Battery Information

By N6VI

Figure 1: Parthian Battery.

A clay jar of a prehistoric battery holds an iron rod surrounded by a copper cylinder.

When filled with vinegar or electrolytic solution, the jar produces 1.1 to 2 volts.

While constructing a railway in 1936 near Baghdad, workers uncovered what appeared to be a prehistoric battery, also known as the Parthian Battery. The object dates back to the Parthian empire and is believed to be 2,000 years old. The battery consisted of a clay jar that was filled with a vinegar solution into which an iron rod surrounded by a copper cylinder was inserted. This device produced 1.1 to 2.0 volts of electricity. Figure 1 illustrates the Parthian Battery.

Not all scientists accept the Parthian Battery as a source of energy. It is possible that the device was used for electroplating, adding a layer of gold or other precious metals to a surface. The Egyptians are said to have electroplated antimony onto copper over 4,300 years ago. Archeological evidence suggests the Babylonians were the first to discover and employ a galvanic technique in the manufacturing of jewelry by using an electrolyte based on grape juice to gold-plate stoneware. The Parthians, who ruled Baghdad (ca. 250 BC), may have used batteries to electroplate silver.

In 1749 American scientist and inventor Benjamin Franklin first used the term "battery" when he was doing experiments with electricity using a set of linked capacitors.

1800 Alessandro Volta an Italian invented the first true battery. Volta stacked discs of copper (Cu) and zinc (Zn) separated by cloth soaked in salty water.

Wires connected to either end of the stack produced a continuous stable current. Each cell (a set of a Cu and a Zn disc and the brine) produces 0.76 Volts (V). A multiple of this value is obtained given by the number of cells that are stacked together.

Up to this point, all existing batteries would be permanently drained when all their chemical reactants were spent. In 1859, Gaston Planté invented the lead–acid battery, the first-ever battery that could be recharged by passing a reverse current through it. A lead-acid cell consists of a lead anode and a lead dioxide cathode immersed in sulfuric acid. Both electrodes react with the acid to produce lead sulfate, but the reaction at the lead anode releases electrons whilst the reaction at the lead dioxide consumes them, thus producing a current. These chemical reactions can be reversed by passing a reverse current through the battery, thereby recharging it.

Planté's first model consisted of two lead sheets separated by rubber strips and rolled into a spiral. His batteries were first used to power the lights in train carriages while stopped at a station.

In 1866, Georges Leclanché invented a battery that consists of a zinc anode and a manganese dioxide cathode wrapped in a porous material, dipped in a jar of ammonium chloride solution. The manganese dioxide cathode has a little carbon mixed into it as well, which improves conductivity and absorption. It provided a voltage of 1.4 volts. This cell achieved very quick success in telegraphy, signaling, and electric bell work.

The dry cell form was used to power early telephones—usually from an adjacent wooden box affixed to fit batteries before telephones could draw power from the telephone line itself.

What is a Battery?

A battery, in concept, can be any device that stores energy for later use. A rock, pushed to the top of a hill, can be considered a kind of battery, since the energy used to push it up the hill (chemical energy, from muscles or combustion engines) is converted and stored as potential kinetic energy at the top of the hill. Later, that energy is released as kinetic and thermal energy when the rock rolls down the hill. Not real practical for everyday use though.

Common use of the word, "battery" in electrical terms, is limited to an electrochemical device that converts chemical energy into electricity, by a galvanic cell. A galvanic cell is a fairly simple device consisting of two electrodes of different metals or metal compounds (an anode and a cathode) and an electrolyte (usually acid, but some are alkaline) solution. A "Battery" is two or more of those cells in series, although many types of single cells are usually referred to as batteries - such as flashlight batteries. As noted above, a battery is an electrical storage device. Batteries do not make electricity, they store it, just as a water tank stores water for future use. As chemicals in the battery change, electrical energy is stored or released. In rechargeable batteries this process can be repeated many times.

