Publications
2024
Hettiarrachchi, E.; Grassian, V.H. "Heterogeneous Reactions of Phenol on Different Components of Mineral Dust Aerosol: Formation of Oxidized Organic and Nitro-Phenolic Compounds" ACS ES&T Air 2024, 1, 4, 259-272
Deeleepojananan, C.; Zhou, J.; Grassian, V.H. "Heterogeneous Interactions and Transformations of Dibasic Esters with Indoor Relevant Surfaces" Environ. Sci.: Processes Impacts 2024, 26, 582-594
2023
Deeleepojananan, C.; Grassian, V.H. "Gas-Phase and Surface-Initiated Reactions of Household Bleach and Terpene-Containing Cleaning Products Yield Chlorination and Oxidation Products Adsorbed onto Indoor Relevant Surfaces" Environ. Sci. Tech. 2023, 57, 49, 20699–20707.
Li, M.; Boothby, C.; Continetti, R. E. and Grassian, V. H. “Size-Dependent Sigmoidal Reaction Kinetics for Pyruvic Acid Condensation at the Air-Water Interface in Aqueous Microdroplets” Journal of the American Chemical Society 2023, 145, 22317-22321.
Kim, P.; Boothby, C.; Grassian, V. H. and Continetti, R. E. “Photo-Induced Reactions of Nitrate in Aqueous Microdroplets by Triplet Energy Transfer” Journal of Physical Chemistry Letters 2023, 14, 10677−10684.
DeMott, P. J.; Hill, T. C. J.; Moore, K. A.; Perkins, R. J.; Mael, L. E.; Busse, H. L.; Lee, H.; Kaluarachchie, C. P.; Mayer, K. J.; Sauer, J. S.; Mitt, B. A.; Tivanski, A. V.; Grassian, V. H.; Cappa, C. C.; Bertram, T. H.; Prather, K. A. “Atmospheric Oxidation Impact on Sea Spray Produced Ice Nucleating Particles” Environmental Science:Atmospheres 2023, 3, 1513-1532
Kim, D.; Townsley, S.; Grassian, V. H. “Vibrational Spectroscopy as a Probe of the Heterogeneities in Geochemical Thin Films and Single Particles on Macro, Micro and Nanoscales” RSC Advances 2023, 13, 28873 – 28884.
Li, J.; Link, M.; Pandit, S.; Webb, M., Mayer, K.; Garofalo, L.; Rediger, K.; Poppendieck, D.; Zimmerman, S.; Vance, M.E.; Grassian, V. H.; Morrison, G.C.; Turpin, B.J.; Farmer, D.K. “The Persistence of Smoke VOCs Indoors: Partitioning, Surface Cleaning, and Air Cleaning in a Smoke-Contaminated House”Science Advances 2023, 9, eadh8263.
Sit, I.; Young, M. A. Kubicki, J. and Grassian, V. H “Distinguishing Different Surface Interactions for Nucleotides Adsorbed onto Hematite and Goethite Particle Surfaces Through ATR-FTIR Spectroscopy and DFT Calculations” Physical Chemistry Chemical Physics 2023, 25, 20557 – 20566
Sit, I.; Fashina, B. T.; Baldo, A. P.; Leung, K.; Grassian, V. H.; Ilgen, A. “Formic and Acetic Acid pKa Values Increase Under Nanoconfinement” RSC Advances 2023, 13, 23147 – 23157
Karimova, K.; Alija, O.; Mora Garcia, S.; Grassian, V. H.; Gerber, R. B. and Navea, J. G. “pH Dependence of the Speciation and Optical Properties of 4-Benzoylbenzoic Acid” Physical Chemistry Chemical Physics 2023, 25, 17306-17319
Miller, K. L.; Sit, I.; Xiang, Y.; Wu, J.; Pustelnik, J.; Tang, M.; Kiratitanaporn, W.; Grassian, V. H.; Chen, S. “Evaluation of CuO Nanoparticle Toxicity on 3D Bioprinted Human iPSC-derived Cardiac Tissues” Bioprinting 2023, e00284, 1-10
Angle, K.J.; Grassian, V.H.; Direct quantification of changes in pH within single levitated microdroplets and the kinetics of nitrate and chloride depletion. Chem. Sci., 2023,14, 6259-6268. DOI: 10.1039/D2SC06994F
Dommer, A.C.; Wauer, N.A.; Angle, K.J.; Davasam, A.; Rubiro, P.; Luo, M.; Morris, C.K.; Prather, K.A., Grassian, V.H.; Amaro, R.E. Revealing the Impacts of Chemical Complexity on Submicrometer Sea Spray Aerosol Morphology. ACS Cent. Sci. 2023, 9, 6, 1088–1103. DOI: 10.1021/acscentsci.3c00184
Hettiarachchi, E.; Grassian, V. H. Heterogeneous Chemistry of Methyl Ethyl Ketone on Mineral Oxide Surfaces: Impacts of Relative Humidity and Nitrogen Dioxide on Product Formation. Environ. Sci.: Atmos. 2023, 3, 799-815. DOI: 10.1039.D3EA00023K
Leobardo Bañuelos, J.; Borguet,E.; Brown, G. E. Jr.; Cyan, R.T.; DeYoreo, J. J.; Dove, P. M.; Gaigeot, M.-P.; Geiger, F. M.; Gibbs, J. M.; Grassian, V. H.; Ilgen, A. G.; Jun, Y.-S.; Kabengi, N.; Katz, L.; Kubicki, J. D.; Lützenkirchen, J.; Putnis, C. V.; Remsing, R. C.; Rosso, K. M.; Rother, G.; Sulpizi, M.; Villalobos, M.; Zhang, H. “Oxide- and Silicate-Water Interfaces and Their Roles in Technology and the Environment” Chemical Reviews 2023, 123, 6413−6544
Kim, D.; Grassian, V. H. Analysis of Micro- and Nanoscale Heterogeneities within Environmentally Relevant Thin Films Containing Biological Components, Oxyanions and Minerals Using AFM-PTIR Spectroscopy. Environ. Sci.: Processes Impacts 2023, 25, 484 – 495. DOI: 10.1039/D3EM00005B.
Angle, K. J.; Nowak, C. M.; Grassian, V. H. Organic Acid Evaporation Kinetics from Aqueous Aerosols: Implications for Aerosol Buffering Capacity in the Atmosphere. Environ. Sci.: Atmos. 2023, 3, 316–327. DOI: 10.1039/D2EA00092J.
Frank, E. S.; Fan, H.; Grassian, V. H.; Tobias, D. J. Adsorption of 6-MHO on Two Indoor Relevant Surface Materials: SiO 2 and TiO 2. Phys. Chem. Chem. Phys. 2023, 25, 3930–3941. DOI: 10.1039/D2CP04876K.
2022
Fan, H.; Lakey, P. S. J.; Frank, E. S.; Tobias, D. J.; Shiraiwa, M.; Grassian, V. H. Comparison of the Adsorption–Desorption Kinetics of Limonene and Carvone on TiO 2 and SiO 2 Surfaces under Different Relative Humidity Conditions. J. Phys. Chem. C 2022. 126, 50, 21253–21262. DOI: 10.1021/acs.jpcc.2c06853.
Alves, M. R.; Deeleepojananan, C.; Or, V. W.; Sit, I.; Grassian, V. H. Insights into Interactions of Chlorine-Based Cleaning Products with Indoor Relevant Surfaces. Environ. Chem. 2022. 19, 6, 343-349 . DOI: 10.1071/EN22031.
Hettiarachchi, E.; Grassian, V. H. Heterogeneous Formation of Organonitrates (ON) and Nitroxy-Organosulfates (NOS) from Adsorbed α-Pinene-Derived Organosulfates (OS) on Mineral Surfaces. ACS Earth Space Chem. 2022, 6, 12, 3017–3030. DOI: 10.1021/acsearthspacechem.2c00259.
Sit, I.; Quirk, E.; Hettiarachchi, E.; Grassian, V. H. Differential Surface Interactions and Surface Templating of Nucleotides (DGMP, DCMP, DAMP, and DTMP) on Oxide Particle Surfaces. Langmuir 2022 DOI: 10.1021/acs.langmuir.2c01604.
Alves, M. R.; Coward, E. K.; Gonzales, D.; Dang, D.; Sauer, J. S.; Mayer, K.; Prather, K. A.; Grassian, V. H. “Changes in Light Absorption and Composition of Marine- Chromophoric Marine-Dissolved Organic Matter Across a Microbial Bloom” Environmental Science: Processes and Impacts 2022, 24, 1923 - 1933
Kaluarachchi, C. P.; Or, V. W.; Lan, Y.; Hasenecz, E. S.; Kim, D.; Madawala, C. K.; Dorcé, G. P.; Mayer, K. J.; Sauer, J. S.; Lee, C.; Cappa, C. D.; Bertram, T. H.; Stone, E. A.; Prather, K. A.; Grassian, V. H.; Tivanski, A. V. Effects of Atmospheric Aging Processes on Nascent Sea Spray Aerosol Physicochemical Properties. ACS Earth Space Chem. 2022 DOI: 10.1021/acsearthspacechem.2c00258.
