Vantablack was created by Surrey Nanosystems in 2012 in partnership with National Physical Laboratory and ABSL Space Products in Great Britain to produce super-black coatings for better performance of imaging systems.
All images courtesy of Surrey Nanosystems
The original version of Vantablack is no longer made since they have developed spray coatings that are more easily applied than the original. Although it is commercially available, it does not come in spray cans for you to apply yourself.