a perfect cycle to equal 1 second.

Some cellphones utilize ulexite (called TV stone) for its fiber optic properties. (Have sample)

Good quality chocolate has cocoa butter that must be carefully crystalized to give it its snap, shine and shelf life. It takes time, practice and know how to form the proper crystals otherwise the chocolate forms a powdery film and feels mealy in a way that people associate with old chocolate. Most chocolate companies substitute other oils to avoid this problem or make coatings that are only chocolate flavored. (have samples). It takes commitment to produce the real thing. Rocky Mountain Chocolates (found at every tourist locale) even add gluten in their coating to raise the melting temperature of their product.

When we come to making our crystal eggs, do you think that cooling slowly will ALWAYS make bigger crystals? Which method will you chose. We will see what happens...

Applications to Everyday Life:

Crystals are all around us. Salts are crystals for food enhancement, fertilizers to nourish food crops and our gardens and Epsom (magnesium) salts to soak our feet

Good quality chocolate requires good crystallization for snap, shine and shelf life.

Bismuth is used in Pepto-Bismol to help relief upset stomachs.

Steel compounds require proper heating to give their products molecular alignment to maximize strength and durability.

Gemstones are not just for beauty. Quartz crystals or silicon dioxide made for watch escapement are man-made. Knowledge on how to create pure crystal without impurities and correct tinsel strength is imperative for accurate time pieces. Crystals are cut at predictable angles to optimize the piezoelectricity of the pieces and for accurate resonant cycles.

Quartz is the base material for a number of gemstones, citrine, amethyst, chrysophrase, chalcedony, Here is a picture of a quartz coated tuning fork that creates the resonant piezoelectricity to give a timepiece accuracy. Just a little bend creates enough power to activate the proper cycle to create an almost perfect second.

Photographs:

egg shells with alum dust glued on and soaked in

alum saturated water and food coloring

Picture of alum crystals in half chicken eggshell:

Russian egg dye from ebay, you can heighten the intensity of color with food coloring:

Getting ready to paint insides of egg shell with Elmer’s Glue and glitter with seed material with fine alum powder.

Set up to cool egg shells at room temperature (to cool slower) and one in a bath of ice water (to cool faster)

Bismuth used for its diamagnetic properties to levitate neodymium magnets. Bismuth is diamagnetic only along its centrifugal edges, not centripetal. It can under careful conditions become polarized through its diaelectric inertial through careful cooling but that is not necessary for levitating powerful even small neodymium magnets (available through internet and Home Depot:

https://www.youtube.com/watch?v=dtM_QnAxigA

Neodymium magnets “float” through eddy currents generated by magnet in copper pipe:

https://www.youtube.com/watch?v=N7tIi71-AjA

You can extract bismuth from Pepto-Bismol: https://www.youtube.com/watch?v=Hp1fYtYEfoQ