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Electrons are arranged or configured in a specific way that follows a pattern.
The total number of electrons must equal the atomic number of the element.
We can use the period (row) of the Periodic Table that an element is in to determine the number of electron shells or energy levels. Period 1 elements have 1 shell or energy level of electrons. Period 2 elements have 2 shells or energy levels of electrons. Period 3 elements have 3 shells or energy levels of electrons. Period 4 elements have 4 shells or energy levels of electrons.
We can use the Group number that an element is in to determine the number of outer shell or valence electrons. Group 1 elements have 1 valence electron, Group 2 elements have 2 valence electrons, Group 13 elements have 3 valence electrons, Group 14 elements have 4 valence electrons, Group 15 elements have 5 valence electrons, Group 16 have 6 valence electrons, Group 17 elements have 7 valence electrons, and Group 18 have a full shell or energy level of electrons (usually 8, but helium, He has 2 electrons in its valence shell).
Shells or energy levels are filled from the inner shell first. This inner shell can hold a maximum or 2 electrons.
Once the inner shell or energy level is filled then the first shell or energy level is filled next. It can hold a maximum of 8 electrons.
The 3rd & 4th shells or energy levels are filled in turn. The 3rd shell or energy level is full when it has 8 electrons.
When we write the electron configuration or arrangement there is a convention to follow.
Li (2, 1) this shows that a lithium atom has 2shells with 2 electrons in the inner shell and 1 valance electron.
Na (2, 8, 1) this shows that a sodium atom has 3 shells with 2 electrons in the inner shell, 8 electrons in the second shell/energy level and 1 valance electron.
Cl (2, 8, 7) this shows that a chlorine atom has 3 shells with 2 electrons in the inner shell, 8 electrons in the second shell/energy level and 7 valance electrons.
Ca (2, 8, 8, 2) this shows that a calcium atom has 4 shells with 2 electrons in the inner shell, 8 electrons in the second and third shells/energy levels and 2 valance electrons.
The representations below show the electron configuration (arrangement) of the first 20 elements.