10.02.2 Reaction Profiles

Syllabus

    • Chemical reactions occur only when reacting particles collide with sufficient energy.

    • The minimum amount of energy that particles must have to react is called the Activation Energy.

    • Reaction profiles can be used to show the relative energies of reactants and products, the Activation Energy and the overall energy change of a reaction.

Students should be able to:

    • draw simple reaction profiles (energy level diagrams) for exothermic and endothermic reactions showing the relative energies of reactants and products, the activation energy and the overall energy change, with a curved line to show the energy as the reaction proceeds

    • use reaction profiles to identify reactions as exothermic or endothermic

    • explain that the activation energy is the energy needed for a reaction to occur.

What does this mean?

Reaction Profiles


In the previous section we saw Reaction Profiles for endo- and exothermic reactions.

In both cases, we have to put energy in before any energy is released.

The minimum amount of energy needed for the reaction to start is the Activation Energy or Ea

This is the energy we have to put in to break bonds in the reactants.

Then some energy is released when new bonds form in the products.

If less energy is released than was put in then the reaction is endothermic.

So this will cool down the surroundings by removing energy.

And it will make us feel colder

If more energy is released than was put in then the reaction is exothermic.

Energy is released to the surroundings making us feel warmer.

In either case, the energy given out or taken in overall is the difference between the starting energy and the final energy.

For some reason, the examiner really wants to see the curved line that represents the progress of the reaction.

Successful and Unsuccessful collisions.

It doesn't matter how much energy reactants have unless they are touching.

So for a reaction to happen, reactants must collide.

If they do not have enough energy then they may collide but no reaction will happen - this is an unsuccessful collision

But even if the collision happens with enough energy (equal to or more than Ea) there is no guarantee of a successful collision because the particles may collide in the wrong orientation (from the wrong side).

We will cover this again in the Rates topic.


Past Paper Questions

2020

2021

06.1

the (minimum) energy needed for particles to react

or

the (minimum) energy needed for a reaction to occur

allow the (minimum) energy needed to start a reaction

2019

2017