Students Learn About:
specialised testing of aircraft materials
– dye penetrant
– X-ray, gamma ray
– magnetic particle
– ultrasonic
aluminium and aluminium alloys used in aircraft including aluminium silicon, aluminium silicon magnesium, aluminium copper
structure/property relationship and alloy applications
– changes in macrostructure and microstructure
– changes in properties
heat treatment of applicable alloys
thermosetting polymers
– structure/property relationships and their application
– manufacturing processes
– compression moulding
– hand lay-up
– vacuum lay-up
– modifying materials for aircraft applications
composites
– types including reinforced glass fibre, Kevlar, carbon fibre and Fibre Metal Laminate (FML) as used in aircraft construction
– structure/property relationships and their application in aircraft
corrosion
– common corrosion mechanisms in aircraft structures
– pit and crevice corrosion
– stress corrosion/cracking
– corrosion prevention in aircraft
Students Learn To:
describe non-destructive tests used on aircraft materials and components
analyse structure, property relationship, uses and appropriateness of materials and processes used in aeronautical engineering applications
investigate the effects of heat treatment on the structure and properties of aluminium alloys
justify appropriate choices of polymers for their application and use in aircraft
describe the uses and application of composites used in aircraft construction
understand the mechanism of corrosion common to aircraft components and identify corrosion prevention techniques
This is similar in principle to X-ray testing but uses gamma rays, which have far greater penetration power. Great care must be taken due to the harm they can have on humans.
Also known as the magnetic dust method, this process is used to find cracks in a part. The piece of metal is placed across two magnetic poles, or a magnetic field is induced in it, and it is then sprinkled with a magnetic powder. The excess powder is removed and cracks are revealed by magnetic powder sticking to the area each side of the crack. This occurs because each side of the crack becomes a magnetic pole.
The major limitation of his method is that it will only work with magnetic materials, which makes it useless with aluminium and titanium alloys, which find extensive use in aircraft.
Identify and justify an appropriate test that could be used to check the airworthiness of the landing gear
Aluminium and its alloys are used in aircraft because of their desirable low density. The aluminum family of alloys was covered in Chapter 2, along with precipitation hardening of duralumin, an important alloy for aeronautical engineering.
One important point as an addendum to the information in Chapter 2. It is possible to refrigerate duralumin after Stage 1 of the precipitation hardening process (p 134), so it will not age. This is done so it can be naturally aged in service, hence receiving max strength whilst in service.
This range of aluminium copper alloys are now the most common family of alloys used in aircraft today. Formerly duralumin (2017) was widely used but the 2024 alloy, which offers higher tensile strengths, has largely replaced this. The 2000 series of alloys have better resistance to crack formation and thus find use in the lower surface of wings and the fuselage where they are most likely to suffer from tensile loads and fatigue cracking. They are usually used in clad form due to them having poorer corrosion resistance than pure aluminium.
This type of aluminium alloy is the basis for most cast aluminium alloys. The silicon improves the castability of the alloy and they exhibit excellent corrosion resistance.
(6000 Series)
Used in both the wrought form and as a casting alloy. These alloys are readily heat- treated by precipitation hardening. Although not generally as strong as the 2000 series alloys, they are more easily worked and offer better corrosion resistance.
These alloys find extensive use in aeronautical applications at various parts of the airframe. These aluminium zine magnesium alloys at times have additions of copper. They are more readily heat treatable than the 2000 series but stress corrosion cracking is a challenge, in part addressed by the addition of copper.
These high strength alloys offer lower densities than standard aluminium alloys, but also present some challenging properties. They have found extensive use in military aircraft and space vehicles. The final version of the external fuel tank of the Space Shuttle was made using aluminium lithium alloys, which yielded a weight saving of around 3.4 tonnes.