H. Fan, E. Frank, D. Tobias, V. Grassian. "Interactions of limonene and carvone on titanium dioxide surfaces" Phys. Chem. Chem. Phys. 2022 DOI: 10.1039/D2CP03021G
E. Coward, K. Seech, M. Carter, R. Flick, V. Grassian. "Of Sea and Smoke: Evidence of Marine Dissolved Organic Matter Deposition from 2020 Western United States Wildfires" Environ. Sci. Technol. Lett. 2022 DOI: 10.1021/acs.estlett.2c00383
S. Pandit, V. Grassian. "Gas-Phase Nitrous Acid (HONO) Is Controlled by Surface Interactions of Adsorbed Nitrite (NO2–) on Common Indoor Material Surfaces" Environ. Sci. Technol. 2022 DOI: 10.1021/acs.est.2c02042
R. Habre, D. Dorman, J. Abbatt, W. Bahnfleth, E. Carter, D. Farmer, G. Gawne-Mittelstaedt, A. Goldstein, V. Grassian, G. Morrison, J. Peccia, D. Poppendieck, K. Prather, M. Shiraiwa, H. Stapleton, M. Williams, M. Harries. "Why Indoor Chemistry Matters: A National Academies Consensus Report" Environ. Sci. Technol.2022 DOI: 10.1021/acs.est.2c04163
V. Grassian. "Physical Chemistry of Environmental Interfaces and the Environment in Physical Chemistry─A Career Perspective" J. Phys. Chem. C. 2022 DOI: 10.1021/acs.jpcc.2c04100
E. Hettiarachchi, V. Grassian. "Heterogeneous Reactions of α-Pinene on Mineral Surfaces: Formation of Organonitrates and α-Pinene Oxidation Products" J. Phys. Chem. A. 2022 DOI: 10.1021/acs.jpca.2c02663
Y. Mantri, I. Sit, J. Zhou, V. Grassian, J. Jokerst. "Photoacoustic Enhancement of Ferricyanide-Treated Silver Chalcogenide-Coated Gold Nanorods" J. Phys. Chem. C. 2022 DOI: 10.1021/acs.jpcc.2c01727
J. Abbatt, G. Morrison, V. Grassian, M. Shiraiwa, C. Weschler, P. Ziemann."How should we define an indoor surface?" Indoor Air. 2022, 32, DOI: 10.1111/ina.12955
H. Fan, E. Frank, P. Lakey, M. Shiraiwa, D. Tobias, V. Grassian. "Heterogeneous Interactions between Carvone and Hydroxylated SiO2" J. Phys. Chem. C. 2022 DOI: 10.1021/acs.jpcc.2c00815
K. Angle, C. Nowak, A. Davasam, A. Dommer, N. Wauer, R. Amaro, V. Grassian. "Amino Acids Are Driven to the Interface by Salts and Acidic Environments" J. Phys. Chem. Lett. 2022 DOI: 10.1021/acs.jpclett.2c00231
V. Or, M. Alves, M. Wade, S. Schwab, R. Corsi, V. Grassian. "Nanoscopic Study of Water Uptake on Glass Surfaces with Organic Thin Films and Particles from Exposure to Indoor Cooking Activities: Comparison to Model Systems" Environ. Sci. Technol. 2022 DOI: 10.1021/acs.est.1c06260
J. Sauer, K. Mayer, C. Lee, M. Alves, S. Amiri, C. Bahaveolos, E. Barnes, D. Crocker, J. Dinasquet, L. Garofalo, C. Kaluarachchi, D. Dang, D. Kilgour, L. Mael, B. Mitts, D. Moon, C. Morris, A. Moore, C. Ni, M. Pendergraft, D. Petras, R. Simpson, S. Smith, P. Tumminello, J. Walker, P. DeMott, D. Farmer, A. Goldstein, V. Grassian, J. Jaffe, F. Malfatti, T. Martz, J. Slade, A. Tivanski, T. Bertram, C. Cappa, K. Prather "The Sea Spray Chemistry and Particle Evolution Study (SeaSCAPE): Overview and Experimental Methods" Environ. Sci. Proc. Imp. 2021 DOI: 10.1039/D1EM00260K
A. Rose, E. Hettiarachchi, V. Grassian. "Monoethanolamine Adsorption on Oxide Surfaces" J. Colloid Interface Sci. 2022 DOI: 10.1016/j.jcis.2022.01.059
N. Karimova, M. Luo, I. Sit, V. Grassian, R. Gerber. "Absorption Spectra and the Electronic Structure of Gallic Acid in Water at Different pH: Experimental Data and Theoretical Cluster Models" J. Phys. Chem. A. 2022 DOI: 10.1021/acs.jpca.1c07333
K. Angle, V. Grassian, A. Ault. "The rapid acidification of sea spray aerosols" Phys. Today 2022 DOI: 10.1063/PT.3.4926
2021
D. Kim, V. Grassian. "Attenuated Total Reflection-Fourier Transform Infrared and Atomic Force Microscopy-Infrared Spectroscopic Investigation of Suwannee River Fulvic Acid and Its Interactions with α-FeOOH" ACS Earth Space Chem. 2021 DOI: 10.1021/acsearthspacechem.1c00288
Kaluarachchi, C. P.; Or, V. W.; Lan, Y.; Madawala, C.; Hasenecz, E. S.; Crocer, D. R.; Morris, C. K.; Lee, H. D.; Mayer, K. J.; Sauer, J. S.; Lee, C.; Malfatti, F.; Stone, E. A.; Bertram, T. H.; Cappa, C. D.; Grassian, V. H.; Prather, K. A.; Tivanski, A. “Size-Dependent Morphology, Composition, Phase State, and Water Uptake of Nascent Submicrometer Sea Spray Aerosols During a Phytoplankton Bloom” ACS Earth & Space Chemistry 2022, 6, 116–130
L. Mael, G. Peiker, H. Busse, V. Grassian. "Temperature-Dependent Liquid Water Structure for Individual Micron-Sized, Supercooled Aqueous Droplets with Inclusions" J. Phys. Chem. A. 2021 DOI: 10.1021/acs.jpca.1c08331
E. Franklin, M. Alves, A. Moore, D. Kilgour, G. Novak, K. Mayer, J. Sauer, R. Weber, D. Dang, M. Winter, C. Lee, C. Cappa, T. Bertram, K. Prather, V. Grassian, A. Goldstein "Atmospheric Benzothiazoles in a Coastal Marine Environment" Environ. Sci. Technol. 2021 DOI: 10.1021/acs.est.1c04422
S. Mora Garcia, S. Pandit, J. Navea, V. Grassian. "Nitrous Acid (HONO) Formation from the Irradiation of Aqueous Nitrate Solutions in the Presence of Marine Chromophoric Dissolved Organic Matter: Comparison to Other Organic Photosensitizers" ACS Earth Space Chem. 2021 DOI: 10.1021/acsearthspacechem.1c00292
L. Mael, H. Busse, G. Peiker, V. Grassian. "Low-Temperature Water Uptake of Individual Marine and Biologically Relevant Atmospheric Particles Using Micro-Raman Spectroscopy" J. Phys. Chem. A. 2021 DOI: 10.1021/acs.jpca.1c08037
I. Ustunol, E. Coward, E. Quirk, V. Grassian. "Interaction of beta-lactoglobulin and bovine serum albumin with iron oxide (α-Fe2O3) nanoparticles in the presence and absence of pre-adsorbed phosphate" Environ. Sci: Nano 2021 DOI: 10.1039/D1EN00388G
P. Roy, L. Mael, T. Hill, L. Mehndiratta, G. Peiker, M. House, P. DeMott, V. Grassian, C. Dutcher "Ice Nucleating Activity and Residual Particle Morphology of Bulk Seawater and Sea Surface Microlayer" ACS Earth Space Chem. 2021 DOI: 10.1021/acsearthspacechem.1c00175
K. Angle, E. Neal, V. Grassian "Enhanced Rates of Transition-Metal-Ion-Catalyzed Oxidation of S(IV) in Aqueous Aerosols: Insights into Sulfate Aerosol Formation in the Atmosphere" Environ. Sci. Technol.2021 DOI: 10.1021/acs.est.1c01932
S. Pandit, S. Mora Garcia, V. Grassian "HONO Production from Gypsum Surfaces Following Exposure to NO2 and HNO3: Roles of Relative Humidity and Light Source" Environ. Sci. Technol. 2021 DOI: 10.1021/acs.est.1c01359
C. Lee, A. Dommer, J. Schiffer, R. Amaro, V. Grassian, K. Prather "Cation-Driven Lipopolysaccharide Morphological Changes Impact Heterogeneous Reactions of Nitric Acid with Sea Spray Aerosol Particles" J. Phys. Chem. Lett. 2021 DOI: 10.1021/acs.jpclett.1c00810
L. Huang, E. Frank, M. Shrestha, S. Riahi, D. Tobias, V. Grassian "Heterogeneous Interactions of Prevalent Indoor Oxygenated Organic Compounds on Hydroxylated SiO2 Surfaces" Environmental Science & Technology 2021 DOI: 10.1021/acs.est.1c00067
N. Karimova, M. Alves, M. Luo, V. Grassian, R. Gerber. "Toward a Microscopic Model of Light Absorbing Dissolved Organic Compounds in Aqueous Environments: Theoretical and Experimental Study" Physical Chemistry Chemical Physics 2021 DOI: 10.1039/D0CP06554D
O’Brien, R. E.; Li, Y.; Kiland, K. J.; Katz, E. F.; Or, V. W.; Legaard, E.; Walhout, E. Q.; Thrasher, C.; Grassian, V. H.; DeCarlo, P. F.; Bertram, A. K.; Shiraiwa, M. “Chemical and Physical Properties of Organic Mixtures on Indoor Surfaces During HOMEChem” Environmental Science: Processes & Impacts 2021, 23, 559-568.
L. Huang, E. Frank, S. Riahi, D. Tobias, V. Grassian. “Adsorption of Constitutional Isomers of Cyclic Monoterpenes on Hydroxylated Silica Surfaces”Journal of Chemical Physics 2021. DOI: 10.1063/5.0042467
H. Alalwan, L. Augustine, B. Hudson, J. Abeysinghe, E. Gillan, S. Mason, V. Grassian, D. Cwiertny. "Linking Solid-State Reduction Mechanisms to Size-Dependent Reactivity of Metal Oxide Oxygen Carriers for Chemical Looping Combustion" ACS Applied Energy Materials 2021. DOI: 10.1021/acsaem.0c02029
I. Sit, H. Wu, V. Grassian. "Environmental Aspects of Oxide Nanoparticles: Probing Oxide Nanoparticle Surface Processes Under Different Environmental Conditions " Annual Review of Analytical Chemistry, 2021 DOI: 10.1146/annurev-anchem-091420-092928
Boatenga, L. K.; Wu, H.; Mirshahghassemi, S.; Grassian, V. H.; Flora, J. R. V.; Lead, J. R. “Mechanistic Study of Oil Adsorption onto PVP-Coated Nanoparticles: An Integrated Experimental and Molecular Dynamics Study” Environmental Science:Nano 2021, 8, 485 – 492
K. Angle, D. Crocker, R. Simpson, K. Mayer, L. Garofalo, A. Moore, S. Mora Garcia, V. Or, S. Srinivasan, M. Farhan, J. Sauer, C. Lee, M. Pothier, D. Farmer, T. Martz, T. Bertram, C. Cappa, K. Prather, V. Grassian. "Acidity Across the Interface from the Ocean Surface to Sea Spray Aerosol" Proceedings of the National Academy of Sciences USA 2021 DOI: 10.1073/pnas.2018397118
2020
Wu, H.; Calzada, S.; Or, V.; Grassian, V. H. “Transformations of CuS Nanoparticles in Humid Environments: Relative Humidity Dependence of the Oxidation of CuS to CuSO4” Nanoscale 2020, 12, 19350 –19358.
H. Wu, V. Or, S. Gonzalez-Calzada, V. Grassian. "CuS nanoparticles in humid environments: adsorbed water enhances the transformation of CuS to CuSO4" Nanoscale 2020 DOI: 10.1039/D0NR05934J
L. Boateng, S. Mirshahghassemi, H. Wu, J. Flora, V. Grassian, J. Lead. "Mechanistic study of oil adsorption onto PVP-coated magnetic nanoparticles: An integrated experimental and molecular dynamics study to inform remediation" Environmental Science: Nano 2020 DOI: 10.1039/D0EN00907E
H. Wu, L. Huang, A. Rose, V. Grassian. "Impact of surface adsorbed biologically and environmentally relevant coatings on TiO2 nanoparticle reactivity" Environmental Science: Nano 2020 DOI: 10.1039/D0EN00706D
E. Frank, H. Fan, M. Shrestha, S. Riahi, D. Tobias, V. Grassian. "Impact of Adsorbed Water on the Interaction of Limonene with Hydroxylated SiO2: Implications of π‑Hydrogen Bonding for Surfaces in Humid Environments" Journal of Physical Chemistry A 2020 DOI: 10.1021/acs.jpca.0c08600
I. Sit, S. Sagisaka, V. Grassian. “Nucleotide Adsorption on Iron (III) Oxide Nanoparticle Surfaces: Insights into Nano-Geo-Bio Interactions Through Vibrational Spectroscopy” Langmuir 2020 DOI: 10.1021/acs.langmuir.0c02633
Liu, Y.; Bé, A. G.; Or, V. W.; Alves, M. R.; Grassian, V. H.; Geiger, F. M. “Indoor Surface Chemistry and Physics: Challenges and Opportunities” Cell Reports Physical Science, 2020, 1, article no. 100256, 1 – 17.
