〒066-8655 北海道千歳市美々758番地90
居室:研究実験棟E124
Tel : 0123-27-6067
E-mail: h-tanaka"at"photon.chitose.ac.jp
<略歴>
1998年3月 名古屋大学工学部応用物理学科 卒業
2000年3月 名古屋大学大学院工学研究科応用物理学専攻 博士前期課程 修了
2003年3月 名古屋大学大学院工学研究科応用物理学専攻 博士後期課程 修了
学位: 博士(工学)
2003年4月 名古屋大学大学院 工学研究科 応用物理学専攻 助手
2004年4月 名古屋大学大学院 工学研究科 マテリアル理工学専攻 助手
2007年4月 名古屋大学大学院 工学研究科 マテリアル理工学専攻 助教
2017年4月 名古屋大学大学院 工学研究科 応用物理学専攻 助教
2022年9月~2024年3月 名古屋大学国際高等研究機構 助教(兼任)
2024年4月 公立千歳科学技術大学 理工学部 応用化学生物学科 准教授
<研究業績>
・原著論文
Y. Suzuki, M. Arczyński, M. Wakizaka, H. Tanaka, R. Ishikawa, T. Yoshida, T. Yamane, K. Sato, R. Sakamoto and M. Yamashita, “Revisiting cobaloxime(II) chemistry and clearing misconceptions of cobaloxime(II) in diamagnetic Ni(II) and Pd(II) matrixes using comprehensive magnetic measurements”, Phys. Chem. Chem. Phys. 27, 10321-10330 (2025). DOI: https://doi.org/10.1039/d5cp00629e
R. Takaki, H. Iguchi,* L. Qu, J. Pirillo, S. Kusaka, Y. Hijikata, H. Tanaka, W. Matsuda, S. Seki, and R. Matsuda*, “Diruthenium(II,II) Complex Assemblies Showing Electrical Conduction via π-Stacked 2-Pyrenecarboxylate Moiety”, Chem. Asian J. 20, e202401599 (2025). DOI: https://doi.org/10.1002/asia.202401599
S. Ito, H. Tanaka, Y. Oshima, K. Kanahashi, H. Ito, B. Chen, H. Ohta and T. Takenobu, “Systematic investigation of charge transport and thermoelectric properties in semicrystalline polymers: electrochemical doping effects on doping level and temperature dependence using one sample”, Appl. Phys. Express 18, 021002 (2025). DOI: https://doi.org/10.35848/1882-0786/adb23e
M. Wakizaka, H. Tanaka, S. Takaishi, M. Yamashita, “Superatomic Stabilization of Dinuclear Platinum (III) through Iodide-Bridged Five-Center Ten-Electron Bonding”, Inorg. Chem. 64, 1, 97-104 (2025). DOI: https://doi.org/10.1021/acs.inorgchem.4c04178
H. Tanaka*, S. Ito, T. Matsui, T. Takenobu*, “Facile and controllable chemical doping of conducting polymers with an ionic liquid dopant”, Appl. Phys. Express 17, 031002-1-4 (2024). DOI: https://doi.org/10.35848/1882-0786/ad2f66
Y. Tanaka, S. Ito, J. Liu, H. Ou, H. Tanaka, J. Pu, A. Ikeno, T. Hatakeyama, T. Takenobu*, “Solution-Processable Ultrapure-Blue Light-Emitting Electrochemical Cells”, Adv. Optical Mater. 2023, 2301119-1-7. DOI: https://doi.org/10.1002/adom.202301119
M. Wakizaka*, R. Ishikawa, H. Tanaka, S. Gupta, S. Takaishi, M. Yamashita*, “Creation of a Field-Induced Co(II) Single-Ion Magnet by Doping into a Zn(II) Diamagnetic Metal–Organic Framework”, Small 2023, 2301966-1-6. DOI: https://doi.org/10.1002/smll.202301966
T. Sakurai, Y. Hiraoka, H. Tanaka, Y. Miyake, N. Fukui, H. Shinokubo*, "Easily Switchable 18π-, 19π-, and 20π-Conjugation of Diazaporphyrin Double-Pincer Bispalladium Complexes" Angew. Chem. Int. Ed. 15, e202300437-1-5 (2023). DOI: https://doi.org/10.1002/anie.202300437
T. Yoshida,* S. Takaishi,* L. Guérin, T. Kojima, H. Ohtsu, M. Kawano, T. Miyamoto, H. Okamoto, K. Kato, M. Takata, Y. Hosomi, S. Yoshida, H. Shigekawa, H. Tanaka, S. Kuroda, H. Iguchi, B. K. Breedlove, Z.-Y. Li, M. Yamashita*, “Hydrogen bonding propagated phase separation in quasi-epitaxial single crystals: a Pd-Br molecular insulator”, Inorg. Chem. 61, 14067-14074 (2022). DOI: https://doi.org/10.1021/acs.inorgchem.2c02078
M. Wakizaka*, M. R. Mian, T. Yoshida, T. Sato, H. Tanaka, T. Miyamoto, H. Okamoto, S. Takaishi, H. Iguchi, and M. Yamashita*, “Ni(III) Mott–Hubbard-like State Containing High-Spin Ni(II) in a Semiconductive Bromide-Bridged Ni-Chain Compound”, Inorg. Chem. 61, 9504-9513 (2022). DOI: https://doi.org/10.1021/acs.inorgchem.2c00473
S. Kuroda*, H. Tanaka, Y. Shimoi, "Microscopic observation of efficient intergrain charge transport processes in organic transistors of semicrystalline poly(3-hexylthiophene)" Appl. Phys. Express. 15, 041004-1-5 (2022). DOI: https://doi.org/10.35848/1882-0786/ac5d79