Worthy of mention here is Alclad. This is duralumin (or other 2000 series alloy) that is clad with pure aluminium. This is done because duralumin is not as corrosion resistant as pure aluminium. The duralumin substrate and pure aluminium sheet are rolled together; pressure welding joins the layers together. The aluminium sheet generally accounts for 1% of the total thickness of the two.
What are the reason certain alloys are used? what are their specific use cases?
What is the history of the development of this material?
Were they any specific points in history that determined the development of this material?
Titanium alloys are used in airframes, landing gear and jet engines because of the combination of properties they offer. The have moderate density, high strength, long fatigue life, toughness and resistance to corrosion and oxidation. They also maintain their mechanical properties up to 500°C. Using titanium alloys to replace some steels and nickel alloys in jet engine construction saves significant weight in the complete jet engine.
Pure titanium is an allotropic material, having an HCP structure (a-Ti) at room temperature and a BCC structure (B-Ti) above 885°C. However, with the addition of alloying elements it is possible to get both structures to exist at room temperature. Pure titanium, a-Ti alloys and ß-Ti alloys are all used in aviation. It is also possible to have an alloy with a mix of a-Ti and ß-Ti and this is called an a-ß-Ti alloy. The titanium alloy using Ti-6A1-4V is an a-ß-Ti alloy and it is one of the most used titanium alloys in the aviation industry. The yield strength of annealed Ti-6A1-4V is approximately 925 MPa.
Nickel-based superalloys, owing to their superior mechanical and chemical properties, find wide applications in the aerospace, marine, nuclear reactor, and chemical industries. But the machinability of nickel-based superalloys is always a matter of concern, while processing them. Wide areas are being explored with a view toward having improved machining performance of nickel-based superalloys. The use of hybrid machining processes, such as thermal-assisted machining, cryogenically enhanced machining, and media-assisted machining, is becoming favoured as they offer enhanced machining conditions and extended cutting tool life during machining of nickel-based superalloys. Future research endeavors might focus on the development of new grades of cutting tools, coating material, and hybridized machining techniques to ensure their stability and thermomechanical properties at high production rates.
https://www.sciencedirect.com/topics/materials-science/nickel-based-superalloys
Like the nickel superalloys, steel's density means it is only used where is strength is essential. While a variety of alloy steels are used in aviation two alloy steels are of particular note. Maraging steels are very low carbon steels (≤0.03%C) with large amounts of nickel (17-19%) with cobalt (8-12%), molybdenum (3-5%) and small amounts of titanium and aluminium. The large amount of nickel means that after austenitising, the steel can be slow cooled to form a martensitic structure, but the martensite is not like that in a quenched plain carbon steel, it is softer with more ductility and toughness. The maraging steel can then be machined and shaped, but it is then aged at around 500°C which results in precipitates forming that strengthen the steel to a great degree; leading to yield strengths up to 2,000 MPa.
Precipitation hardened stainless steels are also used in some structural applications for aircraft where corrosion resistance and strength are required. Stainless steel were used in some early supersonic and hypersonic aircraft to cope with the outer skin heating due to friction, but lighter alloys such as titanium alloys have largely replaced them.
The structure of fibre reinforced composites has a big impact on their behaviour. This is because the way that the fibres are arranged will affect how the loads are carried. Unidirectional fires are fibres that all travel parallel to one another. These include materials like continuous MMCs.
These materials are very effective at carrying a load parallel to the fibres. They are, however, more likely to suffer separation of the fibres if bending occurs. Such materials are termed anisotropic, i.e. their properties differ in different directions. It is possible to arrange shorter fibres in random direction; this will lower the maximum tensile strength but increases the resistance to separation if bending occurs.
Consider the following factors when selecting a manufacturing process for your product:
Form: Do your parts have complex internal features or tight tolerance requirements? Depending on the geometry of a design, manufacturing options may be limited, or they may require significant design for manufacturing (DFM) optimization to make them economical to produce.
