The heteroepitaxial growth of compound semiconductors on silicon is challenging because of differences in lattice parameters and thermal expansion coefficients. For GaAs/Si these differences amount to 4.2% for the lattice parameter and 123%, for the thermal expasion coeffient. The first critical issue, arising from the lattice misfit, is then how to control the density of dislocations. Dislocations are required to relax the misfit strain but often negatively affect the optical and electrical properties of active layers. In particular, threading dislocations reaching the surface may drastically decrease carrier mobility and lifetime of a device. The second concerns wafer bowing and crack formation caused by the mismatch of thermal expansion coefficients. This becomes especially relevant for film thicknesses beyond a few micrometers.
It is possible to overcome simultaneously the issue of defects induced by lattice and thermal mismatch by partitioning the epilayer into a space filling array of prismatic III-V semiconductor crystals a few um in width by out-of-equilibrium deposition onto tall Si pillars. The finite gaps between neighbouring crystals and their faceted growth front allows for the complete expulsion of threding dislocations and other extended defects generated at the GaAs/Si interface. In addition the high aspect ratio promotes the relaxation of the thermal strain. We expect our strategy based on molecular beam epitaxy (MBE) and micron-sized silicon patterning to be applicable for the monolithic integration of a large variety of compound semiconductors.
see e.g. "Monolithic integration of optical grade GaAs on Si (001) substrates deeply patterned at a micron scale" by S. Bietti at al. Appl. Phys. Lett. 103, 262106 (2013)
Left - GaAs prismatic crystal grown on Si pillar (dark grey area at the bottom of the image). Right - GaAs emission intensity at different spots in the GaAs crystal (follow the color code)
Top view of an array of GaAs crystals covering a Si subtrate
ST Microelectronics
Politecnico di Milano
Università di Milano Bicocca
OPTEC
CLOSED
MICROSPIRE - Future and Emerging Technology FET-H2020
Politecnico di Milano
Università di Milano Bicocca
University of Marburg
University of Dresden
University of Glasgow
CLOSED
Prof. Giovanni Isella - Politecnico di Milano
Prof. Leo Miglio - Università di Milano Bicocca
Prof. Francesco Montalenti - Università di Milano Bicocca
Douglas Paul - University of Glasgow
Kerstin Voltz - University of Marburg