Define relative atomic mass, Ar, as the average mass of naturally occurring atoms of an element on a scale where the 12C atom has a mass of exactly 12 units
Define relative molecular mass, Mr, as the sum of the relative atomic masses (relative formula mass or Mr will be used for ionic compounds)
Define the mole in terms of a specific number of particles called Avogadro’s constant
You may remember that different isotopes exist for most elements. The example shows the 3 Lithium isotopes. These have mass numbers of 6, 7 and 8. So which should we choose for our mass calculations?
Most periodic tables will give you the mass number as a non integer. Here from ptable.com we see Ar for Lithium is 6.94. This is the average mass of the naturally occurring isotopes. You should not use these numbers in your stoichiometry calculations!
Now look at the Ar for Lithium from your IGCSE Periodic Table. You can see they have rounded these to the nearest whole number (with one exception). Please only use your IGCSE periodic table for stoichiometry.
Relative atomic mass: (Ar); the average mass of naturally occurring atoms of an element on a scale where the 12C atom has a mass of exactly 12 units
Relative molecular mass: (Mr); the sum of the relative atomic masses of elements in a covalent molecule
Relative formula mass: (Mr); the sum of the relative atomic masses of elements in an ionic compound
Give the relative atomic mass, Ar, for Vanadium and Fluorine.
Give the relative formula mass, Mr, of Sulfuric Acid, H2SO4.
Ar for Vanadium = 51
Ar for Fluorine = 19
Mr of Sulfuric Acid, H2SO4 = 98
One mole (1 mol) of a substance contains 6.02x1023 (the Avogadro constant) atoms, molecules or formula units
When counting the number of atoms, molecules, or formula units in a substance, we are going to be dealing with very BIG numbers.
Let’s take a look at a special big number: 6.02 x 1023
This number is called Avogadro’s constant. Something very interesting happens if you take 6.02 x 1023 particles of any substance and measure its mass.
The mole is a unit that tells us the amount of substance there is.
Specifically, it is the number of particles (6.02 x 1023, Avogadro’s constant) needed for a substance’s mass to equal its relative atomic mass in grams.
One mole of C = 6.02 x 1023 carbon atom
One mole of H2 = 6.02 x 1023 H2 molecules
One mole of MgO = 6.02 x 1023 MgO “formula units”
Give the molar masses (with unit g/mol) of Calcium Carbonate and Silicon (iv) Oxide. You need to determine the formula first
Calcium Carbonate: 100 g/mol (Calcium Carbonate is CaCO3)
Silicon (iv) Oxide: 60g/mol (Silicon (iv) Oxide is SiO2)
You must memorize this triangle. It is quicker with the symbols if you can.
Mass, m (g)
Molar Mass, M (g/mol)
Number of moles, n (mol)
The mass of 0.68 mol of Carbon Dioxide
The molar mass of a gas where 0.020 mol has a mass of 0.64g, and suggest what gas it could be
How many moles of Hydrogen gas (NOT Hydrogen atoms!) there would be in 0.24kg.
Answers
m = 30g
M = 32 g/mol. Could be oxygen gas (O2)
n = 120 mol