Volume/cost: What’s the total or the annual volume of parts you’re planning to manufacture? Some manufacturing processes have high front costs for tooling and setup, but produce parts that are inexpensive on a per-part basis. In contrast, low volume manufacturing processes have low startup costs, but due to slower cycle times, less automation, and manual labor, cost per part remains constant or decreases only marginally when volume increases.
Lead time: How quickly do you need parts or finished goods produced? Some processes create first parts within 24 hours, while tooling and setup for certain high volume production processes takes months.
Material: What stresses and strains will your product need to stand up to? The optimal material for a given application is determined by a number of factors. Cost must be balanced against functional and aesthetic requirements. Consider the ideal characteristics for your specific application and contrast them with the available choices in a given manufacturing processes.
Thermoplastics are the most commonly used type of plastic. The main feature that sets them apart from thermosets is their ability to go through numerous melt and solidification cycles without significant degradation. Thermoplastics are usually supplied in the form of small pellets or sheets that are heated and formed into the desired shape using various manufacturing processes. The process is completely reversible, as no chemical bonding takes place, which makes recycling or melting and reusing thermoplastics feasible.
Common types of thermoplastic materials:
Acrylic (PMMA)
Acrylonitrile butadiene styrene (ABS)
Polyamide (PA)
Polylactic acid (PLA)
Polycarbonate (PC)
Polyether ether ketone (PEEK)
Polyethylene (PE)
Polypropylene (PP)
Polyvinyl chloride (PVC)
In contrast with thermoplastics, thermosetting plastics (also referred to as thermosets) remain in a permanent solid state after curing. Polymers in thermosetting materials cross-link during a curing process that is induced by heat, light, or suitable radiation. This curing process forms an irreversible chemical bond. Thermosetting plastics decompose when heated rather than melting, and will not reform upon cooling. Recycling thermosets or returning the material back into its base ingredients is not possible.
Common types of thermoplastic materials:
Cyanate ester
Epoxy
Polyester
Polyurethane
Silicone
Vulcanized rubber
This process takes an unpolymerised preform and compresses it in a mould with heat. The heat and the pressure form the shape and polymerise the polymer. The finished moulding is then ejected. It is used for making plugs, switches and casters.
This is similar to compression moulding but instead of the polymerising happening in the mould, it happens in the adjacent cavity. The molten polymer is transferred via a sprue to the actual mould. It is also used for moulding thermosets.
This is where fibres are placed into a mould and the resin is manually applied onto the fibres. First a gel coat is applied, and then the fibre reinforcement is added in the form of mat or cloth. The resin is poured, brushed or sprayed on, then rollers are used to force the resin to impregnate the fibre mat. In areas where extra thickness sis needed more fibre mat is placed down and the resin rolled into that area again. It is essential that the resin bonds properly to the fibres. An alternative to hand lay-up is the spray-up process where a special gun sprays the resin and continuous strand roving (glass fibre) which is chopped and sprayed at the same time. This chopped roving and resin mix in the mould. It is then rolled to remove air and improve impregnation of the resin into the fibres.
The vacuum bag autoclave process is usually used with epoxy resin based composites. The material used is called prepreg and is uni directional carbon fibres within a partially cured epoxy resin. The material is arranged in years in the mould and then placed in a bag. A vacuum is applied to the bag and this removes any air within the laminates. The bag is then placed in an autoclave at an appropriate temperature and elevated pressure where curing is then completed. For epoxy resins the autoclave will be set to a temperature of around 190°C and at a pressure of around 690 kPa (6.9 bar). This vacuum bag process finds use in forming composite aircraft panels such as wings and other large surfaces
With fuel costs representing the highest of all operating costs for aircraft, it's not surprising that the demand for lighter aircraft has risen with it. To put this in perspective, it is interesting to note that years ago MIT researchers estimated that for each passenger to carry a cell phone, it cost Southwest Airlines and additional $1.2m annually in fuel costs. If the passengers each carried a laptop then the cost jumped to $21.6m!