A. Yagi, N. Okada, N. Fukui, H. Tanaka, T. Hatakeyama, H. Shinokubo*, “Nitrogen Extrusion of Diazacorrphycenes to Azacorroles and Synthesis of Two Types of Copper 10-Azacorrole Complexes”, Chem. Lett. 51, 321-324 (2022). DOI: https://doi.org/10.1246/cl.210777
S. Ito, K. Kanahashi, H. Ohta, H. Ito, T. Takenobu*, H. Tanaka*, “Structure and thermoelectric properties of electrochemically doped polythiophene thin films: Effect of side chain density”, Appl. Phys. Lett. 119, 183304-1-6 (2021). DOI: https://doi.org/10.1063/5.0067769
H. Ito*, H. Mada, K. Watanabe, H. Tanaka*, T. Takenobu*, “Charge transport and thermoelectric conversion in solution-processed semicrystalline polymer films under electrochemical doping”, Commun. Phys. 4, 8-1-9 (2021). DOI: https://doi.org/10.1038/s42005-020-00510-2
M. R. Mian, M. Wakizaka*, T. Yoshida, H. Iguchi*, S. Takaishi, U. Afrin, T. Miyamoto, H. Okamoto, H. Tanaka, S. Kuroda, B. K. Breedlove and M. Yamashita*, “An unusual Pd(III) oxidation state in the Pd-Cl chain complex with high thermal stability and electrical conductivity”, Dalton Trans. 50, 1614-1619 (2020). DOI: https://doi.org/10.1039/d0dt03848b
K. Kanahashi, Y.-Y. Noh, W.-T. Park, H. Yang, H. Ohta, H. Tanaka*, and T. Takenobu*, “Charge and thermoelectric transport mechanism in donor-acceptor copolymer films”, Phys. Rev. Research, 2, 043330-1-10 (2020). DOI: https://doi.org/10.1103/PhysRevResearch.2.043330
M. R. Mian, U. Afrin, H. Iguchi*, S. Takaishi, T. Yoshida, T. Miyamoto, H. Okamoto, H. Tanaka, S. Kuroda and M. Yamashita*, “Conductive zigzag Pd(III)-Br chain complex realized by a multiple-hydrogen-bond approach”, CrystEngComm 22, 3999-4004 (2020). DOI: https://doi.org/10.1039/D0CE00332H
H. Tanaka*, S. Kawamura, P. Sonar, Y. Shimoi, T. T. Do, T. Takenobu*, “Highly efficient microscopic charge transport within crystalline domains in a furan-flanked diketopyrrolopyrrole-based conjugated copolymer”, Adv. Funct. Mater. 30, 2000389-1-10 (2020). DOI: https://doi.org/10.1002/adfm.202000389
Q. Liu, K. Kanahashi, K. Matsuki, S. Manzhos, K. Feron, S.E. Bottle, K. Tanaka, T. Takenobu, H. Tanaka*, P. Sonar*, “Triethylene Glycol Substituted Diketopyrrolopyrrole- and Isoindigo-Dye Based Donor-Acceptor Copolymers for Organic Light-Emitting Electrochemical Cells and Transistors”, Adv. Electron. Mater. 6, 1901414-1-9 (2020). DOI: https://doi.org/10.1002/aelm.201901414
S. Kuroda*, H. Tanaka, Y. Shimoi, K. Takimiya, “Spatial extent of wave functions of charge carriers in a thienothiophene-based high-mobility molecular semiconductor”, Appl. Phys. Express. 13, 041004-1-4 (2020). DOI: https://doi.org/10.35848/1882-0786/ab7e08
H. Tanaka*, K. Kanahashi, N. Takekoshi, H. Mada, H. Ito*, Y. Shimoi, H. Ohta, T. Takenobu*, “Thermoelectric properties of a semicrystalline polymer doped beyond the insulator-to-metal transition by electrolyte gating”, Sci. Adv. 6, eaay8065-1-8 (2020). DOI: https://doi.org/10.1126/sciadv.aay8065
H. Tanaka*, A. Wakamatsu, M. Kondo, S. Kawamura, S. Kuroda, Y. Shimoi, W. -T. Park, Y. -Y. Noh*, and T. Takenobu*, “Microscopic observation of efficient charge transport processes across domain boundaries in donor-acceptor-type conjugated polymers”, Commun. Phys. 2, 96-1-10 (2019). DOI: https://doi.org/10.1038/s42005-019-0196-7
S. Schott, E. McNellis, C. Nielsen, H.-Y. Chen, S. Watanabe, H. Tanaka, I. McCulloch, K. Takimiya, J. Sinova, and H. Sirringhaus* "Tuning the effective spin-orbit coupling in molecular semiconductors", Nat. Commun. 8, 15200-1-10 (2017). DOI: https://doi.org/10.1038/ncomms15200
M. R. Mian, H. Iguchi*, S. Takaishi, H. Murasugi, T. Miyamoto, H. Okamoto, H. Tanaka, S. Kuroda, B. K. Breedlove, and M. Yamashita*, “Multiple-Hydrogen-Bond Approach to Uncommon Pd(III) Oxidation State: A Pd−Br Chain with High Conductivity and Thermal Stability”, J. Am. Chem. Soc. 139, 6562-6565 (2017). DOI: https://doi.org/10.1021/jacs.7b02558
T. Sakanoue*, J. Li, H. Tanaka, R. Ito, S. Ono, S. Kuroda, T. Takenobu*, “High Current Injection into Dynamic p–n Homojunction in Polymer Light-Emitting Electrochemical Cells”, Adv. Mater. 29, 1606392-1-7 (2017). DOI: https://doi.org/10.1002/adma.201606392
