If a material absorbs thermal energy, then unless it is melting or boiling, its temperature rises.
However, some materials have a greater capacity for absorbing thermal energy than others.
For example, if you heat a kilogram each of water and aluminium, the water must be supplied with nearly five times as much energy as the aluminium for the same rise in temperature:
4200 joules of energy are needed to raise the temperature of 1 kg of water by 10C.
900 joules of energy are needed to raise the temperature of 1 kg of aluminium by 10C.
Scientifically speaking, water has a specific heat capacity of 4200 J/(kg °C). Aluminium has a specific heat capacity of only 900 J/(kg 0C). Other specific heat capacities are shown in the table below left.
The energy that must be transferred to an object to increase its temperature can be calculated using this equation:
In symbols:
where m is the mass in kg, c is the specific heat capacity in J/(kg 0C), and ΔT represents the temperature change in °C (or in K).
The same equation can also be used to calculate the energy transferred when a hot object cools down.
In this case, the temperature change is 50 °C.
So: energy transferred = mcΔT = 2 X 4200 X 50 J
= 420 000 J
A table showing the Specific Heat Capacities of different materials
Thermal Capacity
The quantity mass X specific heat capacity is called the thermal capacity (or heat capacity). For example, if there is 2 kg of water in a kettle: thermal capacity of the water = 2 kg X 4200 J/(kg °C) = 8400 J/ °C
This means that, for each 1°C rise in temperature, 8400 joules of energy must be supplied to the water in the kettle. A greater mass of water would have a higher thermal capacity.
Measuring Specific Heat Capacity
Water
A typical experiment is shown on the right. Here, the beaker contains 0.5 kg of water.
When the 100 watt electric heater is switched on for 230 seconds, the temperature of the water rises by 10 °C.
From these figures, a value for the specific heat capacity of water can be calculated:
(Omitting some of the units for simplicity)
energy transferred to water = mcΔT - 0.5 X c X 10
energy supplied by heater = power X time = 100 X 230 = 23 000 J
so: 0.5 X c X 10 = 23 000
Rearranged and simplified, this gives c = 4600
so the specific heat capacity of water is 4600 J/(kg °C).
This method makes no allowance for any thermal energy lost to the beaker or the surroundings, so the value of c is only approximate.
Aluminium
Aluminium (or other metal) The method is as previous, except that a block of aluminium is used instead of water.
The block has holes drilled in it for the ; heater and thermometer. As before, c is calculated from this equation:
power X time = mcΔT (assuming no thermal energy losses)
A video revising specific heat capacity
5.10---Specific-Heat-Capacity.mp4
Storing Thermal Energy
Because of its high specific heat capacity, water is a very useful substance for storing and carrying thermal energy.
For example, in central heating systems, water carries thermal energy from the boiler to the radiators around the house.
In car cooling systems, water carries unwanted thermal energy from the engine to the radiator.
Night storage heaters use concrete blocks to store thermal energy. Although concrete has a lower specific heat capacity than water, it is more dense, so the same mass takes up less space.
Electric heating elements heat up the blocks overnight, using cheap, ‘off-peak’ electricity supplied through a special meter.
The hot blocks release thermal energy through the day as they cool down.
In most central heating systems, water is used to carry the thermal energy.