Introduction to Spectroscopy (pdf)1.
IR, MS, and NMR Spectroscopies, in brief, 27 pages (pdf)
Mass Spectroscopy
Content:
Introduction to Mass Spectrometry (pdf)1.
EIMS Fragmentation (pdf)1.
Mass Spec. PowerPoint (pdf) accessed 9/9/2015 Prof. Klapstein, Saint Francis Xavier Univ.
computational article: formation of tropylium (pdf)
Exercises:
Mass spectra of common functional groups - C6 compounds (pdf)
In-class MS problems (pdf)
In-class MS solutions Compounds A thru E (pdf)
In-class MS solutions Compounds F thru Q (pdf)
Infrared Spectroscopy
Content:
H.T.'s IR Notes (pdf)
IR spectra of nujol and more (pdf)
IR spectra of aromatics/alkenes (pdf)
IR phenyl substitution (pdf)
CW vs. FTIR instrumentation (pdf)
ThermoNicolet FTIR configuration (pdf)
Mayo Web IR Spectroscopy chapter (pdf)
Introduction to Raman Spectroscopy (pdf)
Exercises:
IR spectra of C6 compounds (pdf)
IR spectra of C6 compounds annotated (pdf)
Pavia IR problems (pdf) (solutions)
Nuclear Magnetic Resonance Spectroscopy
Content:
H.T.'s NMR Notes (pdf)
Equivalent and Inequivalent Nuclei (pdf)
Equivalent and Inequivalent Nuclei - HT notes (pdf)
Coupling Trees (pdf)
Standard pulse sequences (pdf)
Decoupling, T1, T2, and DEPT (pdf)
Pulsed Field Gradient NMR (pdf)
TOCSY vs. COSY (pdf)
Animations:
net magnetic vector precession (mov)
Bloch Decay T1 relaxation (mov)
Bloch Decay with fast T2 (mov)
Hahn echo Carr-Purcell (mov)
pulse field gradient (mov)
T1 relaxation (mov)
Instrument Considerations:
NMR Instrumental Parameters (pdf)
NMR Field Strength and ∆v (pdf)
Exercises:
1D NMR
In-class simple H NMR problems - Pavia (pdf) (solution)
In-class MS/IR/H & C NMR problems 1 - 1 thru 5 (pdf) (solution)
In-class MS/IR/H & C NMR problems 2 - 15...61 (pdf) (solution)
In-class MS/IR//H & C NMR PS3 (pdf) (solution)
8.23 - MS/IR/NMR problem (pdf) (solution)
Hillary (pdf) (solution)
2D NMR - COSY, HETCOR, & HMQC
Pavia 1 (pdf) (solution)
Pavia2 (pdf) (solution)
9.43 - 2D problem (pdf) (solution)
9.44 - 2D problem (pdf) (solution)
9.45 -2D problem (pdf) (solution)
8.40A - 2D problem (pdf) (solution)
8.41A - 2D problem (pdf) (solution)
HMBC
9.36 - 2D problem (pdf) (solution)
8.44 - 2D problem (pdf) (solution)
INADEQUATE
8.46 - 2D problem (pdf) (solution)
8.35 - 2D problem (pdf) (solution)
9.52 - 2D problem (pdf) (solution)
8.39 - 2D problem (pdf) (solution)
NOE Difference
9.50 - 2D problem (pdf) (solution)
9.47 - 2D problem (pdf) (solution)
Luminescence Spectroscopy
presentation (pdf)
1. adapted from Andrew Harned's course URL: https://harnedgroup.com/classes/, accessed 01/20/2020.