Y Liu, A. Be, V. Or, M. Alves, V. Grassian, F. Geiger. "Challenges and Opportunities in Molecular-Level Indoor Surface Chemistry and Physics" Cell Reports Physical Science 2020 DOI: 10.1016/j.xcrp.2020.100256
L. Huang, T. Liu, V. Grassian. "Radical-Initiated Formation of Aromatic Organosulfates and Sulfonates in the Aqueous Phase" Environmental Science and Technology 2020 DOI: 10.1021/acs.est.0c05644
A. Ault, V. Grassian, N. Carslaw, D. Collins, H. Destaillats, D. Donaldson, D. Farmer, J. Jiminez, V. McNeill, G. Morrison, R. O'Brien, M. Shiraiwa, M. Vance, J. Wells, W. Xiong. "Indoor Surface Chemistry: Developing a Molecular Picture of Reactions on Indoor Interfaces" Chem 2020 DOI: 10.1016/j.chempr.2020.08.023
P. Roy, L. Mael, I. Makhnenko, R. Martz, V. Grassian, C. Dutcher. "Temperature-Dependent Phase Transitions of Aqueous Aerosol Droplet Systems in Microfluidic Traps" ACS Earth and Space Chemistry 2020 DOI: 10.1021/acsearthspacechem.0c00114
S. Larsen, R. Larsen, V. Grassian. "Building Bridges between Sustainability and Chemistry in Education and Outreach" Chemistry Education for a Sustainable Society Vol. 1 Ch. 4 2020 DOI: 10.1021/bk-2020-1344.ch004
H. Lee, S. Wigley, C. Lee, V. Or, E. Hasenecz, E. Stone, V. Grassian, K. Prather, A. Tivanski. "Physicochemical Mixing State of Sea Spray Aerosols: Morphologies Exhibit Size Dependence" ACS Earth and Space Chemistry 2020 DOI: 10.1021/acsearthspacechem.0c00153
M. Luo, N. Wauer, K. Angle, A. Dommer, M. Song, C. Nowack, R. Amaro, V. Grassian. "Insights into the Behavior of Nonanoic Acid and Its Conjugate Base at the Air/Water Interface Through a Combined Experimental and Theoretical Approach" Chemical Science 2020 DOI: https://doi.org/10.1039/D0SC02354J
M. Luo, D. Shemesh, M. Sullivan, M. Alves, M. Song, R. Gerber, V. Grassian. "The Impact of pH and NaCl and CaCl2 Salts on the Speciation and Photochemistry of Pyruvic Acid in the Aqueous Phase" Journal of Physical Chemistry A 2020 DOI: 10.1021/acs.jpca.0c01016
M. Alves, J. Sauer, K. Prather, V. Grassian, C. Wilkins. "Liquid Sampling-Atmospheric Pressure Glow Discharge Ionization as a Technique for the Characterization of Salt-Containing Organic Samples" Analytical Chemistry 2020 DOI: 10.1021/acs.analchem.0c00361
D. Shemesh, M. Luo, V. Grassian, R. Gerber. "Absorption Spectra of Pyruvic Acid in Water: Insights from Calculations for Small Hydrates and Comparison to Experiment" Physical Chemistry Chemical Physics 2020 DOI: 10.1039/D0CP01810D
H. Lee, H. Morris, O. Laskina, C. Sultana, C. Lee, T. Jayarathne, J. Cox, X. Wang, E. Hascencz, P. DeMott, T. Bertram, C. Cappa, E. Stone, K. Prather, V. Grassian, A. Tivanksi. "Organic Enrichment, Physical Phase State, and Surface Tension Depression of Nascent Core-Shell Sea Spray Aerosols During Two Phytoplankton Blooms" ACS Earth Space Chem 2020 DOI: 10.1021/acsearthspacechem.0c00032
V. W. Or, M. Wade, S. Patel, M. R. Alves, D. Kim, S. Schwab, H. Przelomski, R. O'Brien, D. Rim, R. L. Corsi, M. E. Vance, D. K. Farmer, V. H. Grassian . "Glass surface evolution following gas adsorption and particle deposition from indoor cooking events as probed by microspectroscopic analysis" Environmental Science: Processes & Impacts. 2020 DOI:10.1039/D0EM00156B
N. Karimova, M. Luo, V. H. Grassian, R. B. Gerber. "Absorption Spectra of Benzoic Acid in Water at Different pH and in the Presence of Salts: Insights from the Integration of Experimental Data and Theoretical Cluster Models". Phys. Chem. Chem. Phys. 2020 DOI: 10.1039/C9CP06728K
2019
Y Li, M Shrestha, M. Luo, I. Sit, M. Song, V. H. Grassian, W. Xiong. "Salting Up of Proteins at the Air/Water Interface". Langmuir 2019 DOI: 10.1021/acs.langmuir.9b01901
L. Huang, E. Coddens, V. H. Grassian. "Formation of Organosulfur Compounds from Aqueous Phase Reactions of S(IV) with Methacrolein and Methyl Vinyl Ketone in the Presence of Transition Metal Ions". ACS Earth and Space Chemistry 2019 DOI: 10.1021/acsearthspacechem.9b00173
J. V. Trueblood, X. Wang, V. Or, M. R. Alves, M. V. Santander, K. A. Prather, V. H. Grassian. "The Old and the New: Aging of Sea Spray Aerosols and Formation of Secondary Marine Aerosol Through OH Oxidation Reactions". ACS Earth and Space Chemistry 2019 DOI: 10.1021/acsearthspacechem.9b00087
M. R. Alves, Y. Fang, K. J. Wall, V. Vaida, V. H. Grassian. "Chemistry and Photochemistry of Pyruvic Acid Adsorbed on Oxide Surfaces". Journal of Physical Chemistry A 2019 DOI: 10.1021/acs.jpca.9b06563
T. I. S. McCollom, L. V. Stebounova, J. H. Park, V. H. Grassian, N. I. Gonzalez-Pech, T. M. Peters. "Design and evaluation of a high-flowrate nanoparticle respiratory deposition (NRD) sampler". Journal of Aerosol Science 2019 DOI: 10.1016/j.jaerosci.2019.04.019
V. H. Grassian. "Physical Chemistry of Environmental Interfaces: Aerosols, Nanomaterials & Indoor Surfaces". The Chemist 2019 91 (2) ISSN: 1945-0702
L. E. Mael, H. Busse, V. H. Grassian. "Measurement of Immersion Freezing and Heterogeneous Chemistry of Atmospherically Relevant Single Particles with Micro-Raman Spectroscopy". Analytical Chemistry 2019. DOI: 10.1021/acs.analchem.9b01819
D. K. Farmer, M. E. Vance, J. P. D. Abbatt, A. Abeleira, M. R. Alves, C. Arata, E. Boedicker, S. Bourne, F. Cardoso-Saladaña, R Corsi, P. F. DeCarlo, A. H. Goldstein, V. H. Grassian, L. Hildebrandt Ruiz, J. L. Jimenez, T. F. Kahan, E. F. Katz, J. M. Mattila, W. W. Nazaroff, A. Novoselac, R. E. O'Brien, V. W. Or, S. Patel, S. Sankhyan, P. S. Stevens, Y. Tian, M. Wade, C. Wang, S. Zhou, Y. Zhou. "Overview of HOMEChem: House Observations of Microbial and Environmental Chemistry". Environmental Science: Processes & Impacts 2019. DOI: 10.1039/C9EM00228F
E. M. Coddens, K. J. Angle, V. H. Grassian. "Titration of Aerosol pH Through Droplet Coalescence" Journal of Physical Chemistry Letters 2019. DOI: 10.1021/acs.jpclett.9b00757
I.B. Ustunol, N.I. Gonzalez-Pech, V.H. Grassian. "pH-Dependent Adsorption of α-Amino Acids, Lysine, Glutamic Acid, Serine and Glycine, on TiO2 Nanoparticle Surfaces" Journal of Colloid and Interface Science, 2019. DOI: 10.1016/j.jcis.2019.06.086
I. Sit, Z. Xu, V. H. Grassian. "Plasma Protein Adsorption on TiO2 Nanoparticles: Impact of Surface Adsorption on Temperature-Dependent Structural Changes". Polyhedron, 2019. DOI: 10.1016/j.poly.2019.06.036
Z. Wang, T. Wang, H. Fu, L. Zhang, M. Tang, C. George, V. H. Grassian, J. Chen. "Enhanced heterogeneous uptake of sulfur dioxide on mineral particles through modification of iron speciation during simulated cloud processing". Atmospheric Chemistry and Physics, 2019. DOI: 10.5194/acp-2019-435
M. Luo, A. Dommer, J. M. Schiffer, D. J. Rez, A. Mitchell, R. E. Amaro, V. H. Grassian. "Surfactant Charge Modulates Structure and Stability of Lipase-Embedded Monolayers at Marine-Relevant Aerosol Surfaces". Langmuir, 2019. DOI: 10.1021/acs.langmuir.9b00689
F. Chen, E. R. Zhao, G. Hableel, T. Hu, T. Kim, J. Li, N. I. Gonzalez-Pech, D. J. Cheng, J. E. Lemaster, Y. Xie, V. H. Grassian, G. L. Sen, J. V. Jokerst. "Increasing the Efficacy of Stem Cell Therapy via Triple-Function Inorganic Nanoparticles", ACS Nano, 2019. DOI: 10.1021/acsnano.9b00653
J. Trueblood, M. Alves, D. Power, M. V. Santander, R. E. Cochran, K. A. Prather, V. H. Grassian. "Shedding Light on Photosensitized Reactions within Marine-Relevant Organic Thin Films", ACS Earth and Space Chemistry, 2019. DOI: 10.1021/acsearthspacechem.9b00066
Bennett, J.; Huang, X.; Fang, Y.; Cwiertny, D.; Grassian, V. H.; Mason, S. “Methane Dissociation on α-Fe2O3 (0001) and Fe3O4 (111) Surfaces: First-Principles Insights into Chemical Looping Combustion” Journal of Physical Chemistry C 2019, 23, 6450-6463. DOI: doi.org/10.1021/acs.jpcc.8b08675
Malfatti, F.; Lee, C.; Tinta, T.; Pendergraft, M.; Celussi, M.; Zhou, Y.; Sultana, C.; Rotter, A.; Axson, J.; Collins, D.; Santander, M.; Anides Morales, A.; Aluwihare, L.; Riemer, N.; Grassian, V. H.; Farooq, A.; Prather, K. “Detection of Active Microbial Enzymes in Nascent Sea Spray Aerosol: Implications for Atmospheric Chemistry and Climate” Environmental Science & Technology Letters 2019, 6, 171–177. DOI: doi.org/10.1021/acs.estlett.8b00699
McCollom, T. I; Stebounova, L. V.; Park, J. H.; Grassian, V. H.; Gonzalez-Pech, N. I.; Peters, T. M., “Design and Evaluation of a High-Flowrate Nanoparticle Respiratory Deposition (NRD) Sampler” Journal of Aerosol Science 2019, 134, 72–79
Wang, J.; Hsu, S.-W.; Gonzalez-Pech, N.; Jhunjhunwala, A.; Hariri, A.; Grassian, V. H.; Tao, A.; Jokerst, J. V. “Copper Sulfide Nanodisks and Nanoprisms for Photoacoustic Ovarian Tumor Imaging” Particle and Particle Systems Characterization 2019, 36, 1900171, 1–7.