Polymer and composite materials meet the challenge of helping reduce aircraft weight by being up to ten times lighter than metal. This sharply lowers lifetime fuel costs, reduces emissions, and extends flight range. By and large, the most efficient airframes contain large amounts of carbon-fiber reinforced polymers and composites. These airframes and components can be responsible for reducing aircraft weight by as much as 20%.
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Weight reduction - savings in the range of 20%-50% are often quoted.
It is easy to assemble complex components using automated layup machinery and rotational molding processes.
Monocoque ('single-shell') molded structures deliver higher strength at a much lower weight.
Mechanical properties can be tailored by 'lay-up' design, with tapering thicknesses of reinforcing cloth and cloth orientation.
Thermal stability of composites means they don't expand/contract excessively with a change in temperature (for example a 90°F runway to -67°F at 35,000 feet in a matter of minutes).
High impact resistance - Kevlar (aramid) armor shields planes, too - for example, reducing accidental damage to the engine pylons which carry engine controls and fuel lines.
High damage tolerance improves accident survivability.
'Galvanic' - electrical - corrosion problems which would occur when two dissimilar metals are in contact (particularly in humid marine environments) are avoided. (Here non-conductive fiberglass plays a role.)
Combination fatigue/corrosion problems are virtually eliminated.
Composites are one of the newest and most important areas for aircraft manufacture. Composite materials offer good specific strength, high resistance to cyclic stresses and weather resistance. Composites may be degraded by UV light, but making them heavily pigmented reduces this. Composites may also be manufactured to be stronger in one direction than another. A composite may be manufactured to be isotropic (equal strength in all directions), or anisotropic (strength in one direction).
Glass Fibre Reinforced Polymers (GFRP), also known by the trade name Fibreglass, are fine glass fibres embedded in a resin matrix. Polyester, vinyl ester and epoxy resins are all possible resin materials. The glass fibre provides tensile strength while the resin provides toughness. Although not quite as strong as other fibres and also heavier, they are a cost effective option that has also found aeronautical use in Fibre Metal Laminates (FML).
This is one of the most important composites in the aircraft industry. Carbon fibre reinforced composites are a composite of carbon fires embedded in a resin matrix, which in aeronautical applications is normally epoxy resin. The combination of the two components produces the desirable strength and toughness. Typically, carbon fire reinforced polymers consist of 62% by volume carbon fires. The overall properties are lightweight, very high specific strength and high modulus of elasticity. Particularly important is the resistance to cyclic stress that carbon fibre exhibits. It is these properties that make it so desirable for aircraft. Not only are fighters such as the Saab Gripen and Eurofighter Typhoon using CFRP, but CFRP is also used in the Boeing 737 and Airbus control surfaces and wingtips. The Boeing 787 Dreamliner has its fuselage predominately made from CFRP One disadvantage of CFRP is that fails like a brittle material; with no plastic failure first. This contrasts with a metal like steel, which progressively fails and usually shows warnings such as cracks or bending. Damage detection and repair are also much more complex.
Aramid fire reinforced composites are very similar to carbon fibre composites. The difference is that Aramid fibres are used in lieu of the carbon fibres in an epoxy resin matrix. Aramid, better known under the trade name Kevlar, offers similar properties to carbon fibre, but is more resistant to impacts and abrasion. This is important in some battlefield conditions where shrapnel or debris could shorten the life of a carbon fibre component by producing surface defects.
These are laminated structures of metal and fibre reinforced composites., the most common one being GLARE (Glass Laminate Aluminium Reinforced Epoxy) which is used in the Airbus A380. Because they are laminated with metals they perform more like metal sheeting than fibre reinforced composite sheets, but they offer enhanced properties to a non-laminated metal sheet. Advantages include, improved impact resistance, better fatigue and corrosion resistance, and weight advantages. They can also have their strength properties directional for specific locations in the fuselage unlike a standard metal sheet.
