Upon completion of this experiment, students will have experienced:
(CLO1). Explain basic chemical concepts related to chemical changes, energy, and properties of matter.
(CLO2). Apply the methods of scientific inquiry
(CLO3). Analyze evidence to decide if generalizations or conclusions based on the obtained data are warranted
(MLO1) Explain the number and location of atom or molecules in the unit cell (lattice point, side, edge or face) for simple cubic, body centered cubic, face centered cubic/cubic close packed and hexagonal close packed unit cells
(MLO1) Calculate the atomic radius of an atom given its density and unit cell packing.
(MLO1) Identify key characteristics and examples of the major types of crystals: ionic, covalent, molecular, or metallic.
Virtual Experimen 23/24 covers properties of liquids and solids.
Complete the pre writing assignment for the laboratory notebook
Complete the pre laboratory problems before coming to the class meeting.
Using the links, videos and resources provided to complete all parts of the laboratory report
Complete the conclusion paragraph for this assignment.
Complete the pre laboratory writing assignment in your laboratory notebook. The prewriting must be completed before the laboratory session begins. The writing should include a purpose/hypothesis of the experiment, a discussion or theory, a detailed step by step summary of the procedure explaining what data will be collected and how you will collect it. Data Tables or space to collect the data should be included within the procedure discussion. Look up any SDS on chemicals you are not familiar with.
Determine the solubility or miscibility of the liquid and solid combinations of water, ethanol, hexane, NaCl and iodine. To complete this assignment, complete the mixtures at home with common chemicals or watch the following videos and describe your observations in the report. Answer the questions required in the assignment.
Determine the affect of polarity on the solubility of ionic and molecular compounds in water or hexane
Solubility of water in ethanol and hexane: https://youtu.be/Z_kM5bIzEH0
Intermolecular forces: Like dissolve like: https://youtu.be/bYUC4NlVHx8
Solubility of Iodine in water, ethanol and hexane: https://youtu.be/z7xnLQ2K3_0
In this part of the experiment you will investigate the relationship between intermolecular forces and capillary action. Use the following simulation to determine the height of various liquids in a capillary tube. https://demonstrations.wolfram.com/CapillaryAction/ The required surface tension and specific gravity needed to measure the height of the liquid in the capillary tube is given in the procedure of the laboratory assignment.
Complete any calculations and questions.
You can complete the optional but colorful demonstration at https://www.123homeschool4me.com/capillary-action-science-experiment_15/ using household chemicals and equipment.
Part A: Use this simulation to collect and graph the vapor pressure of several substances every 10 degrees between 0 and 100 degrees.
Create the graph of the vapor pressure and temperature.
Part B. Watch these three videos and report on the rate of evaporation for ethanol, acetone and water.
Evaporation and Intermolecular Attractions: https://youtu.be/Oq-hb0sMspw
Evaporation project: https://youtu.be/xZHv1Ye0JIk
Evaporation of ethanol, acetone and water: https://youtu.be/wS872X6_Zww
Part C: Boiling Points. Use the following videos to understand when a liquid boils under both temperature and pressure conditions. Watch the Water in a vacuum chamber - Triple point to observe when all three states of water can coexist.
https://youtu.be/zzVtbvVS2lQ
mrsciguy
A classroom demonstration of the effects of lowering the air pressure on the boiling point of water.
Sergey Pilipenko
https://youtu.be/Py0GEByCke4
What is boiling? An introduction to why water boils.
This video represents a proof of concept for the development of STEM learning resources collaboratively developed by students and a STEM expert (in this case Dr. B, a GHS teacher).
Video (0:00-0:15, 1:00-1:10), animation (the one with the green circle - 0:47 - 0:59), as well as research/script writing support, provided by students. Molecular simulations by Dr. B. using AtomSmith software.
The final version will contain student voice overs as well as Dr. B.
Boiling is a concept many students struggle with. Many believe the bubbles contain either air, H2 and O2 gases, or heat. Much of this is due to the difficulty visualizing the behavior of water molecules during boiling.
MrGrodskiChemistry
Cold water about 23 degree Celsius water is placed in a vacuum chamber and boils when the pressure in the chamber approximates the vapor pressure. I placed a thermometer inside the chamber and observed a decrease in temperature as it boils
https://youtu.be/y4BGV7-1lhs
I put water in a vacuum chamber to bring it to its triple point.
We will build models using the Solid State Model Kit. The manual for the kit contains directions for building 100 different solid state structures. We will be building specific structures for this lab. I have build most of these models in the video below and have taken pictures of several of the models.