N. I. Gonzalez-Pech, L. V. Stebounova, I. B. Ustunol, J. H. Park, T. R. Anthony, T. M. Peters, V. H. Grassian. "Size, composition, morphology, and health implications of airborne incidental metal-containing nanoparticles", Journal of Occupational and Environmental Hygiene, 2018. DOI: 10.1080/15459624.2018.1559925
Y. Fang, P. S. J. Lakey, S. Riahi, A. T. McDonald, M. Shrestha, D. J. Tobias, M. Shiraiwa, V. H. Grassian "A molecular picture of surface interactions of organic compounds on prevalent indoor surfaces: limonene adsorption on SiO2 " Chemical Science, 2019, Accepted Manuscript. DOI:10.1039/C8SC05560B
Y. Fang, D. Lesnicki, K. J. Wall, M. Gaigeot, M. Sulpizi, V. Vaida, V. H. Grassian "Heterogeneous Interactions between Gas-Phase Pyruvic Acid and Hydroxylated Silica Surfaces: A Combined Experimental and Theoretical Study" The Journal of Physical Chemistry A, 2018 Accepted Manuscript. DOI: 10.1021/acs.jpca.8b10224
Y. Fang, S. Riahi, A.McDonald, M. Shrestha, D.J. Tobias, V. H. Grassian "What is the Driving Force Behind the Adsorption of Hydrophobic Molecules on Hydrophilic Surfaces?" The Journal of Physical Chemistry C Letters, 2018, Accepted Manuscript. DOI: 10.1021/acs.jpclett.8b03484
Grassian, V. H. “Physical Chemistry of Environmental Interfaces: Aerosols, Nanomaterials and Indoor Surfaces” The Chemist 2019, 91, 13-17.
Coddens, E.M.; Huang, L.; Wong, C.; Grassian, V. H. “Influence of Glyoxal on the Catalytic Oxidation of S(IV) in Acidic Aqueous Media” ACS Earth and Space Chemistry 2019, 3, 142 – 149.
H. Wu, N. Gonzalez Pech, V.H. Grassian, "Displacement Reactions Between Environmentally and Biologically Relevant Ligands on TiO2 Nanoparticles: Insights into the Aging of Nanoparticles in the Environment" Environmental Science: Nano, 2019, DOI: 10.1039/C8EN00780B
2018
S. Jayalath, S. C. Larsen, V. H. Grassian, "Surface adsorption of Nordic aquatic fulvic acid on amine-functionalized and non-functionalized mesoporous silica nanoparticles" Environmental Science: Nano, 2018 DOI: 10.1039/C8EN00618K
J. M. Schiffer, L. E. Mael, L. A. Prather, R. E. Amaro, V. H. Grassian, "Sea Spray Aerosol: Where Marine Biology Meets Atmospheric Chemistry" ACS Central Science, 2018, Article ASAP. DOI: 10.1021/acscentsci.8b00674
E.M. Coddens, L. Huang, C. Wong, V. H. Grassian "Influence of glyoxal on the catalytic oxidation of S(IV) in acidic aqueous media" ACS Earth & Space Chemistry, 2018, Just Accepted Manuscript, DOI: 10.1021/acsearthspacechem.8b00168
D Kwon, MJ Sovers, VH Grassian, PD Kleiber, MA Young "Optical Properties of Humic Material Standards: Solution Phase and Aerosol Measurements " ACS Earth & Space Chemistry, Just Accepted Manuscript.. DOI: 10.1021/acsearthspacechem.8b00097
V.W.Or, M.R.Alves, M.Wade, S.Schwab, R.L.Corsi, V.H.Grassian "Crystal Clear? Microspectroscopic Imaging and Physicochemical Characterization of Indoor Depositions on Window Glass" Environmental Science & Technology Letters, 2018, 5 (8). DOI: 10.1021/acs.estlett.8b00355
J.M.Schiffer , M.Luo M , A.C. Dommer, G Thoron , M. Pendergraft , M.V. Santander , D. Lucero, E. Pecora de Barros , K.A. Prather, V.H.Grassian, R.E Amaro "Impacts of Lipase Enzyme on the Surface Properties of Marine Aerosols.", The Journal of Physical Chemistry Letters, 2018, 9(14). DOI: 10.1021/acs.jpclett.8b01363
H.A. Alalwan, S.E. Mason, V.H. Grassian, D.M. Cwiertny, "α-Fe2O3 Nanoparticles as Oxygen Carriers for Chemical Looping Combustion: An Integrated Materials Characterization Approach to Understanding Oxygen Carrier Performance, Reduction Mechanism, and Particle Size Effects" Energy & Fuels, 2018, 32(7). DOI: 10.1021/acs.energyfuels.8b01539
D.B. Collins, V. H. Grassian, "Chapter 10 - Gas–Liquid Interfaces in the Atmosphere: Impacts, Complexity, and Challenges, In Developments in Physical & Theoretical Chemistry", Physical Chemistry of Gas-Liquid Interfaces, 2018, DOI:10.1016/B978-0-12-813641-6.00010-8.
L. Huang, R.E. Cochran, E.M. Coddens, V.H.Grassian, "Formation of Organosulfur Compounds through Transition Metal Ion-Catalyzed Aqueous Phase Reactions" Environmental Science & Technology Letters, 2018 5(6). DOI:10.1021/acs.estlett.8b00225
N.I. Gonzalez-Pech, V.H. Grassian"Surface Chemical Functionalities of Environmental Nanomaterials" Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Encyclopedia of Interfacial Chemistry. Surface Science and Electrochemistry. 2018, DOI:10.1016/B978-0-12-409547-2.13188-9
L.V. Stebounova, N.I. Gonzalez-Pech, J.H. Park, T.R. Anthony, V.H. Grassian, T.M. Peters, "Particle Concentrations in Occupational Settings Measured with a Nanoparticle Respiratory Deposition (NRD) Sampler" Annals of Work Exposures and Health, 2018 62(6). DOI:10.1093/annweh/wxy033
C.S. McCluskey, T.C. J. Hill, C.M. Sultana, O.Laskina, J. Trueblood, M.V. Santander, C.M. Beall, J.M. Michaud, S.M. Kreidenweis, L.A. Prather, V. Grassian, and P.J. DeMott, "A mesocosm double feature: Insights into the chemical make-up of marine ice nucleating particles" Journal of the Atmospheric Sciences. DOI:10.1175/JAS-D-17-0155.1
M. Shrestha, M.Luo, Y. Li, B. Xiang, W.Xiong , V.H. Grassian "Let there be light: stability of palmitic acid monolayers at the air/salt water interface in the presence and absence of simulated solar light and a photosensitizer"Chemical Science, 2018, 9. DOI: 10.1039/C8SC01957F
V.W.Or, A. D. Estillore, A. V. Tivanski, V.H.Grassian, "Lab on a Tip: Atomic Force Microscopy - Photothermal Infrared Spectroscopy of Atmospherically Relevant Organic/Inorganic Aerosol Particles in the Nanometer to Micrometer Size Range" Analyst, 2018, 143. DOI:10.1039/C8AN00171E
D. Kwon, V.W. Or, M. J. Sovers, M. Tang, P. D. Kleiber, V. H. Grassian, M.A. Young, "Optical Property Measurements and Single Particle Analysis of Secondary Organic Aerosol Produced from the Aqueous Phase Reaction of Ammonium Sulfate with Methylglyoxal" ACS Earth and Space Chemistry, 2018, 2 (4). DOI: 10.1021/acsearthspacechem.8b00004
T.H. Bertram, R.E. Cochran, V.H. Grassian, E.A. Stone, "Sea spray aerosol chemical composition: elemental and molecular mimics for laboratory studies of heterogeneous and multiphase reactions" Chemical Society Reviews, 2018, 47 DOI: 10.1039/C7CS00008A
S. Jayalath, H. Wu, S.C. Larsen, V.H. Grassian, "Surface Adsorption of Suwannee River Humic Acid on TiO2 Nanoparticles: A Study of pH and Particle Size" Langmuir. 2018, 34(9). DOI: 10.1021/acs.langmuir.8b00300
L. Stebounova , N. Gonzalez Pech , T. M. Peters, V.H. Grassian, "Physicochemical properties of air discharge-generated manganese oxide nanoparticles: Comparison to welding fumes" Environmental Science:Nano. 2018, 5. DOI: 10.1039/C7EN01046J
2017
H. D. Lee, A. D. Estillore, H. S. Morris, K. K. Ray, A. Alejandro, V. H. Grassian, V. Tivanski, "Direct Surface Tension Measurements of Individual Submicrometer Particles Using Atomic Force Microscopy" Journal of Physical Chemistry A. 2017, 121 (43). DOI: 10.1021/acs.jpca.7b04041
D. Q. Pham, R. E.O'Brien, M. Fraund, D. Bonanno, O. Laskina, C. Beall, K. A Moore, S. Forestieri, X. Wang, C. Lee, C. M. Sultana, V. H. Grassian, C. D. Cappa, K. A. Prather, and R. C. Moffet, "Biological Impacts on Carbon Speciation and Morphology of Sea Spray Aerosol" ACS Earth and Space Chemistry, 2017, 1 (9) . DOI: 10.1021/acsearthspacechem.7b00069
Z. Xu, V. H. Grassian, "Bovine Serum Albumin Adsorption on TiO2 Nanoparticle Surface: Effects of pH and Co-Adsorption of Phosphate on Protein-Surface Interactions and Protein Structure" Journal of Physical Chemistry C. 2017, 121 (39) . DOI: 10.1021/acs.jpcc.7b07525
L. G. Vargas Buonfiglio, I. A. Mudunkotuwa, M. H. Abou Alaiwa, O. G. Vanegas Calderón, J. A. Borcherding, A. K. Gerke, J. Zabner, V. H. Grassian, A. P. Comellas, "Effects of Coal Fly Ash Particulate Matter on the Antimicrobial Activity of Airway Surface Liquid" Environmental Health Perspectives 2017 125 (7). DOI: 10.1289/EHP876
A. D. Estillore, H. S. Morris, V. W. Or, H. D. Lee, M. R. Alves, M. A. Marciano, O. Laskina, Z. Qin, A. V. Tivanski, V. H. Grassian, "Linking hygroscopicity and surface microstructure of model inorganic salts, simple and complex carbohydrates, and authentic sea spray aerosol particles" Physical Chemistry Chemical Physics 2017 Accepted. DOI: 10.1039/C7CP04051B
B. E. Givens, N. D. Diklich, J. Fiegel, V. H. Grassian, "Adsorption of bovine serum albumin on silicon dioxide nanoparticles: Impact of pH on nanoparticle–protein interactions" Biointerphases 2017 12(2), 02D404. DOI: 10.1116/1.4982598
R. E. Cochran, O. Laskina, J. V. Trueblood, A. D. Estillore, H. S. Morris, T. Jayarathne, C. M. Sultana, C. Lee, P. Lin, J. Laskin, A. Laskin, J. A. Dowling, Z. Qin, C. D.Cappa, T. H. Bertram, A. V. Tivanski, E. A .Stone, K. A. Prather, V. H. Grassian, "Molecular Diversity of Sea Spray Aerosol Particles: Impacts of Ocean Biology on Particle Composition and Hygroscopicity" Chem 2017 2(5), 655-667. DOI: 10.1016/j.chempr.2017.03.007.