K. Kang, S. Watanabe, K. Broch, A. Sepe, A. Brown, I. Nasrallah, M. Nikolka, Z. Fei, M. Heeney, D. Matsumoto, K. Marumoto, H. Tanaka, S. Kuroda, and H. Sirringhaus*, “Two-Dimensional Coherent Charge Transport in Highly Ordered Conducting Polymers Doped by Solid State Diffusion”, Nat. Mater. 15, 896-902 (2016). DOI: https://doi.org/10.1038/nmat4634
T. Yoshida, S. Takaishi*, H. Iguchi, H. Okamoto, H. Tanaka, S. Kuroda, Y. Hosomi, S. Yoshida, H. Shigekawa, T. Kojima, H. Ohtsu, M. Kawano, B. K. Breedlove, L. Gué rin, and M. Yamashita*, “Optically visible phase separation between Mott-Hubbard and charge-density-wave domains in a Pd-Br chain complex”, ChemistrySelect 2, 259 –263 (2016). DOI: https://doi.org/10.1002/slct.201600065
H. Ito*, T. Harada, H. Tanaka, S. Kuroda, “Critical regime for the insulator-metal transition in highly-ordered conjugated polymers gated with ionic liquid”. Jpn. J. Appl. Phys. 55, 03DC08-1-5 (2016). DOI: https://doi.org/10.7567/jjap.55.03dc08
H. Tanaka*, S. Nishio, H. Ito, and S. Kuroda, “Microscopic signature of insulator-to-metal transition in highly-doped semicrystalline conducting polymers in ionic-liquid-gated transistors”, Appl. Phys. Lett. 107, 243302-1-5 (2015). DOI: https://doi.org/10.1063/1.4938137
H. Tanaka*, E. Sawada, K. Azuma, and S. Kuroda, “Direct probing of gate-bias stress effect in organic transistors by electron spin resonance spectroscopy”, Appl. Phys. Express 8, 051603-1-4 (2015). DOI: https://doi.org/10.7567/apex.8.051603
T. Harada, H. Ito*, Y. Ando, S. Watanabe, H. Tanaka and S. Kuroda, “Signature of the insulator-metal transition of a semicrystalline conjugated polymer in ionic-liquid-gated transistors”, Appl. Phys. Express 8, 021601-1-4 (2015). DOI: https://doi.org/10.7567/apex.8.021601
Y. Kinoshita, H. Tanaka*, Y. Shimoi, K. Takimiya, and S. Kuroda, “Low-temperature carrier dynamics in high-mobility organic transistors of alkylated dinaphtho-thienothiophene as investigated by electron spin resonance”, Appl. Phys. Lett. 105, 033301-1-5 (2014). DOI: https://doi.org/10.1063/1.4890962
S. Kumagai, S. Takaishi*, B. K. Breedlove, H. Okamoto, H. Tanaka, S. Kuroda, and M. Yamashita*, “Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature”, Chem. Commun. 50, 8382-8384 (2014). DOI: https://doi.org/10.1039/c4cc02547d
S. Takaishi*, H. Kitagawa, H. Tanaka, S. Kuroda, R. Ikeda, “Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(II) complex CuCl2(pdz) with a staggered g-tensor”, Dalton Trans. 43, 11529-11532 (2014). DOI: https://doi.org/10.1039/c4dt00809j
H. Tanaka*, M. Hirate, S. Watanabe, and S. Kuroda, “Microscopic Signature of Metallic State in Semicrystalline Conjugated Polymers Doped with Fluoroalkylsilane Molecules”, Adv. Mater. 26, 2376-2383 (2014). DOI: https://doi.org/10.1002/adma.201304691
H. Ito*, T. Tokai, J. Suzuki, H. Tanaka, and S. Kuroda, “Photocarrier Recombination of Polymer/Fullerene Composites in Surface-Type Photocells”, Jpn. J. Appl. Phys. 53, 01AB09-1-4 (2014). DOI: https://doi.org/10.7567/jjap.53.01ab09
H. Tanaka*, M. Hirate, S. Watanabe, K. Kaneko, K. Marumoto, T. Takenobu, Y. Iwasa, and S. Kuroda, “Electron spin resonance observation of charge carrier concentration in organic field-effect transistors during device operation”, Phys. Rev. B, 87, 045309-1-7 (2013). https://doi.org/10.1103/PhysRevB.87.045309
L. Pilia, E. Sessini, F. Artizzu, M. Yamashita, A. Serpe, K. Kubo, H. Ito, H. Tanaka, S. Kuroda, J. Yamada, P. Deplano, C. J. Gómez-García, and M. L. Mercuri*, “New BDH-TTP/[MIII(C5O5)3]3− (M = Fe, Ga) Isostructural Molecular Metals”, Inorg. Chem. 52, 423-430 (2012). DOI: https://doi.org/10.1021/ic302234j
S. Watanabe, H. Tanaka, S. Kuroda*, A. Toda, H. Tomikawa, S. Nagano, and T. Seki, “Charge transport anisotropy due to interfacial molecular orientation in polymeric transistors with controlled in-plane chain orientation”, Appl. Phys. Express 5, 021602-1-3 (2012). DOI: https://doi.org/10.1143/apex.5.021602
