Molecular Orbital Theory 1
Simple Molecular Orbital Theory
Assignment 5:
Watch the lecture video below.
Simple Molecular Orbital Theory
Chemistry 107 Lecture 06
and
Character Tables and One Application of Symmetry
Chemistry 107 Lecture 04
Explanation: (a) In the first 12 minutes, vibrational selection rules are presented for the MCl3(CO)3 compounds. (b) Molecular Orbital Theory requires energy, symmetry, and overlap. Linear combinations of atomic orbital method (LCAO) method is introduced along with the first three "Basic Rules of MO Theory." RULE 1: The number of MOs out equals the number of AOs in. RULE 2: If AOs are degenerate, the interaction is proportional to the overlap interval, S. RULE 3: Orbitals must have the same symmetry to have non-zero overlap. Overlap and bond type is presented.
Video 1: YouTube video: https://www.youtube.com/watch?v=1CH6CeORL_g&list=PLqOZ6FD_RQ7kGnKLTbdwZ3IGVNXK43k7S&index=7, 50 minutes.
pdf Supporting Materials: Chemistry 107 lecture supplements: Simple Molecular Orbital Theory (6_Ch5_Simple MO Theory.pdf).
Test your understanding:
MO Theory Quiz - "MO_Theory_NO" (pdf)
MO Theory Quiz Solutions - " MO_Theory_NO_soln" (pdf)
Worksheet:
MO part 1: Simple Molecular Orbital Theory (pdf) (solutions)