R. E. Cochran, O. S. Ryder, V. H. Grassian, K. A. Prather, "Sea Spray Aerosol: The Chemical Link between the Oceans, Atmosphere, and Climate " Accounts of Chemical Research 2017 50(3), 599-604. DOI: 10.1021/acs.accounts.6b00603
H.A. Alalwan, C. M. Cwiertny, V.H. Grassian, "Co3O4 Nanoparticles as Oxygen Carriers for Chemical Looping Combustion:A Materials Characterization Approach to Understanding Oxygen Carrier Performance" Chemical Engineering Journal 2017, 319, 279-287. DOI: 10.1016/j.cej.2017.02.134
B.E. Givens, Z. Xu, J. Fiegel, V.H. Grassian, "Bovine Serum Albumin Adsorption on SiO2 and TiO2 Nanoparticle Surfaces at Circumneutral and Acidic pH: A Tale of Two Nano-Bio Surface Interactions," Journal of Colloid and Interface Science 2017, 493, 334-341. DOI: 10.1016/j.jcis.2017.01.011.
J.H. Park, I.A. Mudunkotuwa, K.J. Crawford, T.R. Anthony, V.H. Grassian, T.M. Peters, "Rapid Analysis of the Size Distribution of Metal-Containing Aerosol," Aerosol Science and Technology 2017, 51, 108-115. DOI: 10.1080/02786826.2016.1245406.
2016
A. Gankanda, E.M. Coddens, Y. Zhang, D.M. Cwiertny, V.H. Grassian, "Sulfate Formation Catalyzed by Coal Fly Ash, Mineral Dust and Iron (III) Oxide: Variable Influence of Temperature and Light," Environmental Science: Processes & Impacts 2016, 18, 1484-1491. DOI: 10.1039/C6EM00430J
T. Jayarathne, C.M. Sultana, C. Lee, F. Malfatti, J.L. Cox, M.A. Pendergraft, K.A. Moore, F. Azam, A.V. Tivanski, C.D. Cappa, T.H. Bertram, V.H. Grassian, K.A. Prather, E.A. Stone, "Enrichment of Saccharides and Divalent Cations in Sea Spray Aerosol During Two Phytoplankton Blooms," Environmental Science & Technology 2016, 50, 11511-11520. DOI: 10.1021/acs.est.6b02988.
A. Gankanda, D.M. Cwiertny, V.H. Grassian, "Role of Atmospheric CO2 and H2O Adsorption on ZnO and CuO Nanoparticle Aging: Formation of New Surface Phases and the Impact on Nanoparticle Dissolution," Journal of Physical Chemistry C 2016, 120, 19195–19203. DOI: 10.1021/acs.jpcc.6b05931.
J.V. Trueblood, A.D. Estillore, C. Lee, J. Dowling, K.A. Prather, V.H. Grassian, "Heterogeneous chemistry of lipopolysaccharides with gas-phase nitric acid: Reactive sites and reaction pathways," Journal of Physical Chemistry A 2016, 120, 6444–6450. DOI: 10.1021/acs.jpca.6b07023.
A.D. Estillore, J.V. Trueblood, V.H. Grassian, "Atmospheric chemistry of bioaerosols: Heterogeneous and multiphase reactions with atmosperic oxidants and other trace gases," Chemical Science 2016, 7, 6604-6616. DOI: 10.1039/C6SC02353C.
T.-H. Chen, L. Wang, J.V. Trueblood, V.H. Grassian, S. M. Cohen, "Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal−Organic Polyhedra," Journal of American Chemical Society 2016,138, 9646–9654. DOI: 10.1021/jacs.6b04971.
M. Tang, W. Larish, Y. Fang, A. Gankanda, V.H. Grassian, "Heterogeneous Reactions of Acetic Acid with Oxide Surfaces: Effects of Mineralogy and Relative Humidity," Journal of Physical Chemistry A 2016, 120, 5609–5616. DOI: 10.1021/acs.jpca.6b05395.
J.M. Alexander, D.M. Bell, D. Imre, P.D. Kleiber, V.H. Grassian, A. Zelenyuk, "Measurement of size-dependent dynamic shape factors of quartz particles in two flow regimes," Aerosol Science and Technology 2016, 50, 870-879. DOI: 10.1080/02786826.2016.1200006.
M. Tang, J.M. Alexander, D. Kwon, A.D. Estillore, O. Laskina, M.A. Young, P.D. Kleiber, V.H. Grassian, "Optical and Physicochemical Properties of Brown Carbon Aerosol: Light Scattering, FTIR Extinction Spectroscopy, and Hygroscopic Growth," Journal of Physical Chemistry A 2016, 120, 4155-4166. DOI: 10.1021/acs.jpca.6b03425.
Y. Fang, M. Tang, V.H. Grassian, "Competition Between Displacement and Dissociation of a Strong Acid Compared to a Weak Acid Adsorbed on Silica Particle Surfaces: The Role of Adsorbed Water," Journal of Physical Chemistry A 2016, 120, 4016-4024. DOI: 10.1021/acs.jpca.6b02262.
L.W. D. Mines, J.H. Park, I.A. Mudunkotuwa, T. R. Anthony, V.H. Grassian, T.M. Peters, "Porous polyurethane foam for use as a particle collection substrate in a nanoparticle respiratory deposition sampler," Aerosol Science and Technology 2016, 50, 497-506. DOI: 10.1080/02786826.2016.1164828 .
R.E. Cochran, T. Jayarathne, E.A. Stone, V.H. Grassian, "Selectivity Across the Interface: A Test of Surface Activity in the Composition of Organic Enriched Aerosols from Bubble Bursting," Journal of Physical Chemistry Letters 2016, 7, 1692-1696. DOI: 10.1021/acs.jpclett.6b00489.
V.H. Grassian, "Environmental Science: Nano – immediacy index and more," Environmental Science: Nano 2016, 3, 234-235. DOI: 10.1039/C6EN90007K. (Editorial)
M. Tang, D.J. Cziczo, and V.H. Grassian, "Interactions of Water with Mineral Dust Aerosol: Water Adsorption, Hygroscopicity, Cloud Condensation, and Ice Nucleation," Chemical Reviews 2016, 116, 4205–4259. DOI: 10.1021/acs.chemrev.5b00529.
A. Wongrakpanich, I.A. Mudunkotuwa, S.M. Geary, A.S. Morris, K.A. Mapuskar, D.R. Spitz, V.H. Grassian, A.K. Salem, "Size-dependent cytotoxicity of copper oxide nanoparticles in lung epithelial cells," Environmental Science: Nano 2016, 3, 365-374. DOI: 10.1039/c5en00271k.
A.D. Estillore, A.P.S. Hettiyadura, Z. Qin, E. Leckrone, B. Wombacher, T. Humphry, E.A. Stone, V.H. Grassian, "Water Uptake and Hygroscopic Growth of Organosulfate Aerosol," Environmental Science & Technology 2016, 50, 4259-4268. DOI: 10.1021/acs.est.5b05014.
H.S. Morris, A.D. Estillore, O. Laskina, V.H. Grassian, A.V. Tivanski, "Quantifying the hygroscopic growth of individual submicrometer particles with atomic force microscopy," Analytical Chemistry 2016, 88, 3647–3654. DOI: 10.1021/acs.analchem.5b04349.
R.E. Cochran, O. Laskina, T. Jayarathne, A. Laskin, J. Laskin, P. Lin, C.M. Sultana, C. Lee, K.A. Moore, C.D. Cappa, T.H. Bertram, K.A. Prather, V.H. Grassian, E.A. Stone, "Analysis of Organic Anionic Surfactants in Fine and Coarse Fractions of Freshly Emitted Sea Spray Aerosol," Environmental Science & Technology 2016, 50, 2477–2486. DOI: 10.1021/acs.est.5b04053.
J.P. Patterson, D.B. Collins, J.M. Michaud, J.L. Axson, C.M. Sultana, T. Moser, A.C. Dommer, J. Conner, V.H. Grassian, M. D. Stokes, G.B. Deane, JE. Evans, M.D. Burkart, K.A. Prather, and N.C. Gianneschi, "Sea Spray Aerosol Structure and Composition Using Cryogenic Transmission Electron Microscopy," ACS Central Science 2016, 2, 40-47 . DOI: 10.1021/acscentsci.5b00344
S.E. Lehman, I.A. Mudunkotuwa, V.H. Grassian, and S.C. Larsen, "Nano-Bio Interactions of Porous and Nonporous Silica Nanoparticles of Varied Surface Chemistry: A Structural, Kinetic, and Thermodynamic Study of Protein Adsorption from RPMI Culture Medium," Langmuir 2016,32, 731–742. DOI: 10.1021/acs.langmuir.5b03997.
P.J. DeMott, T.C.J.Hill, C.S. McCluskey, K. A. Prather, D.B. Collins, R.C. Sullivan, M.J. Ruppel, R.H. Mason, V.E. Irish, T. Lee, C.Y. Hwang, T.S. Rhee, J.R. Snider, G.R. McMeeking, S. Dhaniyala, E.R. Lewis, J.J.B. Wentzell, J. Abbatt, C. Lee, C.M. Sultana, A.P. Ault, J.L. Axson, M. Diaz Martinez, I. Venero, G. Santos-Figueroa, M.D. Stokes, G.B. Deane, O.L. Mayol-Bracero, V.H. Grassian, T.H. Bertram, A.K. Bertram, B.F. Moffett, G.D. Franc, "Sea spray aerosol as a unique source of ice nucleating particles," Proceedings of the National Academy of Sciences USA 2016, 113, 5797-5803. DOI: 10.1073/pnas.1514034112.
L. Klüser, C. Di Biagio, P.D. Kleiber, P. Formenti, V.H. Grassian, "Optical properties of non-spherical desert dust particles in the terrestrial infrared – An asymptotic approximation approach," Journal of Quantitative Spectroscopy and Radiative Transfer 2016, 178, 209–223. DOI: 10.1016/j.jqsrt.2015.11.020.
S.E. Lehman, A.S. Morris, P.S. Mueller, A.K. Salem, V.H. Grassian, and S.C. Larsen, "Silica Nanoparticle-Generated ROS as a Predictor of Cellular Toxicity: Mechanistic Insights and Safety by Design," Environmental Science: Nano 2016, 3, 56-66. DOI: 10.1039/C5EN00179J.
V.H. Grassian, A.J. Haes, I.A. Mudunkotuwa, P. Demokritou, A.B. Kane, C.J. Murphy, J.E. Hutchison, J.A. Isaacs, Y.-S. Jun, B. Karn, S.I. Khondaker, S.C. Larsen, B.L.T. Lau, J.M. Pettibone, O.A. Sadik, N.B. Saleh, C. Teague, "NanoEHS – Defining Fundamental Science Needs: No Easy Feat when the Simple itself is Complex," Environmental Science: Nano 2016, 3, 15-27. DOI: 10.1039/C5EN00112A.