After watching the video, describe the structure in the pictures below or on the video and answer the appropriate questions for each model.
The following websites contain cell structure that also can be used to answer these questions
3D crystal models: http://www.ibiblio.org/e-notes/Cryst/Cryst.htm
Interactive 3D Chemistry: https://www.chemtube3d.com/
Cubic close packed (ccp) and the hexagonal close packed (hcp) structures.
http://www.ibiblio.org/e-notes/Cryst/FCCcp.html versus http://www.ibiblio.org/e-notes/Cryst/hex.html
Simple cubic structure or Primitive Cubic
https://www.chemtube3d.com/simple-cubic-lattice/
http://www.ibiblio.org/e-notes/Cryst/Cubic4.html
Body centered cubic structure
https://www.chemtube3d.com/_bccfinal/
http://www.ibiblio.org/e-notes/Cryst/BCC2.html
Cubic Close packing/Face centered cubic
https://www.chemtube3d.com/ccp-cubic-close-packing/
http://www.ibiblio.org/e-notes/Cryst/FCC.html
Hexagonal close packing - https://www.chemtube3d.com/hexagonal-close-packing/
CsCl - https://www.chemtube3d.com/_csclfinal/
CaF2 (Fluorite) - https://www.chemtube3d.com/_fluoritefinal/
NaCl - https://www.chemtube3d.com/_rocksaltfinal/
http://www.ibiblio.org/e-notes/Cryst/NaCl2.html
ZnS (zinc blend) - https://www.chemtube3d.com/_blendefinal/
Video of models being built
Coordination number 8
8 coord. hole
Page 93
Coordination number 6
Octahedral hole
Page 93
Coordination number 4
Tetrahedral hole
Coordination number 4
Tetrahedral hole
Primitive or Simple Cubic unit cell
Page 9
SCC Eight unit cells
note the yellow ball is on the corner of all 8 cells
Simple Cubic Unit cell
Body Diagonal
Page 10
note this is the same structure as the 8 coordinate structure.
Body Centered cubic unit cell
Page 18
Cubic Close Packed
note the third layer is not directly over the first layer
Cubic Close Packed
body diagonal
Cubic Close Packed
body diagonal
Face Centered Cubic Unit cell
Page 26
Comparison of the face centered cubic (FCC) with the diagonal of the cubic close packed (CCP) structures. Note that the face is visible on the ccp structure if we rotate and look at a slightly different angle. They are the same structures.
Hexagonal Close Packed
first layer
Second Layer
Hexagonal close packed (hcp)
third layer - note that the atoms in the first and third layer are directly over each other.
Compared to the Cubic close packed (ccp) - note the first and third layers are not directly over each other.
Sodium Chloride unit cell
Page 33
NaCl unit cell extended
Zinc sulfide blend
Page 51
Tetrahedral holes filled
We will determine the atomic radius of a metallic element from a cube of the pure metal after determining the density of the metal.
Use the pictures of the measurements for several metals in the procedure part V of the laboratory assignment to complete the calculations for the atomic radius of both a bcc and ccp unknown. compare the atomic radius to the accepted radius of the element and answer the questions in the assignment.
Once you have determined the density of the unknown. determine it's identity using the density of elements from least to greatest: https://www.angstromsciences.com/density-elements-chart
Density of the elements can also be looked up on https://www.webelements.com/
The elements pack as different unit cells. We will be using metal elements that pack as cubic close pack (ccp) or body centered cubic (bcc) as possible unknowns. See the table for possible unknowns.
Atomic radii of the elements can be found on webelements under atomic properties of the element or on the website: https://environmentalchemistry.com/yogi/periodic/atomicradius.html Generally the atomic radius is given in pm (picometers) but this last link gives the radius in an older unit of angstrom (1 A = 100 pm)
Engineer Thileban Explains - This video tutorial explains how to solve unit cell chemistry problems associated with closed packed structures such as the body centered cubic structure and the face centered cubic structure also known as the cubic closest packing structure. This video explains how to calculate the atomic radius, edge length and density of a cubic crystal lattice structure. You need to know the coordination number or number of atoms per unit cell associated with a given cubic crystal structure. This video contains plenty of examples and practice problems.
Complete the data and result tables, graphs, calculations and answer all required questions.
Complete a conclusion paragraph using the RERUNS method. A discussion of how to write a conclusion paragraph is given in Appendix D: How to Write a Formal Laboratory Report