Upon completion of this experiment, students will:
(CLO1). Explain basic chemical concepts related to chemical changes, energy, and properties of matter.
(CLO3). Analyze evidence to decide if generalizations or conclusions based on the obtained data are warranted
(CLO4). Interpret and utilize mathematical formulas while solving problems
(MLO) Use the Gas laws, combined gas and ideal gas equations to perform calculations to determine pressure, volume or temperature for a given gas using values at standard temperature and standard pressure of gases.
Use Graphical analysis to determine the relationship between the above variables.
Experiment 15 covers the gas laws by looking at Boyle's and Charles' Laws, Pressure, Volume and Temperature relationships.
Complete the pre laboratory problems before coming to the class meeting.
Complete the Report for Experiment 15
Using the MicroLab system to collect pressure and volume data to complete Part A of the laboratory assignment, create the appropriate graphs and answer all questions.
Using the data provided in the experiment, use Excel or Google sheets to complete the graph for Charles' law and answer all questions.
Consider using Activity 4 to complete the graphs for this experiment.
There are several quantities or properties that can be measured for a gas. These include the volume, amount, temperature and pressure. The volume of the gas represents the amount of space that is being occupied by the particles of gas. According to the Kinetic Molecular Theory, ideal gases are mostly empty space where volume of the gaseous particle is considered to be zero; therefore, gases can be compressed easily, pushing the particles closer together. Because gases are in constant motion, the gas particles can also expand easily to fill any space by moving further apart. We know that a gas will occupy any volume expanding or compressing to fill the volume. Further, ideal gases have no attraction or repulsive forces between the gaseous particles and they collide elastically.
The amount of the gas can be represented by the number of individual atoms or molecules present, the number of moles of individuals present or by the mass of the individuals present. The relationship between mass and moles is very important to understand. Formula, molecular or molar mass is equivalent to the mass of the substance present in one mole of individual particles of the substance.
The temperature is a measure of the heat, the motion of the particles or the kinetic energy of the molecules. According to the Kinetic Molecular Theory, temperature also affects the kinetic energy of the particles. As the temperature increases, the particles speed up becoming more energetic, which means the kinetic energy increases. If the temperature decreases, the particles lose energy, slowing down. If the particles become cold enough, they can lose all energy and all motion stops. At this point, the matter has reached absolute zero (zero Kelvin).
Lastly, Pressure is dependent upon how often the particles hit the surface and the force exerted by the particles as they collide with the surface of the container. If there are many collisions with the surface of the container, the pressure will be greater and if the collisions are more forceful because the molecules are moving with greater speed, having greater energy, the pressure will be greater. So both the amount of the substance present and the temperature of the matter will affect the pressure. The kinetic molecular theory states the particles in an ideal gas do not have attractive or repulsive forces between particles. If strong intermolecular forces exist between particles, then the pressure of the gas can be affected.
The gas laws compare any two of the above variables and try to understand how one variable is affected by the other. There are several gas laws. Boyle’s Law is the relationship between Pressure and Volume: VP = kb (a constant value when temperature and amount are constant) or volume is proportional to the inverse pressure 1/P. Boyle’s Law can also be written P1V1 = P2V2. The data from determining the pressure at various volumes can then be graphed and the resulting relationship can determine if volume and pressure are directly or indirectly proportional.
Charles’ Law is the relationship between Volume and Temperature: V= kcT or Volume is proportional to Temperature. Charles’ Law can be written
V1/T1 =V2/T2. In a graph, where Temperature is the independent variable, x, and Volume is the dependent variable, y, the data should be linear. Extrapolation of the graph to the x intercept or where the volume is zero, the temperature should theoretically be 0 Kelvin or absolute zero.
There are other gas laws, but this assignment is to show the relationships between volume and pressure and volume and temperature.
In this simulation, students will investigate three of the fundamental gas laws, including Boyle’s Law, Charles’ Law and Gay-Lussac’s Law. Students will have the opportunity to visually examine the effect of changing the associated variables of pressure, volume, or temperature in each situation. Also, students will analyze the gas samples at the particle level as well as manipulate quantitative data in each scenario. Finally students will interpret trends in the data by examining the graph associated with each of the gas laws.
Ideal Gas Law
Pressure
Volume
Temperature
Pump gas molecules to a box and see what happens as you change the volume, add or remove heat, and more. Measure the temperature and pressure, and discover how the properties of the gas vary in relation to each other.
Describe the behavior of the gas particles in the box.
Identify the relationship between pressure, volume, temperature, and number of gas molecules.
Describe the relationship between particle-wall collisions and pressure.
Predict how changing temperature will affect the speed of molecules.
This podcast explains the relationship of Volume and Temperature for an ideal gas using the PHeT Gas Properties simulation.
Marc Seigel
This podcast explains the relationship between Pressure and Temperature of an ideal gas. It uses the PHeT Gas Properties simulation.
There is no required pre laboratory writing assignment.
The pre laboratory problems are questions about the laboratory assignment, background, definitions or procedure and calculations.
We will test the validity of Boyle’s Law that says Volume is directly proportional to inverse pressure. This means that as the volume increases, the pressure decreases or as volume decreases, pressure increases. We will use a syringe that is connected to a pressure sensor. We could use a manometer to measure pressure, but it is difficult to change the volume with this type of tool. So we will use a pressure sensor connected to the MicroLab interface and a computer
North Carolina School of Science and Mathematics - Part of NCSSM CORE collection: This video shows the relationship between volume and pressure by placing a balloon, a marshmallow, and shaving cream a vacuum bell jar. http://www.dlt.ncssm.edu
Please attribute this work as being created by the North Carolina School of Science and Mathematics. This work is licensed under Creative Commons CC-BY http://creativecommons.org/licenses/b...
This is part A of the lab performed by Dr. Sullivan
This experiment could be completed using the MicroLab program to collect both volume and temperature data but we will use the data provided in the laboratory report. According to Charles’ law, the volume is directly proportional to temperature. According to the Kinetic Molecular theory, the particles that comprise an ideal gas have zero volume. The volume the gas occupies is the volume between the particles. So when a gas is cooled and the particle begin to condense into the liquid and finally the solid phase, it is theorized that the volume of the gas particles will be zero. So when a gas occupies zero volume, the temperature of the system should be zero on the Kelvin scale.
The given data of volume (y-axis) and Temperature (x-axis) will be plotted in a scatter plot and extrapolated to determine the x intercept when the volume on the y-axis is zero. Activity 4 can be used to create this scatter plot and extrapolate the data to determine the x intercept.
North Carolina School of Science and Mathematics
Part of NCSSM CORE collection: This video shows the collection of volume and temperature data by measuring the volume of air in a flask at different temperatures. Flasks of different volumes are used and the data is used to estimate the value of absolute zero. http://www.dlt.ncssm.edu
How low can you go? Estimate absolute zero by graphing volume versus temperature data for gases in a sealed syringe.
There are no post laboratory problems or conclusion paragraph for this laboratory assignment.