2015
O. Laskina, H.S. Morris, J.R. Grandquist, A.D. Estillore, E.A. Stone, V.H. Grassian, and A.V. Tivanski, "Substrate-deposited sea spray aerosol particles: Influence of analytical method, substrate and storage conditions on particle size, phase and morphology," Environmental Science and Technology 2015, 49, 13447–13453. DOI: 10.1021/acs.est.5b02732.
V.H. Grassian, "Particle Chemistry in the Environment: Challenges and Opportunities," Journal of Physical Chemistry Letters 2015, 6, 3880-3881. DOI: 10.1021/acs.jpclett.5b02008.
I.A. Mudunkotuwa and V.H. Grassian, "Biological and Environmental Media Control Oxide Nanoparticle Surface Composition: The Roles of Biological Components (Proteins and Amino Acids), Inorganic Oxyanions and Humic Acid," Environmental Science: Nano 2015, 2, 429-439. DOI: 10.1039/C4EN00215F.
I. Al-Naiema, A.D. Estillore, I.A. Mudunkotuwa, V.H. Grassian, E.A. Stone, "Impacts of Co-firing Biomass on Emissions of Particulate Matter to the Atmosphere," Fuel 2015, 162, 111-120. DOI: 10.1016/j.fuel.2015.08.054.
C. Lee, C.M. Sultana, D.B. Collins, M.V. Santander, J.L. Axson, F. Malfatti, G.C. Cornwell, J.R. Grandquist, G.B. Deane, M.D. Stokes, F. Azam, V.H. Grassian, K.A. Prather, "Advancing Model Systems for Fundamental Laboratory Studies of Sea Spray Aerosol using the Microbial Loop," Journal of Physical Chemistry A, 2015 119, 8860–8870. DOI: 10.1021/acs.jpca.5b03488.
I.A. Mudunkotuwa, T.R. Anthony, V.H. Grassian, T.M. Peters, "Accurate Quantification of TiO2 Nanoparticles Collected on Air Filters Using a Microwave-Assisted Acid Digestion Method," Journal of Occupational and Environmental Hygiene 2015, 13, 30-39. DOI:10.1080/15459624.2015.1072278.
X. Wang, C.M. Sultana, J. Trueblood, T.C.J. Hill, F. Malfatti, C. Lee, O. Laskina, K.A. Moore, C.M. Beall, C.S. McCluskey, G.C. Cornwell, Y. Zhou, J.L. Cox, M.A. Pendergraft, M.V. Santander, T.H. Bertram, C.D. Cappa, F. Azam, P.J. DeMott, V.H. Grassian and K.A. Prather, "Impact of Bacterial Enzymatic Activity on Organic Enrichment in Sea Spray Aerosol: A Tale of Two Blooms," ACS Central Science 2015, 1, 124-131. DOI: 10.1021/acscentsci.5b00148.
V.H. Grassian and E.A. Stone, "Chemistry’s Contributions to Our Understanding of Atmospheric Science and Climate," Journal of Chemical Education 2015, 92, 595-597. (An Editorial)
P.K. Quinn, D.B. Collins, V.H. Grassian, K.A. Prather, T.S. Bates, "Chemistry and Related Properties of Freshly Emitted Sea Spray Aerosol,"Chemical Reviews 2015, 115, 4383–4399. DOI: 10.1021/cr500713g.
H.S. Morris, V.H. Grassian, A.V. Tivanski, "Humidity-Dependent Surface Tension Measurements of Individual Inorganic and Organic Submicrometre Liquid Particles," Chemical Science 2015, 6, 3242-3247. DOI: 10.1039/C4SC03716B.
J.M. Alexander, V.H. Grassian, M.A. Young, P.D. Kleiber, "Optical Properties of Selected Components of Mineral Dust Aerosol Processed with Organic Acids and Humic Material," Journal of Geophysical Research: Atmospheres 2015, 120, 2437–2452. DOI: 10.1002/2014JD022782.
J.H. Park, I.A. Mudunkotuwa, L.W.D. Mines, T.R. Anthony, V.H. Grassian, T.M. Peters, "A Granular Bed for Use in a Nanoparticle Respiratory Deposition Sampler," Aerosol Science and Technology 2015, 49, 179-187. DOI: 10.1080/02786826.2015.1013521.
V.H. Grassian, "Environmenal Science: Nano - the first year a successful launch," Environmental Science: Nano 2015, 2, 9-10. DOI: 10.1039/C4EN90025A. (An Editorial)
O. Laskina, H.S. Morris, J.R. Grandquist, Z. Qin, E.A. Stone, A.V. Tivanski, V.H. Grassian, "Size matters in water uptake and hygroscopic growth of atmospherically relevant multi-component aerosol particles," Journal of Physical Chemistry A 2015, 119, 4489-4497. DOI: 10.1021/jp510268p.(ACS Editors' Choice)
2014
C.E. Nanayakkara, J.K. Dillon, V.H. Grassian, "Surface Adsorption and Photochemistry of Gas-Phase Formic Acid on TiO2 Nanoparticles: The Role of Adsorbed Water in the Surface Coordination Mode. Adsorption Kinetics, and Rate of Photoproduct Formation," Journal of Physical Chemistry C 2014, 118, 25487-25495. DOI: 10.1021/jp507551y.
C.E. Nanayakkara, W.A. Larish, V.H. Grassian, "Titanium Dioxide Nanoparticle Surface Reactivity with Atmospheric Gases, CO2, SO2, and NO2: Roles of Surface Hydroxyl Groups and Adsorbed Water in the Formation and Stability of Adsrobed Products," Journal of Physical Chemistry C 2014, 118, 23011-23021. DOI: 10.1021/jp504402z.
A. Gankanda and V.H. Grassian, "Nitrate Photochemistry on Laboratory Proxies of Mineral Dust Aerosol: Wavelength Dependence and Action Spectra," Journal of Physical Chemistry C 2014, 118, 29117–29125. DOI: 10.1021/jp504399a.
I.A. Mudunkotuwa and V.H. Grassian, "Histidine Adsorption on TiO2 Nanoparticles: An Integrated Spectroscopic, Thermodynamic, and Molecular-Based Approach toward Understanding Nano–Bio Interactions," Langmuir 2014, 30, 8751–8760. DOI: 10.1021/la500722n.
A.P. Ault, T.L. Guasco, J. Baltrusaitis, O.S. Ryder, J.V. Trueblood, D.B. Collins, M.J. Ruppel, L.A. Cuadra-Rodriguez, K.A. Prather, and V.H. Grassian, "Heterogeneous Reactivity of Nitric Acid with Nascent Sea Spray Aerosol: Large Differences Observed between and within Individual Particles," Journal of Physical Chemistry Letters 2014, 5, 2493–2500. DOI: 10.1021/jz5008802.
D.B. Collins, D.F. Zhao, M.J. Ruppel, O. Laskina, J.R. Grandquist, R.L. Modini, M.D. Stokes, L.M. Russell, T.H. Bertram, V.H. Grassian, G.B. Deane, and K.A. Prather, "Direct aerosol chemical composition measurements to evaluate the physicochemical differences between controlled sea spray aerosol generation schemes," Atmospheric Measurement Techniques 2014, 7, 3667-3683.DOI: 10.5194/amt-7-3667-2014.
O. Laskina, M.A. Young, P.D. Kleiber, and V.H. Grassian, "Infrared Optical Constants of Organic Aerosols: Organic Acids and Model Humic-Like Substances (HULIS)," Aerosol Science and Technology 2014, 48, 630-637. DOI: 10.1080/02786826.2014.904499.
J.H. Park, I.A. Mudunkotuwa, J.S. Kim, A. Stanam, P.S. Thorne, V.H. Grassian, and T.M. Peters. "Physicochemical Characterization of Simulated Welding Fumes from a Spark Discharge System," Aerosol Science and Technology 2014, 48, 768-776. DOI: 10.1080/02786826.2014.925536.
A. Adamcakova-Dodd, L.V. Stebounova, J.S. Kim, S.U. Vorrink, A.P. Ault, P.T. O’Shaughnessy, V.H. Grassian, P.S. Thorne, "Toxicity assessment of zinc oxide nanoparticles using sub-acute and sub-chronic murine inhalation models," Particle and Fibre Toxicology 2014, 11, 15. DOI:10.1186/1743-8977-11-15.
A.R. Baker, O. Laskina, and V.H. Grassian, "Processing and Ageing in the Atmosphere," A Book Chapter in Mineral Dust: A Key Player in the Earth System, Eds: P. Knippertz and J.-B.W. Stuut, 2014, 75-92. DOI: 10.1007/978-94-017-8978-3_4.
J. Borcherding, J. Baltrusaitis, H. Chen, L. Stebounova, C.-M. Wu, G. Rubasinghege, I.A. Mudunkotuwa, J.C. Caraballo, J. Zabner, V.H. Grassian, and A.P. Comellas, "Iron oxide nanoparticles induce Pseudomonas aeruginosa growth, induce biofilm formation, and inhibit antimicrobial peptide function," Environmental Science: Nano 2014, 1, 123-132. DOI: 10.1039/C3EN00029J.
Vicki H. Grassian, "Environmental Science: Nano – a journal is born. A new journal with a large scope that focuses on small materials," Environmental Science: Nano 2014, 1, 8-10. DOI: 10.1039/C3EN90001K.
I.A. Mudunkotuwa, A. Al Minshid, and V.H. Grassian, "ATR-FTIR spectroscopy as a tool to probe surface adsorption on nanoparticles at the liquid–solid interface in environmentally and biologically relevant media," Analyst 2014, 139, 870-881. DOI: 10.1039/C3AN01684F.
2013
T.L. Guasco, L.A. Cuadra-Rodriguez, B.E. Pedler, A.P. Ault, D.B. Collins, D. Zhao, M.J. Kim, M.J. Ruppel, S.C. Wilson, R.S. Pomeroy, V.H. Grassian, F. Azam, T.H. Bertram, K.A. Prather, "Transition Metal Associations with Primary Biological Particles in Sea Spray Aerosol Generated in a Wave Channel," Environmental Science & Technology, 2013, 48, 1324-1333. DOI: 10.1021/es403203d.
C.E. Nanayakkara, P.M. Jayaweera, G. Rubasinghege, J. Baltrusaitis, and V.H. Grassian, "Surface Photochemistry of Adsorbed Nitrate: The Role of Adsorbed Water in the Formation of Reduced Nitrogen Species on α-Fe2O3Particle Surfaces," Journal of Physical Chemistry A, 2013, 118, 158–166. DOI: 10.1021/jp409017m.
C.E. Nanayakkara, P.M. Jayaweera, J. Baltrusaitis, V.H. Grassian, "Photochemistry of Adsorbed Nitrate Formed From Nitric Acid Adsorption on α-Fe2O3 Particle Surfaces: The Role of Adsorbed Water in the Formation of Nitrogen-Reduced Surface Species," Journal of Physical Chemistry A, 2013, 118, 158-166. DOI: 10.1021/jp409017m.
G. Rubasinghege, S. Ogden, J. Baltrusaitis, and V.H. Grassian, "Heterogeneous Uptake and Adsorption of Gas-Phase Formic Acid on Oxide and Clay Particle Surfaces: The Roles of Surface Hydroxyl Groups and Adsorbed Water in Formic Acid Adsorption and the Impact of Formic Acid Adsorption on Water Uptake," Journal of Physical Chemistry A, 2013, 117, 11316-11327. DOI: 10.1021/jp408169w.