Batteries are not 100% efficient - some energy is lost as heat and chemical reactions when charging and discharging. If you use 1000 watts from a battery, it might take 1050 or 1250 watts or more to fully recharge it.

Internal Resistance

Part - or most - of the loss in charging and discharging batteries is due to internal resistance. This is converted to heat, which is why batteries get warm when being charged up. The lower the internal resistance, the better. There is a good explanation and demonstration of Internal Resistance here (YouTube)

Slower charging and discharging rates are more efficient. A battery rated at 180 amp-hours over 6 hours might be rated at 220 AH at the 20-hour rate, and 260 AH at the 48-hour rate. Much of this loss of efficiency is due to higher internal resistance at higher amperage rates - internal resistance is not a constant - kind of like "the more you push, the more it pushes back".

Typical efficiency in a lead-acid battery is 85-95%, in alkaline and NiCad battery it is about 65%. True deep cycle AGM's (such as Concorde) can approach 98% under optimum conditions, but those conditions are seldom found so you should figure as a general rule about a 10% to 20% total power loss when sizing batteries and battery banks.

Practically all batteries used in PV and all but the smallest backup systems are Lead-Acid type batteries. Even after over a century of use, they still offer the best price to power ratio. A few systems use NiCad, but we do not recommend them except in cases where extremely cold temperatures (-50 F or less) are common. They are expensive to buy, and very expensive to dispose of due the the hazardous nature of Cadmium.

We have had almost no direct experience with the NiFe (alkaline) batteries, but from what we have learned from others we do not not recommend them - one major disadvantage is that there is a large voltage difference between the fully charged and discharged state. Another problem is that they are very inefficient - you lose from 30-40% in heat just in charging and discharging them. Many inverters and charge controls have a hard time with them. It appears that the only current source for new cells seems to be from Hungary. In the past they were often used by railroads as backup power, but nearly all have now changed over to newer types.

An important fact is that ALL of the batteries commonly used in deep cycle applications are Lead-Acid. This includes the standard flooded (wet) batteries, gelled, and AGM. They all use the same chemistry, although the actual construction of the plates etc varies.

NiCads, Nickel-Iron, and other types are found in a few systems, but are not common due to their expense, environmental hazards, and/or poor efficiency.

Types of Batteries

Batteries are divided in two ways, by application (what they are used for) and construction (how they are built). The major applications are automotive, marine, and deep-cycle. Deep-cycle includes solar electric (PV), backup power, traction, and RV and boat "house" batteries. The major construction types are flooded (wet), gelled, and AGM (Absorbed Glass Mat). AGM batteries are also sometimes called "starved electrolyte" or "dry", because the fiberglass mat is only 95% saturated with Sulfuric acid and there is no excess liquid.

Flooded may be standard, with removable caps, or the so-called "maintenance free" (that means they are designed to die one week after the warranty runs out). All AGM & gelled are sealed and are "valve regulated", which means that a tiny valve keeps a slight positive pressure. Nearly all sealed batteries are "valve regulated" (commonly referred to as "VRLA" - Valve Regulated Lead-Acid). Most valve regulated are under some pressure - 1 to 4 psi at sea level.

Battery Lifespan

The lifespan of a deep cycle battery will vary considerably with how it is used, how it is maintained and charged, temperature, and other factors. In extreme cases, it can vary to extremes - we have seen L-16's killed in less than a year by severe overcharging and water loss, and we have a large set of surplus telephone batteries that sees only occasional (10-15 times per year) heavy service that were just replace after 35+ years. We have seen gelled cells destroyed in one day when overcharged with a large automotive charger. We have seen golf cart batteries destroyed without ever being used in less than a year because they were left sitting in a hot garage or warehouse without being charged. Even the so-called "dry charged" (where you add acid when you need them) have a shelf life of 18 months at most. (They are not totally dry - they are actually filled with acid, the plates formed and charged, then the acid is dumped out).

