IFIMUP has a long tradition and is internationally recognized for its fundamental research on the physics of advanced materials with significant scientific and technological impact, through the detailed, accurate and systematic characterization of a wide range of physical properties over extended ranges of temperature, magnetic and electric fields. The research activity covers the Physics of Transition Metal Oxides, Polariazable Materials, Magnetic Materials, Ferroelectrics and related Materials, Multiferroics and Magnetoelectrics, Colossal magnetoresistance compounds and Oxide Conductors”. The scientific activity has also extended to the use of non-invasive spectroscopic techniques (Raman, SERS) for biomedical proposes.
In the last decade nanotechnologies have been introduced and extended research has been done in the areas of magnetic, ferroic, magnetoelectric and multiferroic thin films, nanogranular and nanostructured magnetic and ferroelectric films, namely multilayers, spin valves and magnetically/electrically driven tunnel junctions. In parallel, fundamental research is being performed in layered/nanostratified materials having giant magnetocaloric and magnetostrictive effects.
More recently, the research activities at IFIMUP have been complemented with significant new work and facilities for ultrafast laser pulse generation and applications. IFIMUP hosts unique systems capable of generating phase-stabilized pulses in the single-cycle regime, unique diagnostics for their measurement and control, and is now using these sources to the study and control of carrier and spin dynamics in many promising materials and at unprecedented temporal resolutions.
The IFIMUP strategic plan relies on established long-standing national and international collaborations and envisages to promote “Excellent Science” within three main thematic vectors:
With the thematic vector on Quantum Materials, IFIMUP aligns its strategy with the EU new flagship project to promote quantum technologies (QT) over the next decade. In this respect, IFIMUP, in collaboration with UM and INL, is instituting the new QuantLAb, a CoLab initiative, to prepare for the newest EU flagship program. Our research embraces two main activities: Strongly correlated systems for room temperature cross coupling effects; Low-dimensional electronic/magnetic systems;
The thematic vector on Advanced Energy Materials directly engages the Secure, Clean and Efficient Energy societal challenge. One aims to develop disruptive technologies to harvest environmental (thermal, triboelectric and solar) energy, which will be key for the ongoing Internet of Things (IoT) revolution. On this, IFIMUP further aligns with regional and national economy-needs, collaborating with both Portuguese and World companies. We aim to deepen the Institute’s engagement towards Secure, Clean and Efficient Energy, embracing two main activities: Energy harvesting systems in remote and harsh environments; Integration of plasmonic and concentration systems in photovoltaic cells;
The third thematic vector is an opportunity to commit to Health and Life Sciences, supported from strong in-house expertise aiming to develop three complementary spectroscopy techniques for biomedicine applications: i) stimulated Raman Spectroscopy (RS) with highly increased acquisition speeds compatible with present clinical practices; ii) Brillouin Scattering Spectroscopy (BSS) to probe mechanical properties in the GHz range, offering a new spectral window to study biomechanical processes; iii) Broad spectrum and high-peak power few-cycle (7 fs) lasers for real-time and multi-labeled fluorescence lifetime imaging microscopy measurements.
A research in Physics-Education and dissemination to the general public is considered a very important activity of the institute. Through national and regional public broadcasting programs, web portals, newsletters, press releases, and public lectures, one informs and engages the general public on IFIMUP research and educational commitment. On this topic, an iconic activity is the so-called “Summer Physics School” happening every early september, involving over 80 high school students that integrate the Physics and Astronomy department/institute for an entire week, developing experimental projects under supervision of PhD Students.
In the 2002-2013 periods the group substantially increased its scientific output and impact in the international community. The group was able to consolidate access to international large scale facilities within international collaborations in the areas of magnetic and structural characterization (neutron and synchrotron radiation facilities, transmission microscopy), nuclear hyperfine techniques for local probe characterization, pulsed and stable extreme high-field infrastructures. The in-house experimental facilities were used thoroughly in order to produce the critical results to motivate proposals at European and USA facilities which were submitted and approved.
The main scientific achievements involve the highlight of the relative importance of spin-dependent tunneling transport in magnetic tunnel junctions, the discovery of a Griffhits-like phase in rare earth based magnetocaloric Tb5Si2Ge2 compounds and the discovery of multiferroic characteristics in charge-ordered compounds like Pr-Ca manganites. In addition the group was able to start a new local research field in the fabrication, functionalization and integration of custom-made nanoporous media for nanoscience applications. Almost perfect hexagonal lattice over large areas (~20 um2) were obtained. Membranes with pores diameter ranging from 15 nm to 100 nm and interpore distances from 50 nm to 200 nm are now routinely achieved (with thickness from ~500 nm upwards, controlled by the anodization time). The application of these templates in the fabrication of NiFe and Ni magnetic nanowires (NW) directly electrodeposited inside the pores was accomplished. Another application was on the fabrication of silica and manganite nanotubes inside the Al2O3 membrane nanopores by a sol-gel method. Work regarding the bio-functionalization of both inside and outside surfaces of the nanotubes is underway. Moreover, the group is now involved in the development and study of metallic nanowire-based metamaterials, using the above bottom-up approach, and their integration in optical fibers for sensors applications. Recently, a new line on the study of magnetic nanoparticles for hyperthermia applications has emerged.
Research activity in the “Polarisable Materials and Functional Nanostructures” group of IFIMUP-IN was focused on a diversified study of materials with interesting magnetic, dielectric properties that made them excellent candidates for the processing and development of devices for emerging technologies. Studying those materials has given rise to further new, challenging fundamental questions, whose answers have turned out to be important in gaining better knowledge of the actual physical mechanisms, and in improving their properties with regard to their technological applications. The following topics have been addressed: competitive interactions, Proton-glass state, relaxation processes, relaxors, non-linear rotation quantum dynamics, magnetoelectric effect and multiferroicity, spin-phonon (pseudospin) coupling, ordering in crystalline soft matter, the role of spin fluctuations and hybridisation effects on the electrical properties of R-T metallics.
The group’s activities in the field of ultrafast laser science and technology are both theoretical and experimental, encompassing the development and application of novel ultrafast light sources and techniques and their application to time-resolved studies of new materials, including low-dimensional magnetic structures, at unprecedented temporal resolutions and wavelength ranges. Recent achievements include the invention of a new method for the simultaneous measurement and control of ultrashort laser pulses dubbed dispersion-scan (d-scan), the demonstration of a unique source of intense laser pulses with a perfectly stabilized phase and record durations of only 3.0 femtoseconds (single-cycle regime), the introduction of new methods for the generation of femtosecond pulses in the deep-ultraviolet range, the first demonstration of broadband ultrafast third-harmonic generation in graphene, and the development of alternative ultrafast pump-probe and high-frequency magnetodynamic techniques.