K.L.S. Worthington, A. Adamcakova-Dodd, A. Wongrakpanich, I.A. Mudunkotuwa, K.A. Mapuskar, V.B. Joshi, C.A. Guymon, D.R. Spitz, V.H. Grassian, P.S. Thorne, A.K. Salem, "Chitosan coating of copper nanoparticles reduces in vitro toxicity and increases inflammation in the lung," Nanotechnology, 2013, 24, 395101. DOI:10.1088/0957-4484/24/39/395101.
A.P. Ault, T.L. Guasco, O.S. Ryder, J. Baltrusaitis, L.A. Cuadra-Rodriguez, D.B. Collins, M.J. Ruppel, T.H. Bertram, K.A. Prather, V.H. Grassian, "Inside versus outside: Ion redistribution in nitric acid reacted sea spray aerosol particles as determined by single particle analysis," Journal of American Chemical Society, 2013, 135, 14528–14531. DOI: 10.1021/ja407117x.
J.M. Alexander, B. Meland, O. Laskina, M.A. Young, V.H. Grassian, and P.D. Kleiber, "Light scattering from diatomaceous earth aerosol," Journal of Quantitative Spectroscopy and Radiative Transfer, 2013, 125, 33–37. DOI: 10.1016/j.jqsrt.2013.04.013.
H. Chen and V.H. Grassian, "Iron Dissolution of Dust Source Materials during Simulated Acidic Processing: The Effect of Sulfuric, Acetic, and Oxalic Acids," Environmental Science & Technology, 2013, 47, 10312-10321. DOI: 10.1021/es401285s.
D.B. Collins, A.P. Ault, R.C. Moffet, M.J. Ruppel, L.A. Cuadra‐Rodriguez, T.L. Guasco, C.E. Corrigan, B.E. Pedler, F. Azam, L.I. Aluwihare, T.H. Bertram, G.C. Roberts, V.H. Grassian, K.A. Prather, "Impact of marine biogeochemistry on the chemical mixing state and cloud forming ability of nascent sea spray aerosol," Journal of Geophysical Research: Atmospheres, 2013, 118, 8553–8565. DOI: 10.1002/jgrd.50598.
C.J. Ebben, A.P. Ault, M.J. Ruppel, O.S. Ryder, T.H. Bertram, V.H. Grassian, K.A. Prather, F.M. Geiger, "Size-Resolved Sea Spray Aerosol Particles Studied by Vibrational Sum Frequency Generation," Journal of Physical Chemistry A, 2013, 117, 6589–6601. DOI: 10.1021/jp401957k.
O. Laskina, M.A. Young, P.D. Kleiber, and V.H. Grassian, "Infrared extinction spectroscopy and micro-Raman spectroscopy of select components of mineral dust mixed with organic compounds," Journal of Geophysical Research: Atmospheres, 2013, 118, 6593–6606, DOI: 10.1002/jgrd.50494.
A.P. Ault, R.C. Moffet, J. Baltrusaitis, D.B. Collins, M.J. Ruppel, L.A. Cuadra-Rodriguez, D. Zhao, T.L. Guasco, C.J. Ebben, F.M. Geiger, T.H. Bertram, K.A. Prather, V.H. Grassian, "Size-Dependent Changes in Sea Spray Aerosol Composition and Properties with Different Seawater Conditions," Environmental Science & Technology, 2013, 47, 5603–5612. DOI: 10.1021/es400416g.
K.A. Prather, T.H Bertram, V.H. Grassian, G.B. Deane, M.D. Stokes, P.J. DeMott, L.I. Aluwihare, B.P. Palenik, F. Azam, J.H. Seinfeld, R.C. Moffet, M.J. Molina, C.D. Cappa, F.M. Geiger, G.C. Roberts, L.M. Russell, A.P. Ault, J. Baltrusaitis, D.B. Collins, C.E. Corrigan, L.A. Cuadra-Rodriguez, C.J. Ebben, S.D. Forestieri, T.L. Guasco, S.P. Hersey, M.J. Kim, W.F. Lambert, R.L. Modini, W. Mui, B.E. Pedler, M.J. Ruppel, O.S. Ryder, N.G. Schoepp, R.C. Sullivan, D. Zhao, "Bringing the ocean into the laboratory to probe the chemical complexity of sea spray aerosol," Proceedings of the National Academy of Sciences, 2013, 110, 7550-7555. DOI:10.1073/pnas.1300262110.
J.A. Borcherding, H. Chen, J.C. Caraballo, J. Baltrusaitis, A.A. Pezzulo, J. Zabner, V.H. Grassian, A.P. Comellas, "Coal Fly Ash Impairs Airway Antimicrobial Peptides and Increases Bacterial Growth," PLoS One, 2013, 8, e57673. DOI: 10.1371/journal.pone.0057673.
A. Gankanda and V.H. Grassian, "Nitrate Photochemistry in NaY Zeolite: Product Formation and Product Stability under Different Environmental Conditions," Journal of Physical Chemistry A, 2013, 117, 2205-2212. DOI: 10.1021/jp312247m.
J.M. Alexander, O. Laskina, B. Meland, M.A. Young, V.H. Grassian, P.D. Kleiber, "A combined laboratory and modeling study of the infrared extinction and visible light scattering properties of mineral dust aerosol," Journal of Geophysical Research: Atmospheres, 2013, 118, 435-452. DOI: 10.1029/2012JD018751.
Q. Ma, H. He, Y. Liu, C. Liu, V.H. Grassian, "Heterogeneous and multiphase formation pathways of gypsum in the atmosphere," Physical Chemistry Chemical Physics, 2013, 15, 19196-19204. DOI: 10.1039/C3CP53424C.
M.M. Monick, J. Baltrusaitis, L.S. Powers, J.A. Borcherding, J.C. Caraballo, I.A. Mudunkotuwa, D.W. Peate, K. Walters, J.M. Thompson, V.H. Grassian, G. Gudmundsson, A.P. Comellas, "Effects of Eyjafjallajökull volcanic ash on innate immune system responses and bacterial growth in vitro," Environmental Health Perspectives, 2013, 121, 691-698. DOI:10.1289/ehp.1206004.
A.P. Ault, D. Zhao, C.J. Ebben, M.J. Tauber, F.M. Geiger, K.A. Prather, V.H. Grassian, "Raman microspectroscopy and vibrational sum frequency generation spectroscopy as probes of the bulk and surface compositions of size-resolved sea spray aerosol particles," Physical Chemistry Chemical Physics, 2013, 15, 6206-6214. DOI: 10.1039/C3CP43899F.
G. Rubasinghege and V.H. Grassian, "Role(s) of adsorbed water in the surface chemistry of environmental interfaces," Chemical Communications, 2013, 49, 3071-3094. DOI: 10.1039/C3CC38872G.
H. Chen, V.H. Grassian, L.V. Saraf, A. Laskin, "Chemical imaging analysis of environmental particles using the focused ion beam/scanning electron microscopy technique: microanalysis insights into atmospheric chemistry of fly ash," Analyst, 2013, 138, 451-460. DOI: 10.1039/C2AN36318F.
2012
R.A. Walker, K. Wilson, A.F. Lee, J. Woodford, V.H. Grassian, J. Baltrusaitis, G. Rubasinghege, G. Cibin, A. Dent, "Preservation of York Minster historic limestone by hydrophobic surface coatings," Scientific Reports, 2012, 2, 880, DOI:10.1038/srep00880.
J. Baltrusaitis, H. Chen, G. Rubasinghege, V.H. Grassian, "Heterogeneous Atmospheric Chemistry of Lead Oxide Particles with Nitrogen Dioxide Increases Lead Solubility: Environmental and Health Implications," Environmental Science & Technology, 2012, 46, 12806-12813. DOI: 10.1021/es3019572.
G. Rubasinghege, P.K. Kyei, M.M. Scherer, V.H. Grassian, "Proton-promoted dissolution of α-FeOOH nanorods and microrods: Size dependence, anion effects (carbonate and phosphate), aggregation and surface adsorption," Journal of Colloid and Interface Science, 2012, 385, 15-23, DOI:10.1016/j.jcis.2012.06.049.
H. Chen, C.E. Nanayakkara, V.H. Grassian, "Titanium dioxide photocatalysis in atmospheric chemistry," Chemical Reviews, 2012, 112, 5919-5948. DOI:10.1021/cr3002092.
O. Laskina, M.A. Young, P.D. Kleiber, V.H. Grassian, "Infrared extinction spectra of mineral dust aerosol: Single components and complex mixtures," Journal of Geophysical Research: Atmospheres, 2012, 117, D18210. DOI: 10.1029/2012JD017756.
H. Fu, J. Lin, G. Shang, W. Dong, V.H. Grassian, G.R. Carmichael, Y. Li, J. Chen, "Solubility of iron from combustion source particles in acidic media linked to iron speciation," Environmental Science & Technology, 2012, 46, 11119-11127. DOI: 10.1021/es302558m.
J. Baltrusaitis and V.H. Grassian, "Atomic Force Microscopy and X-ray Photoelectron Spectroscopy Study of NO2 Reactions on CaCO3 (101̅4) Surfaces in Humid Environments," Journal of Physical Chemistry A, 2012, 116, 9001-9009. DOI: 10.1021/jp305122d.
L. Klüser, P. Kleiber, T. Holzer-Popp, V.H. Grassian, "Desert dust observation from space–Application of measured mineral component infrared extinction spectra," Atmospheric Environment, 2012, 54, 419-427. DOI: 10.1016/j.atmosenv.2012.02.011.
A. Adamcakova-Dodd, L.V. Stebounova, P.T. O'Shaughnessy, J.S. Kim, V.H. Grassian, P.S. Thorne, "Murine pulmonary responses after sub-chronic exposure to aluminum oxide-based nanowhiskers," Particle and Fibre Toxicology, 2012, 9, 22. DOI:10.1186/1743-8977-9-22.
B. Meland, J.M. Alexander, C.S. Wong, V.H. Grassian, M.A. Young, P.D. Kleiber, "Evidence for particle size–shape correlations in the optical properties of silicate clay aerosol," Journal of Quantitative Spectroscopy and Radiative Transfer, 2012, 113, 549–558. DOI: 10.1016/j.jqsrt.2012.01.012.
L.A. Wijenayaka, G. Rubasinghege, J. Baltrusaitis, V.H. Grassian, "Surface chemistry of α-FeOOH nanorods and microrods with gas-phase nitric acid and water vapor: Insights into the role of particle size, surface structure, and surface hydroxyl groups in the adsorption and reactivity of α-FeOOH with atmospheric gases," Journal of Physical Chemistry C, 2012, 116, 12566-12577. DOI: 10.1021/jp301139x.
G. Rubasinghege and V.H. Grassian, "Surface-Catalyzed Chlorine and Nitrogen Activation: Mechanisms for the Heterogeneous Formation of ClNO, NO, NO2, HONO, and N2O from HNO3 and HCl on Aluminum Oxide Particle Surfaces,"Journal of Physical Chemistry A, 2012, 116, 5180-5192. DOI: 10.1021/jp301488b.
