Places to buy or listen to world music:
Public Radio Market - music highlighted in various programs including World Cafe
Microfondo - Calabash Music - World music, including a free daily download
Smithsonian Global Sound for Libraries - can listen to individual tracks and create playlists
Smithsonian Folkways (search by World, World History is mostly speeches)
Harmonia Mundi World Music Store (also classical)
National Geographic Store Music CDs
Amazon.com's World Music Site, including new released
Metropolitan Museum of Art Store Music CDs
PRI's the World - Downloadable clip on Global Hits
Not exactly world music, but the last 18 years (and various weeks) in Rap! by Flocabulary also some world history songs