H. Tanaka*, S. Kuroda, H. Iguchi, S. Takaishi, and M. Yamashita, “Electron spin resonance observation of dehydration-induced spin excitations in quasi-one-dimensional iodo-bridged diplatinum complexes”, Phys. Rev. B 85, 073104-1-5 (2012). DOI: https://doi.org/10.1103/physrevb.87.045309
H. Ito*, Y. Nishikawa, J. Suzuki, A. Suzuki, S. Watanabe, H. Tanaka, H. Kishida, A. Nakamura, S. Kuroda, “Quadrimolecular Recombination of Persistent Photocarriers in Surface-Type Photocells of Regioregular Poly(3-hexylthiophene)/Methanofullerene Composites”, Jpn. J. Appl. Phys. 50, 091602-1-4 (2011). DOI: https://doi.org/10.1143/jjap.50.091602
H. Tanaka*, M. Kozuka, S. Watanabe, H. Ito, Y. Shimoi, K. Takimiya, S. Kuroda, “Observation of field-induced charge carriers in high-mobility organic transistors of a thienothiophene-based small molecule: Electron spin resonance measurements”, Phys. Rev. B 84, 081306-1-4 (R) (2011). DOI: https://doi.org/10.1103/PhysRevB.84.081306
M. Tsuji, N. Arai, K. Marumoto, J. Takeya, Y. Shimoi, H. Tanaka, S. Kuroda, T. Takenobu, Y. Iwasa, “Electron Spin Resonance Study of Interface Trap States and Charge Carrier Concentration in Rubrene Single-Crystal Field-Effect Transistors”, Appl. Phys. Express 4, 085702-1-3 (2011). DOI: https://doi.org/10.1143/apex.4.085702
S. Watanabe*, H. Tanaka, H. Ito, S. Kuroda, T. Mori, K. Marumoto and Y. Shimoi, “Direct determination of interfacial molecular orientations in field-effect devices of P3HT/PCBM composites by electron spin resonance”, Org. Electron. 12, 716-723 (2011). DOI: https://doi.org/10.1016/j.orgel.2011.01.024
K. Marumoto*, N. Arai, H. Goto, M. Kijima, K. Murakami, Y. Tominari, J. Takeya, Y. Shimoi, H. Tanaka, S. Kuroda, T. Kaji, T. Nishikawa, T. Takenobu and Y. Iwasa, “Microscopic mechanisms behind the high mobility in rubrene single-crystal transistors as revealed by field-induced electron spin resonance”, Phys. Rev. B 83(7), 075302-1-6 (2011). DOI: https://doi.org/10.1103/PhysRevB.83.075302
S. Watanabe*, H. Tanaka, S. Kuroda, A. Toda, S. Nagano, T. Seki, A. Kimoto, J. Abe, ”Electron spin resonance observation of field-induced charge carriers in ultrathin-film transistors of regioregular poly(3-hexylthiophene) with controlled in-plane chain orientation”, Appl. Phys. Lett. 96, 173302-1-3 (2010). DOI: https://doi.org/10.1063/1.3421538
H. Tanaka*, Y. Yokoi, N. Hasegawa, S. Kuroda, T. Iijima, T. Sato, T. Yamamoto, “Quadrimolecular recombination kinetics of photogenerated charge carriers in the composites of regioregular polythiophene derivatives and soluble fullerenes”, J. Appl. Phys. 107, 083708-1-9 (2010). DOI: https://doi.org/10.1063/1.3380839
H. Iguchi, S. Takaishi, H. Miyasaka, M. Yamashita*, H. Matsuzaki, H. Okamoto, H. Tanaka, and S. Kuroda, “Water-Vapor-Induced Reversible Switching of Electronic States in an MMX-Type Chain Complex with Retention of Single Crystallinity”, Angew. Chem. Int. Ed. 49, 552-555 (2010). DOI: https://doi.org/10.1002/ange.200905608
S. Kuroda*, S. Watanabe, K. Ito, H. Tanaka, H. Ito, K. Marumoto, “Electron spin resonance of charge carriers in organic field-effect devices”, Appl. Magn. Reson. 36, 357-370 (2009). DOI: https://doi.org/10.1007/s00723-009-0032-4
M. Sasaki, H. Wu, D. Kawakami, S. Takaishi, T. Kajiwara, H. Miyasaka, B. K. Breedlove, M. Yamashita*, H. Kishida, H. Matsuzaki, H. Okamoto, H. Tanaka, and S. Kuroda, ”Effect of an In-Plane Ligand on the Electronic Structures of Bromo-Bridged Nano-Wire Ni-Pd Mixed-Metal Complexes, [Ni1-xPdx(bn)2Br]Br2 (bn = 2S,3S-Diaminobutane)”, Inorg. Chem. 48, 7446-7451 (2009). DOI: https://doi.org/10.1063/1.3380839
H. Tanaka*, S. Watanabe, H. Ito, K. Marumoto, S. Kuroda, “Direct observation of the charge carrier concentration in organic field-effect transistors by electron spin resonance”, Appl. Phys. Lett. 94, 103308-1-3 (2009). DOI: https://doi.org/10.1063/1.3100193