A lot of research has been done into metal matrix composites, with an intention to use them in advanced high-speed jets. MMCs are similar to the two above except that the matrix is not a polymer but a metal. An example would be boron fibre aluminium, a composite using an aluminum matrix with boron fibres to reinforce it. This improves the tensile strength of the aluminium alloy by a huge factor. For example aluminium alloy 6061 has a tensile strength of 310 MPa. With a boron/6061 composite with 51% boron, the tensile strength is increased to 1417 MPa. MC's exist in three forms, continuous fibre reinforced MMCs, discontinuous fibre reinforced MMCs and particulate reinforced MMCs. The continuous fibre type gives far greater tensile strength but is also more difficult to make. The discontinuous fibre type is manufactured using powder metallurgy methods (see Chapter 2). MMCs are capable of withstanding higher temperatures, as the metal matrix can withstand elevated temperatures better than the epoxy matrix. They are, however, heavier than polymer matrix composites.
Epoxy adhesives are used to join composite aircraft surfaces to the base structure. Aircraft such as the Eurofighter Typhoon utilise epoxy adhesives in this way.
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The structure of fibre reinforced composites has a big impact on their behaviour. This is because the way that the fibres are arranged will affect how the loads are carried. Unidirectional fires are fibres that all travel parallel to one another. These include materials like continuous MMCs. These materials are very effective at carrying a load parallel to the fibres. They are, however, more likely to suffer separation of the fibres if bending occurs. Such materials are termed anisotropic, i.e. their properties differ in different directions.
It is possible to arrange shorter fibres in random direction; this will lower the maximum tensile strength but increases the resistance to separation if bending occurs. Another option is to arrange the fibres at angles of 0°, 45° and 90° to one another in alternate layers. This is similar to plywood in principle and will produce a material that maximises strength in desired directions. This does not, however, make it isotopic, as isotropic materials have the same strength in all directions. It is also possible to produce a three-dimensional structure of fires that will give the required strength along three axes.
Corrosion is a great problem in aircraft design. The frames and skin of aircraft are already highly stressed, so weakening via corrosion is a major concern. Although composites offer resistance to electrochemical corrosion, UV light and the weather may degrade them. A large majority of aircraft still use metal airframes and skins, so corrosion is still a problem. Corrosion mechanisms are outlined in Chapter 1 and the student should refer to this section.
This is a concentration cell that occurs because of different oxygen levels at the top and bottom of a crevice. The example in Chapter 1 of a car door is similar to crevice corrosion, but crevice corrosion usually involves a very fine gap that traps a fluid at the base. This type of corrosion is a concern, as metal aircraft are often riveted with fine gaps where the skins join. Moisture forms in these gaps each time the aircraft crosses the "dew point". The dew point is a particular combination of pressure, temperature and moisture content in the air, where water precipitates onto a surface (e.g. misting of a car windscreen). Aircraft always have moisture on them because of: condensation on the airframe from temperature changes in the atmosphere [20°C at sea level, -53°C at 10,671 m (35,000 ft)] airborne moisture accumulating rain
This is a particularly dangerous form of corrosion, where the action of tensile stress and corrosive environment conspire to bring about crack formation. The stresses that cause SCC can be residual stresses or applied. On their own neither would cause failure but with the two-combined failure occurs. Different alloys are effected by different environments; stainless steels are susceptible to SCC in chloride environments but safe in ammonia-based environments, while brasses are the reverse. Some aluminum alloys may suffer SCC in seawater or in the presence of air and water vapour.
In SCC the combined action involves the tensile stress causing pits or cracks to form and then the corrosion occurring with the tip of the crack becoming anodic. It has been shown that applying cathodic protection will stop SC occurring. But once the protection is removed the SC continues. SC can be reduced or prevented though lowering stress levels, removing the corrosive environment if possible, changing alloys to one not effected by the environment present or applying cathodic protection.
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