These are some typical (minimum - maximum) typical expectations for batteries if used in deep cycle service. There are so many variables, such as depth of discharge, maintenance, temperature, how often and how deep cycled, etc. that it is almost impossible to give a fixed number

• Starting: 3-12 months

• Marine: 1-6 years

• Golf cart: 2-7 years

• AGM deep cycle: 4-8 years

• Gelled deep cycle: 2-5 years

• Deep cycle (L-16 type etc): 4-8 years

• Rolls-Surrette premium deep cycle: 7-15 years

• Industrial deep cycle (Crown and Rolls 4KS series): 10-20+ years.

• Telephone (float): 2-20 years. These are usually special purpose "float service", but often appear on the surplus market as "deep cycle". They can vary considerably, depending on age, usage, care, and type.

• NiFe (alkaline): 5-35 years

• NiCad: 1-20 years

Starting, Marine, or Deep-Cycle Batteries

Starting: (sometimes called SLI, for starting, lighting, ignition) batteries are commonly used to start and run engines. Engine starters need a very large starting current for a very short time. Starting batteries have a large number of thin plates for maximum surface area. The plates are composed of a Lead "sponge", similar in appearance to a very fine foam sponge. This gives a very large surface area, but if deep cycled, this sponge will quickly be consumed and fall to the bottom of the cells. Automotive batteries will generally fail after 30-150 deep cycles if deep cycled, while they may last for thousands of cycles in normal starting use (2-5% discharge).

Deep cycle batteries are designed to be discharged down as much as 80% time after time, and have much thicker plates. The major difference between a true deep cycle battery and others is that the plates are SOLID Lead plates - not sponge. This gives less surface area, thus less "instant" power like starting batteries need. Although these can be cycled down to 20% charge, the best lifespan vs cost method is to keep the average cycle at about 50% discharge. Unfortunately, it is often impossible to tell what you are really buying in some of the discount stores or places that specialize in automotive batteries. The golf car battery is quite popular for small systems and RV's. The problem is that "golf car" refers to a size of battery case (commonly called GC-2, or T-105), not the type or construction - so the quality and construction of a golf car battery can vary considerably - ranging from the cheap off brand with thin plates up to true deep cycle brands, such as Crown, Deka, Trojan, etc. In general, you get what you pay for.

Marine batteries are usually a "hybrid", and fall between the starting and deepcycle batteries, though a few (Rolls-Surrette and Concorde, for example) are true deep cycle. In the hybrid, the plates may be composed of Lead sponge, but it is coarser and heavier than that used in starting batteries. It is often hard to tell what you are getting in a "marine" battery, but most are a hybrid. Starting batteries are usually rated at "CCA", or cold cranking amps, or "MCA", Marine cranking amps - the same as "CA". Any battery with the capacity shown in CA or MCA may or may not be a true deep-cycle battery. It is sometimes hard to tell, as the term deep cycle is often overused - we have even seen the term "deep cycle" used in automotive starting battery advertising. CA and MCA ratings are at 32 degrees F, while CCA is at zero degree F. Unfortunately, the only positive way to tell with some batteries is to buy one and cut it open - not much of an option.

Deep Cycle Battery as a Starting Battery There is generally no problem with this, providing that allowance is made for the lower cranking amps compared to a similar size starting battery. As a general rule, if you are going to use a true deep cycle battery (such as the Concorde SunXtender) also as a starting battery, it should be oversized about 20% compared to the existing or recommended starting battery group size to get the same cranking amps. That is about the same as replacing a group 24 with a group 31. With modern engines with fuel injection and electronic ignition, it generally takes much less battery power to crank and start them, so raw cranking amps is less important than it used to be. On the other hand, many cars, boats, and RV's are more heavily loaded with power sucking "appliances", such as megawatt stereo systems etc. that are more suited for deep cycle batteries. We have used the Concorde SunXtender AGM batteries in some of our vehicles with no problems. It will not hurt a deep cycle battery to be used as a starting battery, but for the same size battery they cannot supply as much cranking amps as a regular starting battery and is usually much more expensive.