H. Ito*, T. Ishihara, H. Tanaka, S. Kuroda, T. Suzuki, S. Onari, Y. Tanaka, J. Yamada, K. Kikuchi, "Roles of spin fluctuation and frustration in the superconductivity of b-(BDA-TTP)2X (X=SbF6 ,AsF6) under uniaxial compression”, Phys. Rev. B 78, 172506-1-4 (2008). DOI: https://doi.org/10.1103/physrevb.78.172506
S. Takaishi*, M. Takamura, T. Kajiwara, H. Miyasaka, M. Yamashita*, M. Iwata, H. Matsuzaki, H. Okamoto, H. Tanaka, S. Kuroda, H. Nishikawa, H. Oshio, K. Kato, M. Takata, “Charge-density-wave to Mott-Hubbard phase transition in quasi-one-dimensional bromo-bridged Pd compounds”, J. Am. Chem. Soc. 130, 12080-12084 (2008). DOI: https://doi.org/10.1021/ja8032026
H. Tanaka*, H. Nishiyama, S. Kuroda, T. Yamashita, M. Mitsumi, and K. Toriumi, ”ESR observations of optically generated solitons in the quasi-one-dimensional iodo-bridged diplatinum complex Pt2(n-pentylCS2)4I”, Phys. Rev. B 78 (3), 033104-1-4 (2008). DOI: https://doi.org/10.1103/physrevb.78.033104
J. Xie, H. Wu, D. Kawakami, H. Iguchi, S. Takaishi, M. Yamashita*, H. Matsuzaki, H. Okamoto, H. Tanaka, and S. Kuroda, “Electronic structure of CoIII doped bromo-bridged Ni complexes, [Ni1-xCox(chxn)2Br]Br2”, Inorg. Chem. 47, 1949-1952 (2008). DOI: https://doi.org/10.1021/ic7012232
S. Takaishi*, M. Yamashita*, H. Matsuzaki, H. Okamoto, H. Tanaka, S. Kuroda, A. Goto, T. Shimizu, T. Takenobu, and Y. Iwasa, ”One-Dimensional Bromo-Bridged NiIII complexes [Ni(S,S-bn)2Br]Br2 (S,S-bn=2S,3S-diaminobutane):Synthesis, Physical Properties, and Electrostatic Carrier Doping”, Chem. Eur. J. 14, 472-477 (2008). DOI: https://doi.org/10.1002/chem.200701299
S. Watanabe, K. Ito, H. Tanaka, H. Ito, K. Marumoto and S. Kuroda*, “Electron spin resonance observation of gate-induced charge carriers in organic field-effect devices fabricated on silicon substrates”, Jpn. J. Appl. Phys. 46, L792-L795 (2007). DOI: https://doi.org/10.1143/JJAP.46.L792
H. Tanaka*, N. Hasegawa, T. Sakamoto, K. Marumoto and S. Kuroda, “Light-Induced ESR Studies of Quadrimolecular Recombination Kinetics of Photogenerated Charge Carriers in Regioregular Poly(3-alkylthiophene)/C60 Composites –Alkyl Chain Dependence”, Jpn. J. Appl. Phys. 46, No.8A, 5187-5192 (2007). DOI: https://doi.org/10.1143/jjap.46.5187
H. Ito*, D. Suzuki, H. Watanabe, H. Tanaka, S. Kuroda, M. Umemiya, N. Kobayashi, M. Goto, K. Sugiura, H. Miyasaka, S. Takaishi, T. Kajiwara, M. Yamashita, E. Ohmichi, T. Osada, “Metal–insulator transition of charge transfer salts based on unsymmetrical donor DMET and metal halide anions, (DMET)4(MCl4)(TCE)2 (M = Mn, Co, Cu, Zn; TCE = 1,1,2-trichloroethane)”, J. Am. Chem. Soc.129, 8510-8518 (2007). DOI: https://doi.org/10.1021/ja070672q
H. Tanaka*, S. Kuroda, T. Yamashita, M. Mitsumi, and K. Toriumi, “ESR studies of the spin dynamics in quasi-one-dimensional iodo-bridged diplatinum complex Pt2(n-pentylCS2)4I”, Phys. Rev. B 73, 245102-1-12 (2006). DOI: https://doi.org/10.1103/physrevb.73.245102
S. Takaishi*, D. Kawakami, M. Yamashita*, M. Sasaki, T. Kajiwara, H. Miyasaka, K. Sugiura, Y. Wakabayashi, H. Sawa, H. Matsuzaki, H. Kishida, H. Okamoto, H. Watanabe, H. Tanaka, K. Marumoto, H. Ito, S. Kuroda, “Dynamical Valence Fluctuation at the Charge−Density−Wave Phase Boundary in Iodide-Bridged Pt Compound [Pt(chxn)2I]I2”, J. Am. Chem. Soc. 128, 6420-6425 (2006). DOI: https://doi.org/10.1021/ja060193b
H. Ito*, M. Hanada, H. Tanaka, S. Kuroda, M. Mitsumi, K. Toriumi, “Conduction Anisotropy of the Halogen-Bridged Metal Complex Pt2(n-butylCS2)4I”, J. Phys. Soc. Jpn. 74(12), 3334-3339 (2005). DOI: https://doi.org/10.1143/jpsj.74.3334
H. Ito*, Y. Yokochi, H. Tanaka, S. Kuroda, R. Kanehama, M. Umemiya, H. Miyasaka, K-I. Sugiura, M. Yamashita, H. Tajima, J. Yamaura, “Charge carriers in divalent BEDT-TTF conductor (BEDT-TTF)Cu2Br4” Phys. Rev. B 71, 085202-1-7 (2005). DOI: https://doi.org/10.1103/physrevb.71.085202
