WCF
Windows Communication Foundation (WCF) is a constituent part of .NET Framework.
See the list of related software at WCF Service Tools page.
Bindings
See the referenced text about WCF Bindings and how to choose and use them.
net.tcp
For performance on internal networks, with WCF-to-WCF communication, use net.tcp binary protocol.
To read about adding a net.tcp binding to a WCF service hosted in IIS 7.5 read the following topic.
Instance Management
See MSDN Magazine article on WCF Instance Management Techniques (link).
References
Windows Communication Foundation (WCF) Bindings and How to Use Them (link).
REST
Interop with jQuery is now easy - wcf.codeplex.com
WS-Security
Microsoft Patterns & Practices - Improving Web Services Security guide (link)
Improving Web Services Security: Scenarios and Implementation Guidance for WCF (link)
Securing .NET Web Services with the WS-Security Protocol (link)
Implement Secure .NET Web Services with WS-Security (link)
Other
- Sending large binary files to/from WCF (link)