What Batteries Are Made Of

Nearly all large rechargeable batteries in common use are Lead-Acid type. (There are some NiCads in use, but for most purposes the very high initial expense, and the high expense of disposal, does not justify them). A few LithiumIon types are starting to make their appearance, but are much more expensive than Lead-Acid and most charge controllers do not have the correct setpoints for proper charging.

The acid is typically 30% Sulfuric acid and 70% water at full charge. NiFe (NickelIron) batteries are also available - these have a very long life, but rather poor efficiency (60-70%) and the voltages are different, making it more difficult to match up with standard 12v/24/48v systems and inverters. The biggest problem with NiFe batteries is that you may have to put in 100 watts to get 70 watts of charge - they are much less efficient than Lead-Acid. What you save on batteries you will have to make up for by buying a larger solar panel system. NiCads are also inefficient - typically around 65% - and very expensive. However, NiCads can be frozen without damage, so are sometimes used in areas where the temperatures may fall below -50 degrees F. Most AGM batteries will also survive freezing with no problems, even though the output when frozen will be little or nothing.

Plate Thickness

Plate thickness (of the Positive plate) matters because of a factor called "positive grid corrosion". This ranks among the top 3 reasons for battery failure. The positive (+) plate is what gets eaten away gradually over time, so eventually there is nothing left - it all falls to the bottom as sediment. Thicker plates are directly related to longer life, so other things being equal, the battery with the thickest plates will last the longest. The negative plate in batteries expands somewhat during discharge, which is why nearly all batteries have separators, such as glass mat or paper, that can be compressed.

Automotive batteries typically have plates about .040" (4/100") thick, while forklift batteries may have plates more than 1/4" (.265" for example in larger RollsSurrette) thick - almost 7 times as thick as auto batteries. The typical golf cart will have plates that are around .07 to .11" thick. The Concorde AGM's are .115", The Rolls-Surrette L-16 type (CH460) is .150", and the US Battery and Trojan L16 types are .090". The Crown L-16HC size has .22" thick plates. While plate thickness is not the only factor in how many deep cycles a battery can take before it dies, it is the most important one.

Most industrial (fork lift) deep-cycle batteries use Lead-Antimony plates rather than the Lead-Calcium used in AGM or gelled deep-cycle batteries and in automotive starting batteries. The Antimony increases plate life and strength, but increases gassing and water loss. This is why most industrial batteries have to be checked often for water level if you do not have Hydrocaps. The self discharge of batteries with Lead-Antimony plates can be high - as much as 1% per day on an older battery. A new AGM typically self-discharges at about 1-2% per month, while an old one may be as much as 2% per week.

Battery Size Codes

Batteries come in all different sizes. Many have "group" sizes, which is based upon the physical size and terminal placement. It is NOT a measure of battery capacity. Typical BCI codes are group U1, 24, 27, and 31. Industrial batteries are usually designated by a part number such as "FS" for floor sweeper, or "GC" for golf cart. Many batteries follow no particular code, and are just manufacturers part numbers. Other standard size codes are 4D & 8D, large industrial batteries, commonly used in solar electric systems.

Battery Group Size Chart

Motorcycle Battery Size Chart

Some common battery size codes used are: (ratings are approximate)

U1 34 to 40 Amp hours

Group 24 70-85 Amp hours

Group 27 85-105 Amp hours

Group 31 95-125 Amp hours

4-D 180-215 Amp hours

8-D 225-255 Amp hours

Golf Cart & T-105 180 to 225 Amp hours

L-16, L16HC etc. 340 to 415 Amp hours

Gelled Electrolyte

Gelled batteries, or "Gel Cells" contain acid that has been "gelled" by the addition of Silica Gel, turning the acid into a solid mass that looks like gooey Jell-O. The advantage of these batteries is that it is impossible to spill acid even if they are broken. However, there are several disadvantages. One is that they must be charged at a slower rate (C/20) to prevent excess gas from damaging the cells. They cannot be fast charged on a conventional automotive charger or they may be permanently damaged. This is not usually a problem with solar electric systems, but if an auxiliary generator or inverter bulk charger is used, current must be limited to the manufacturers specifications. Most better inverters commonly used in solar electric systems can be set to limit charging current to the batteries.