M. Mitsumi*, H. Goto, S. Umebayashi, Y. Ozawa, M. Kobayashi, T. Yokoyama, H. Tanaka, S. Kuroda, K. Toriumi*, “A neutral mixed-valent conducting polymer formed by electron transfer between metal d and ligand p orbitals” Angew. Chem. Int. Ed. 44, 4164-4168 (2005). DOI: https://doi.org/10.1002/ange.200501189
K. Marumoto*, H. Takahashi, H. Tanaka, S. Kuroda, T. Ishii, R. Kanehama, N. Aizawa and M. Yamashita, “Electron spin resonance studies of silver complexes of octaethylporphyrin cocrystallized with fullerenes: observation of triplet spin states due to magnetic dipolar interactions”, J. Phys.: Condensed Matter 16, 8753-8762 (2004). DOI: https://doi.org/10.1088/0953-8984/16/47/025
M. Yamashita*, D. Kawakami, S. Matsunaga, Y. Nakayama, M. Sasaki, S. Takaishi, F. Iwahori, H. Miyasaka, K. Sugiura, Y. Wada, H. Miyamae, H. Matsuzaki, H. Okamoto, H. Tanaka, K. Marumoto and S. Kuroda, “[{[Pt(en)2][PtX2(en)2]}3][{(MX5)X3}2]·12H2O: Quasi-one-dimensional halogen-bridged PtII-PtIV mixed-valence compounds with magnetic counter-anions”, Angew. Chem. Int. Ed. 43, 4763-4767 (2004). DOI: https://doi.org/10.1002/anie.200460580
S. Takaishi*, H. Miyasaka, K. Sugiura, M. Yamashita*, H. Matsuzaki, H. Kishida, H. Okamoto, H. Tanaka, K. Marumoto, H. Ito, S. Kuroda and T. Takami, “Visualization of local valence structures in quasi-one-dimensional halogen-bridged complexes [Ni1-xPdx(chxn)2Br]Br2 by STM”, Angew. Chem. Int. Ed. 43, 3171-3175 (2004). DOI: https://doi.org/10.1002/anie.200453905
M. Yamashita*, T. Ono, S. Matsunaga, M. Sasaki, S. Takaishi, F. Iwahori, H. Miyasaka, K.-i. Sugiura, H. Kishida, H. Okamoto, H. Tanaka, Y. Hasegawa, K. Marumoto, H. Ito, S. Kuroda, N. Kimura, "Carrier doping effect into quasi-one-dimensional bromo-bridged Ni(III) complexes with strong electron-correlation by Cu(II) ions, [Ni1-xCux(chxn)2Br]Br2-x", Inorg. Chem. Commun. 42, 7692-7694 (2003). DOI: https://doi.org/10.1021/ic0349555
H. Tanaka*, S. Kuroda, T. Yamashita, M. Mitsumi and K. Toriumi, “ESR observations of valence ordering states and thermally excited solitons in MMX complexes Pt2(RCS2)4I (R = n-Butyl and n-Pentyl)”, J. Phys. Soc. Jpn. 72, 2169-2172 (2003). DOI: https://doi.org/10.1143/JPSJ.72.2169
H. Ito*, Y. Hasegawa, H. Tanaka, S. Kuroda, M. Mitsumi and K. Toriumi, “Uniaxial compression of the Halogen-bridged binuclear metal complex Pt2(n-ButylCS2)4I”, J. Phys. Soc. Jpn. 72(9), 2149-2152 (2003). DOI: https://doi.org/10.1143/jpsj.72.2149
M. Yamashita*, H. Aso, S. Matsunaga, K. Takizawa, K. Nakata, C. Katchi-Terajima, F. Iwahori, T. Ishii, H. Miyasaka, K. Sugiura, T. Kawashima, K. Takai, N. Kuroda, M. Shiro, H. Kishida, H. Okamoto, H. Takahashi, H. Tanaka, K. Marumoto and S. Kuroda, “Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged PtII-PtIV mixed-valence compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4・12H2O”, Chem. Lett. 32, 278-279 (2003). DOI: https://doi.org/10.1246/cl.2003.278
H. Tanaka*, K. Marumoto, S. Kuroda, T. Manabe and M. Yamashita, “ESR detection of induced spin moments in halogen-bridged mixed-metal complexes Ni1-xPdx(chxn)2Br3”, J. Phys. Soc. Jpn. 71, 1370-1375 (2002). DOI: https://doi.org/10.1143/jpsj.71.1370
H. Tanaka*, K. Marumoto, S. Kuroda, T. Ishii, R. Kanehama, N. Aizawa, H. Matsuzaka, K. Sugiura, H. Miyasaka, T. Kodama, K. Kikuchi, I. Ikemoto and M. Yamashita, “Electron spin resonance studies of Co(tbp)・C60 single crystal”, J. Phys.: Condensed Matter 14, 3993-4000 (2002). DOI: https://doi.org/10.1088/0953-8984/14/15/313
M. Yamashita*, K. Yokoyama, S. Furukawa, T. Manabe, T. Ono, K. Nakata, C. Kachi-Terajima, F. Iwahori, T. Ishii, H. Miyasaka, K. Sugiura, H. Matsuzaki, H. Kishida, H. Okamoto, H. Tanaka, Y. Hasegawa, K. Marumoto, H. Ito and S. Kuroda, "Tuning of electronic structures of quasi-one-dimensional bromo-bridged Ni(Ⅲ) complexes with strong electron-correlation by doping of Co(Ⅲ) ions,[Ni1-xCox(chxn)2Br]Br2", Inorganic Chemistry 41, 1998-2000 (2002). DOI: https://doi.org/10.1021/ic011326r
