Singlet Oxygen Reaction Links

Post date: Feb 15, 2019 6:37:31 AM

https://www.nature.com/articles/s41467-017-01906-5.pdf (Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons)

supplmentary material link: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-017-01906-5/MediaObjects/41467_2017_1906_MOESM1_ESM.pdf

picture of setup on page 37 and 39 https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-017-01906-5/MediaObjects/41467_2017_1906_MOESM2_ESM.pdf

General procedure for C-H bond functionalization of cyclic and linear ether: A dry test tube (20 mL) with rubber septum and magnetic stirrer bar was charged with aliphatic ether (1 mL). The test tube was purged with dry oxygen for 10 minutes and then added 1 x 10-5 M of photosensitizer (typically meso-TPP or rosebengal) and again purged with dry oxygen for 5 minutes. Finally, it was added 10 mol% of Lewis acid (ϒ-Al2O3). The solution was then irradiated using 100 W Hg lamp or a blue-LEDs array for 8 h at room temperature under an 1 atm oxygen atmosphere. The unreacted starting material was evaporated using a rotary evaporator, and the residue products were submitted for NMR analysis.

Starna cell accessories (cuvette with septum, see page 31): http://www.starnacells.com/d_download/Starna.pdf

• https://www.labsphere.com/site/assets/files/2570/the-radiometry-of-light-emitting-diodes-leds.pdf

• https://www.comsol.com/blogs/calculating-the-emission-spectra-from-common-light-sources/

  • Photosensitized singlet oxygen and its applications Coordination Chemistry Reviews 2002

  • e-EROS link to singlet oxygen: http://reag.paperplane.io/00002484.htm e-EROS general link: http://reag.paperplane.io/