On December 25, 2021, NASA launched the James Webb Space Telescope (JWST) from French Guiana, heralding a new era in our comprehension of exoplanets and beyond. In the nearly two years since JWST became fully operational, it has facilitated groundbreaking discoveries, from offering direct evidence of photochemical processes in exoplanet atmospheres to unveiling unprecedented images of the universe. However, researchers from the University of Bristol and the University of Minnesota have found that combining JWST's infrared observations with UV/Vis data from the Hubble and Spitzer telescopes results in even more comprehensive exoplanet atmospheric spectra. This integrated approach offers a more robust understanding of the chemical and physical processes underlying exoplanet atmospheres.
Why study exoplanet atmospheres?
Exoplanets are cool but far, far away. The closest exoplanet, Proxima Centauri b, is approximately 4.2 light-years away, a distance that renders any thought of sending a
probe or visiting impossible. Instead, astronomers must turn to indirect methods such as analysing the light that passes through exoplanet atmospheres to glean insights into these distant worlds.
By studying the light filtering through an exoplanet's atmosphere, astronomers can identify the molecules and chemical species present. This information provides a wealth of knowledge about the exoplanet, including its physical and chemical environment. For example, on Earth, the presence of ozone (O3) in our atmosphere reveals a great deal about our planet, from the photochemical reactions that produce it to the biological activity that supplies the oxygen necessary for its formation. Remember that ozone is produced in our atmosphere by the following UV-induced reaction: 2O2 → O3 + O.
The same principle applies to exoplanet atmospheres. By examining the molecular composition of the atmosphere of these distant worlds, astronomers can infer crucial details about the planet's conditions, such as potential volcanic activity, lightning, geysers, or other dynamic processes. But how do astronomers identify these molecules?
Molecular fingerprints
Molecules interact with light in various ways depending on the wavelength and energy of the light. When exposed to ultraviolet (UV) and visible (Vis) light, electrons within the molecules transition to higher energy levels. Exposure to infrared (IR) light, on the other hand, causes the molecules to vibrate in very specific ways. These interactions produce unique spectra, which are collections of bands showing the wavelengths at which molecules absorb light. Figure 1 shows the infrared spectrum for water. There are three main modes of vibrations for water when interacting with infrared light: bending, and symmetric and asymmetric stretches.