T. Ishii*, R. Kanehama, N. Aizawa, M. Yamashita*, H. Matsuzaka, K. Sugiura, H. Miyasaka, T. Kodama, K. Kikuchi, I. Ikemoto, H. Tanaka, K. Marumoto and S. Kuroda, “Fullerene C60 exhibiting a strong intermolecular interaction in a cocrystallinte with C4 symmetrical cobalt tetrakis(di-tert-butylphenyl)porphyrin”, J. Chem. Soc., Dalton Trans. 20, 2975-2980 (2001). DOI: https://doi.org/10.1039/B104514H
K. Marumoto*, H. Tanaka, S. Kozaki, S. Kuroda, S. Miya, T. Kawashima and M. Yamashita, “ESR observation of averaged-valence and charge-density-wave states in quasi-one-dimensional halogen-bridged binuclear metal complexes”, Solid State Commun. 120, 101-106 (2001). DOI: https://doi.org/10.1016/s0038-1098(01)00334-9
K. Marumoto*, H. Tanaka, S. Kuroda, T. Manabe and M. Yamashita, “Induced spin moments in quasi-one-dimensional halogen-bridged mixed metal complexes of nickel and palladium”, Phys. Rev. B 60, 7699-7702 (1999). DOI: https://doi.org/10.1103/PhysRevB.60.7699
・国際会議プロシーディングス
S. Kawamura, A. Wakamatsu, S. Kuroda, T. Takenobu, and H. Tanaka*, “Microscopic observation of highly mobile charge carriers in organic transistors of semicrystalline conducting polymers”, Jpn. J. Appl. Phys. 57, 02CA04-1-4 (2018).DOI: https://doi.org/10.7567/JJAP.57.02CA04
S. Watanabe, H. Tanaka, H. Ito, K, Marumoto, S. Kuroda*, “ESR studies of ambipolar charge carriers in metal-insulator-semiconductor diodes of regioregular poly(3-hexylthiophene)/PCBM composites”, Synth. Met. 159, 893-896 (2009). DOI: https://doi.org/10.1016/j.synthmet.2009.01.050
H. Ito*, T. Ishihara, H. Tanaka, S. Kuroda, J. Yamada, “Uniaxial Compression on the Superconductivity of β-BDA-TTP Salts”, J. Phys.: Conference Series 132, 012012-1-7 (2008). DOI: https://doi.org/10.1088/1742-6596/132/1/012012
H. Tanaka*, T. Mizutani, S. Kuroda, “Control of formation and molecular orientation of J-aggregates in Langmuir–Blodgett films of mixed merocyanine dyes”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 284-285, 97-102 (2006). DOI: https://doi.org/10.1016/j.colsurfa.2005.10.057
H. Ito*, Y. Yokochi, D. Suzuki, H. Tanaka, S. Kuroda, K. Enomoto, S. Uji, M. Umemiya, H. Miyasaka, K. -i. Sugiura, and M. Yamashita, “Field-induced SDW phase and superconductivity of (DMET)2CuCl2” Synth. Met. 156, 162-165 (2006). DOI: https://doi.org/10.1016/j.synthmet.2005.12.001
H. Ito*, Y. Yokochi, H. Tanaka, S. Kuroda, R. Kanehama, M. Umemiya, H. Miyasaka, K. -i. Sugiura, M. Yamashita, “Electrical conduction in divalent BEDT-TTF salts” Synth. Met. 153, 441-444 (2005). DOI: https://doi.org/10.1016/j.synthmet.2005.07.326
H. Tanaka*, Y. Hasegawa, H. Ito, S. Kuroda, T. Yamashita, M. Mitsumi, and K. Toriumi, “Control of the electronic phase transition of the MMX-chain complex Pt2(n-pentylCS2)4I with the uniaxial compression”, Synth. Met. 152, 141-144 (2005). DOI: https://doi.org/10.1016/j.synthmet.2005.07.112
H. Tanaka*, K. Marumoto, S. Kuroda and M. Yamashita, “LESR studies of long-lived photogenerated spins in the MX-chain complex, Pd(chxn)2Br3”, Synth. Met. 135-136, 317-318 (2003). DOI: https://doi.org/10.1016/s0379-6779(02)00601-x
T. Ono, M. Yamashita*, K. Yokoyama, S. Furukawa, T. Manabe, K. Sugiura, T. Ishii, H. Miyasaka, H. Matsuzaki, H. Kishida, H. Okamoto, K. Marumoto, H. Tanaka, Y. Hasegawa, S. Kuroda, H. Ito, "Tuning of spin density wave strength of Ni(III) complexes with strong electron correlation", Synth. Met. 135-136, 357-358 (2003). DOI: https://doi.org/10.1016/s0379-6779(02)00567-2
H. Tanaka*, K. Marumoto, S. Kuroda, T. Manabe, S. Furukawa and M. Yamashita, “ESR studies of quasi-one-dimensional halogen-bridged mixed-metal complexes”, EPR in the 21st Century: Basics and Applications to Material, Life and Earth Sciences, eds. A. Kawamori, J. Yamauchi and H. Ohta (Elsevier, Amsterdam, 2002) 79-84.
