electron orbitals

Chapter 11 Lecture Slides
ElectConfig-wkst.pdf
ElectConfig-wkst-KEY.pdf
electron configuration
  • Rutherford’s atom consists of a tiny, dense nucleus at the center and electrons that occupy most of the volume of the atom.

  • The hydrogen atom can emit only certain energies as it changes
    from a higher to a lower energy.

  • Hydrogen has quantized energy levels

  • The Bohr model assumed electrons travel around the nucleus in circular orbits, which is incorrect.

  • The wave mechanical model assumes the electron has both particle and wave properties and describes electrons as occupying orbitals.

    • The orbitals are different from the Bohr orbits.

    • Probability maps indicate the likelihood of finding the electron at a given point in space.

    • The size of an atom can be described by a surface that contains 90% of the total electron probability.

  • Atomic energy levels are broken down into principal levels (n), which contain various numbers of sublevels.

    • The sublevels represent various types of orbitals (s, p, d, f),
      which have different shapes.

    • The number of sublevels increases as n increases.

  • A given atom has Z protons in its nucleus and Z electrons surrounding the nucleus.

  • The electrons occupy atomic orbitals starting with the lowest energy (the orbital closest to the nucleus).

  • The Pauli exclusion principle states that an orbital can hold only two electrons with opposite spins.

  • The electrons in the highest energy level are called valence electrons.

  • The electron arrangement for a given atom explains its position on the periodic table.

  • Atomic size generally increases down a group of the periodic table and decreases across a period.

  • Ionization energy generally decreases down a group and increases across a period.