Some other disadvantages of gel cells is that they must be charged at a lower voltage (2/10th's less) than flooded or AGM batteries. If overcharged, voids can develop in the gel which will never heal, causing a loss in battery capacity. In hot climates, water loss can be enough over 2-4 years to cause premature battery death. It is for this and other reasons that we no longer sell any of the gelled cells except for replacement use. The newer AGM (absorbed glass mat) batteries have all the advantages (and then some) of gelled, with none of the disadvantages.

Temperature Effects on Batteries

Battery capacity (how many amp-hours it can hold) is reduced as temperature goes down, and increased as temperature goes up. This is why your car battery dies on a cold winter morning, even though it worked fine the previous afternoon. If your batteries spend part of the year shivering in the cold, the reduced capacity has to be taken into account when sizing the system batteries. The standard rating for batteries is at room temperature - 25 degrees C (about 77 F). At approximately -22 degrees F (-27 C), battery AH capacity drops to 50%. At freezing, capacity is reduced by 20%. Capacity is increased at higher temperatures - at 122 degrees F, battery capacity would be about 12% higher.

Battery charging voltage also changes with temperature. It will vary from about 2.74 volts per cell (16.4 volts) at -40 C to 2.3 volts per cell (13.8 volts) at 50 C. This is why you should have temperature compensation on your charger or charge control if your batteries are outside and/or subject to wide temperature variations. Some charge controls have temperature compensation built in (such as Morningstar) - this works fine if the controller is subject to the same temperatures as the batteries. However, if your batteries are outside, and the controller is inside, it does not work that well. Adding another complication is that large battery banks make up a large thermal mass.

Cycles vs Lifespan

A battery "cycle" is one complete discharge and recharge cycle. It is usually considered to be discharging from 100% to 20%, and then back to 100%. However, there are often ratings for other depth of discharge cycles, the most common ones are 10%, 20%, and 50%. You have to be careful when looking at ratings that list how many cycles a battery is rated for unless it also states how far down it is being discharged. For example, one of the widely advertised telephone type (float service) batteries have been advertised as having a 20-year life. If you look at the fine print, it has that rating only at 5% DOD - it is much less when used in an application where they are cycled deeper on a regular basis. Those same batteries are rated at less than 5 years if cycled to 50%. For example, most golf cart batteries are rated for about 550 cycles to 50% discharge - which equates to about 2 years.

Battery life is directly related to how deep the battery is cycled each time. If a battery is discharged to 50% every day, it will last about twice as long as if it is cycled to 80% DOD. If cycled only 10% DOD, it will last about 5 times as long as one cycled to 50%. Obviously, there are some practical limitations on this - you don't usually want to have a 5 ton pile of batteries sitting there just to reduce the DOD. The most practical number to use is 50% DOD on a regular basis. This does NOT mean you cannot go to 80% once in a while. It's just that when designing a system when you have some idea of the loads, you should figure on an average DOD of around 50% for the best storage vs cost factor. Also, there is an upper limit - a battery that is continually cycled 5% or less will usually not last as long as one cycled down 10%. This happens because at very shallow cycles, the Lead Dioxide tends to build up in clumps on the the positive plates rather in an even film. The graph above shows how lifespan is affected by depth of discharge. The chart is for a Concorde Lifeline battery, but all lead-acid batteries will be similar in the shape of the curve, although the number of cycles will vary.

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