LO 6.1 The student is able to, given a set of experimental observations regarding physical, chemical, biological, or environmental processes that are reversible, construct an explanation that connects the observations to the reversibility of the underlying chemical reactions or processes.
LO 6.12 The student can reason about the distinction between strong and weak acid solutions with similar values of pH, including the percent ionization of the acids, the concentrations needed to achieve the same pH, and the amount of base needed to reach the equivalence point in a titration.
LO 6.13 The student can interpret titration data for monoprotic or polyprotic acids involving titration of a weak or strong acid by a strong base (or a weak or strong base by a strong acid) to determine the concentration of the titrant and the pKa for a weak acid, or the pKb for a weak base.
LO 6.14 The student can, based on the dependence of Kw on temperature, reason that neutrality requires [H+] = [OH–] as opposed to requiring pH = 7, including especially the applications to biological systems.
LO 6.15 The student can identify a given solution as containing a mixture of strong acids and/or bases and calculate or estimate the pH (and concentrations of all chemical species) in the resulting solution.
LO 6.16 The student can identify a given solution as being the solution of a monoprotic weak acid or base (including salts in which one ion is a weak acid or base), calculate the pH and concentration of all species in the solution, and/or infer the relative strengths of the weak acids or bases from given equilibrium concentrations.
LO 6.17 The student can, given an arbitrary mixture of weak and strong acids and bases (including polyprotic systems), determine which species will react strongly with one another (i.e., with K >1) and what species will be present in large concentrations at equilibrium.
LO 6.18 The student can design a buffer solution with a target pH and buffer capacity by selecting an appropriate conjugate acid-base pair and estimating the concentrations needed to achieve the desired capacity.
LO 6.19 The student can relate the predominant form of a chemical species involving a labile proton (i.e., protonated/deprotonated form of a weak acid) to the pH of a solution and the pKa associated with the labile proton.
LO 6.20 The student can identify a solution as being a buffer solution and explain the buffer mechanism in terms of the reactions that would occur on addition of acid or base.
LO 6.21 The student can predict the solubility of a salt, or rank the solubility of salts, given the relevant Ksp values.
LO 6.22 The student can interpret data regarding solubility of salts to determine, or rank, the relevant Ksp values.
LO 6.23 The student can interpret data regarding the relative solubility of salts in terms of factors (common ions, pH) that influence the solubility.
LO 6.24 The student can analyze the enthalpic and entropic changes associated with the dissolution of a salt, using particulate level interactions and representations.
LO 6.25 The student is able to express the equilibrium constant in terms of ΔG° and RT and use this relationship to estimate the magnitude of K and, consequently, the thermodynamic favorability of the process.