T. Manabe, K. Yokoyama, T. Ishii, H. Miyasaka, H. Matsuzaka, M. Yamashita*, T. Kawashima, H. Matsuzaki, H. Kishida, H. Okamoto, K. Marumoto, H. Tanaka, H. Itoh and S. Kuroda, "Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexes, Ni1-xPdx(chxn)2ClyBr1-yY2", Mol. Cryst. Liq. Cryst. 376, 165-170 (2002). https://doi.org/10.1080/10587250210772
H. Tanaka*, K. Marumoto, S. Kuroda, T. Manabe and M. Yamashita, “ESR detection of induced moments Pd3+ in halogen-bridged Ni-Pd mixed-metal complexes”, Synth. Met. 120, 949-950 (2001). DOI: https://doi.org/10.1016/s0379-6779(00)00604-4
T. Manabe, T. Kawashima, T. Ishii, H. Matsuzaka, M. Yamashita*, K. Marumoto, H. Tanaka, S. Kuroda, H. Kitagawa, T. Mitani, H. Okamoto, “Syntheses and physical properties of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Cl3”, Synth. Met. 116(1-3), 415-418 (2001).DOI: https://doi.org/10.1016/s0379-6779(00)00449-5
T. Manabe, T. Ishii, H. Matsuzaka, M. Yamashita*, T. Kawashima, K. Marumoto, H. Tanaka, H. Ito, S. Kuroda, H. Okamoto, "Synthesis and physical properties of halogen-bridged Ni-Pd mixed-metal complexes, Ni1-xPdx(chxn)2XY2", Synth. Met. 120, 925-926 (2001). DOI: https://doi.org/10.1016/s0379-6779(00)01091-2
・解説
伊東 裕、田中 久暁、竹延 大志、「フレキシブル熱電デバイスの現状と展望」、応用物理, Vol.90 (7), 402-408 (2021).
田中久暁、竹延大志、「ウェアラブル熱電素子の実現に向けた導電性高分子の熱電物性解明」、機能材料, Vol.41 (3), 9-20 (2021).
田中久暁、竹延大志、「ウェアラブル電池の実現に向けた高分子熱電変換素子」、自動車技術, Vol.74 (9), 102-103 (2020).
田中久暁、竹延大志、「プラスチックを用いた熱電変換素子 -温度差を用いて発電するフレキシブルな電源の実現に向けて-」、クリーンエネルギー, 29 (7), 30-36 (2020).
田中久暁、「電子スピン共鳴法による擬一次元金属錯体および導電性高分子における素励起の研究」、電子スピンサイエンス、第10巻 春号(通号18)19-25 (2012).
・著書
田中久暁、竹延大志、「導電性高分子の熱電物性」、次世代熱電変換材料・モジュールの開発 ―熱電発電の黎明― 第Ⅱ編第2章5節 pp. 120-130、シーエムシー出版 2020年3月5日. ISBN: 978-4-7813-1492-1
黒田新一、伊東裕、田中久暁、丸本一弘、「ソリトン,ポーラロンによる共役ポリマーデバイスの機能発現とその制御」、次世代共役ポリマーの超階層制御と革新機能 第Ⅲ編第2章 pp 243-249、シーエムシー出版 2009年1月.
・外部資金等獲得実績
科学研究費補助金
基盤研究(B) R.7-9年度「π共役系高分子の集積構造制御による物性開発」(代表者)
基盤研究(B) R.4-6年度「導電性高分子の構造・物性制御による革新的電子機能の創出」(代表者)
学術変革領域(A)R.2-6年度「高密度共役キラル分子集積体における高効率電流-スピン流変換」(分担者) 代表:須田理行(領域名:「高密度共役の科学:電子共役概念の変革と電子物性をつなぐ」 計画研究A04班)
基盤研究(C) H.26-28年度「キャリア注入による高結晶性有機半導体薄膜の電子状態制御と機能開拓」(代表者)
基盤研究(B) H.25-27年度「高移動度を示す有機トランジスター中のキャリアの電子状態とダイナミクス」(分担者)代表:黒田新一
基盤研究(B) H.22-24年度「有機電界効果デバイス界面の電子・スピン機能とその制御」(分担者)代表:黒田新一
若手研究(B)H.21-22年度「擬一次元ハロゲン架橋金属錯体における分子修飾による電子相制御と機能開拓」(代表者)
基盤研究(B) H.17-19年度「有機デバイスにおける電界注入キャリアーの電子スピン共鳴による研究」(分担者)代表:黒田新一
若手研究(B)H.17-18年度「競合する電子相を有するハロゲン架橋金属錯体の光誘起電子スピン共鳴法による研究」(代表者)
その他外部資金
立松財団 2020年度 特別研究助成 R.2年度(3年間)「電子スピン共鳴法を用いたπ共役高分子の微視的電子機能解明」(代表者)
村田学術振興財団第36回研究助成 R.2年度「電解質ゲート法による導電性高分子の熱電変換機能発現とその最適化」(代表者)
池谷科学技術振興財団 単年度研究助成 R.2年度「ドナー・アクセプタ型高分子を用いた高性能熱電変換素子の開発」(代表者)
村田学術振興財団 第29回研究助成 H.25年度「電子スピン共鳴法による有機半導体デバイス界面における注入キャリアの微視的評価」(代表者)
立松財団研究助成 H.21年度「キャリアのミクロ観測に基づく有機電界効果トランジスタの特性評価と高機能化」(代表者)