L.V. Stebounova, H. Morgan, V.H. Grassian, S. Brenner, "Health and safety implications of occupational exposure to engineered nanomaterials," Wiley Interdisciplinary Reviews: Nanomedicine and Nanobiotechnology, 2012, 4, 310-321. DOI:10.1002/wnan.174.
A.P. Ault, T.M. Peters, E.J. Sawvel, G.S. Casuccio, R.D. Willis, G.A. Norris, V.H. Grassian, "Single-particle SEM-EDX analysis of iron-containing coarse particulate matter in an urban environment: Sources and distribution of iron within Cleveland, Ohio," Environmental Science & Technology, 2012, 46, 4331-4339. DOI: 10.1021/es204006k.
I.A. Mudunkotuwa, J.M. Pettibone, V.H. Grassian, "Environmental implications of nanoparticle aging in the processing and fate of copper-based nanomaterials, Environmental Science & Technology, 2012, 46, 7001-7010. DOI: 10.1021/es203851d.
H. Chen, A. Laskin, J. Baltrusaitis, C.A. Gorski, M.M. Scherer, V.H. Grassian, "Coal fly ash as a source of iron in atmospheric dust," Environmental Science & Technology, 2012, 46, 2112-2120. DOI: 10.1021/es204102f.
K.M. Gierlus, O. Laskina, T.L. Abernathy, V.H. Grassian, "Laboratory study of the effect of oxalic acid on the cloud condensation nuclei activity of mineral dust aerosol," Atmospheric Environment, 2012, 46, 125-130. DOI: DOI: 10.1016/j.atmosenv.2011.10.027.
C.E. Nanayakkara, J. Pettibone, V.H. Grassian, "Sulfur dioxide adsorption and photooxidation on isotopically-labeled titanium dioxide nanoparticle surfaces: Roles of surface hydroxyl groups and adsorbed water in the formation and stability of adsorbed sulfite and sulfate,"Physical Chemistry Chemical Physics, 2012, 14, 6957-6966. DOI: 10.1039/C2CP23684B.
2011
I.A. Mudunkotuwa, T. Rupasinghe, C.M. Wu, V.H. Grassian, "Dissolution of ZnO nanoparticles at circumneutral pH: a study of size effects in the presence and absence of citric acid," Langmuir, 2011, 28, 396-403. DOI: 10.1021/la203542x.
H. Chen, C.O. Stanier, M.A. Young, V.H. Grassian, "A kinetic study of ozone decomposition on illuminated oxide surfaces," Journal of Physical Chemistry A, 2011, 115, 11979-11987. DOI: 10.1021/jp208164v.
J.S. Kim, A. Adamcakova-Dodd, P.T. O'Shaughnessy, V.H. Grassian, P.S. Thorne, "Effects of copper nanoparticle exposure on host defense in a murine pulmonary infection model," Particle and Fibre Toxicology, 2011, 8, 29. DOI: 10.1186/1743-8977-8-29.
J.G. Navea, M.A. Young, S. Xu, V.H. Grassian, C.O. Stanier, "The atmospheric lifetimes and concentrations of cyclic methylsiloxanes octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5) and the influence of heterogeneous uptake," Atmospheric Environment, 2011, 45, 3181-3191. DOI:10.1016/j.atmosenv.2011.02.038.
A.C. Reisetter, L.V. Stebounova, J. Baltrusaitis, L. Powers, A. Gupta, V.H. Grassian, M.M. Monick, "Induction of inflammasome-dependent pyroptosis by carbon black nanoparticles," Journal of Biological Chemistry, 2011, 286, 21844-21852. DOI: 10.1074/jbc.M111.238519.
J. Baltrusaitis, J. Schuttlefield, E. Zeitler, V.H. Grassian, "Carbon dioxide adsorption on oxide nanoparticle surfaces," Chemical Engineering Journal, 2011, 170, 471-481. DOI:10.1016/j.cej.2010.12.041.
CM Wu, J Baltrusaitis, EG Gillan, VH Grassian, "Sulfur dioxide adsorption on ZnO nanoparticles and nanorods," Journal of Physical Chemistry C,2011, 115, 10164-10172. DOI: 10.1021/jp201986j.
B. Meland, P.D. Kleiber, V.H. Grassian, M.A. Young, "Visible light scattering study at 470, 550, and 660nm of components of mineral dust aerosol: Hematite and goethite," Journal of Quantitative Spectroscopy and Radiative Transfer, 2011, 112, 1108-1118. DOI: 10.1016/j.jqsrt.2010.12.002.
S.W. Bian, I.A. Mudunkotuwa, T. Rupasinghe, V.H. Grassian, "Aggregation and dissolution of 4 nm ZnO nanoparticles in aqueous environments: influence of pH, ionic strength, size, and adsorption of humic acid," Langmuir, 2011, 27, 6059-6068. DOI: 10.1021/la200570n.
G. Rubasinghege, S.N. Spak, C.O. Stanier, G.R. Carmichael, V.H. Grassian, "Abiotic mechanism for the formation of atmospheric nitrous oxide from ammonium nitrate," Environmental Science & Technology, 2011, 45, 2691-2697. DOI: 10.1021/es103295v.
L.V. Stebounova, A. Adamcakova-Dodd, J.S. Kim, H. Park, P.T. O'Shaughnessy, V.H. Grassian, P.S. Thorne, "Nanosilver induces minimal lung toxicity or inflammation in a subacute murine inhalation model," Particle and Fibre Toxicology, 2011, 8, 5. DOI:10.1186/1743-8977-8-5.
H. Chen, J.G. Navea, M.A. Young, V.H. Grassian, "Heterogeneous photochemistry of trace atmospheric gases with components of mineral dust aerosol," Journal of Physical Chemistry A, 2011, 115, 490-499. DOI: 10.1021/jp110164j.
A. Adamcakova‐Dodd, P. S. Thorne, V. H. Grassian, "In Vivo Toxicity Studies of Metal and Metal Oxide Nanoparticles," General, Applied and Systems Toxicology, 2011. DOI: 10.1002/9780470744307.gat244.
S. Elzey, J. Baltrusaitis, S. Bian, V.H. Grassian, "Formation of paratacamite nanomaterials via the conversion of aged and oxidized copper nanoparticles in hydrochloric acidic media," Journal of Materials Chemistry, 2011, 21, 3162-3169. DOI: 10.1039/C0JM03705B.
I.A. Mudunkotuwa and V.H. Grassian, "The devil is in the details (or the surface): impact of surface structure and surface energetics on understanding the behavior of nanomaterials in the environment," Journal of Environmental Monitoring, 2011, 13, 1135-1144. DOI: 10.1039/C1EM00002K.
L.V. Stebounova, E. Guio, V.H. Grassian, "Silver nanoparticles in simulated biological media: a study of aggregation, sedimentation, and dissolution," Journal of Nanoparticle Research, 2011, 13, 233-244. DOI: 10.1007/s11051-010-0022-3.
J. Baltrusaitis, P.M. Jayaweera, V.H. Grassian, "Sulfur dioxide adsorption on TiO2 nanoparticles: Influence of particle size, coadsorbates, sample pretreatment, and light on surface speciation and surface coverage," Journal of Physical Chemistry C, 2011, 115, 492-500. DOI: 10.1021/jp108759b.
2010
G. Rugansinghege, R. Lentz, H. Park, M.M. Scherer, V.H. Grassian, “Nanorod Dissolution Quenched in the Aggregated State,” Langmuir, 2010, 26, 1524–1527. DOI: 10.1021/la903950e
J. Baltrusaitis and V.H. Grassian, “Carbonic Acid Formation from Reaction of Carbon Dioxide and Water Coordinated to Al(OH)3: A Quantum Chemical Study,” Journal of Physical Chemistry A, 2010 114, 2350-2356. DOI: 10.1021/jp9097809
S. Elzey and V.H. Grassian, “Agglomeration, Isolation and Dissolution of Commercially Manufactured Silver Nanoparticles in Aqueous Environments,” Journal of Nanoparticle Research, 2010, 12, 1945-1958. DOI: 10.1007/s11051-009-9783-y
H. Park and V. H. Grassian, “Commercially Manufactured Engineered Nanomaterials for Environmental and Health Studies: Important Insights Provided by Independent Characterization,” Environmental Toxicology and Chemistry, 2010 29, 715-721.
G. Rubasinghege, R.W. Lentz, S. Elzey, J. Baltrusaitis, P.M. Jayaweera, M.M. Scherer, V.H. Grassian, V.H. “Simulated Atmospheric Processing of Iron Oxyhydroxide Minerals at Low pH: Roles of Particle Size and Acid Anion in Iron Dissolution,” Proceedings of the National Academy of Sciences, 2010, 107, 6628-6633. DOI: 10.1073/pnas.0910809107
H. Fu, D. Cwiertny, G.R. Carmichael, M.M. Scherer, V.H. Grassian, “Photoreductive Dissolution of Fe-Containing Mineral Dust Particles in Acidic Media,” Journal of Geophysical Research: Atmospheres, 2010, 115, D11304 doi:10.1029/2009JD012702.
J.G. Navea, H. Chen, M. Huang, G. R. Carmichael, V.H. Grassian, “A Comparative Evaluation of Water Uptake on Several Mineral Dust Sources,” Environmental Chemistry, 2010, 7, 162–170. DOI: 10.1071/EN09122.
G. Rubasinghege, S. Elzey, J. Baltrusaitis, P.M. Jayaweera, V.H. Grassian, “Reactions on Atmospheric Dust Particles: Surface Photochemistry and Size-Dependent Nanoscale Redox Chemistry,” Journal of Physical Chemistry Letters (Invited Perspectives Article), 2010, 1, 1729–1737. DOI: 10.1021/jz100371d. See video http://pubs.acs.org/page/jpclcd/vicki-video.html
S. Gassó, V.H. Grassian, R.L. Miller, “Interactions between Mineral Dust, Climate and Ocean Ecosystems,” Elements, 2010, 6, 247-253. DOI: 10.2113/gselements.6.4.247.
S. Elzey and V.H. Grassian, “Nanoparticle Dissolution from the Particle Perspective: Insights on Nanoscale Processes from Particle Sizing Measurements,” Langmuir, 2010, 26, 12505–12508. DOI: 10.1021/la1019229.
B. Meland, P.D. Kleiber, V.H. Grassian, M.A. Young, “Correlated IR spectroscopy and visible light scattering measurements of mineral dust aerosol,” Journal of Geophysical Research: Atmospheres, 2010, 115, D20208, doi:10.1029/2010JD014389.
S.-W. Bian, J. Baltrusaitis, P. Galhotra, V.H. Grassian, “A Template-Free, Thermal Decomposition Method to Synthesize Mesoporous MgO with a Nanocrystalline Framework and Its Application in Carbon Dioxide Adsorption,” Journal of Materials Chemistry, 2010, 20, 8705-8710. DOI: 10.1039/C0JM01261K.
T.M. Peters and V.H. Grassian, “Engineered Nanomaterials” an invited book chapter in Patty's Industrial Hygiene, Sixth Edition, Eds. Vernon Rose and Barbara Cohrssen, John Wiley and Sons, 2010.
I. A. Mudunkotuwa and V.H. Grassian, “Citric Acid Adsorption on TiO2 Nanoparticles in Aqueous Suspensions at Acidic and Circumneutral pH: Surface Coverage, Surface Speciation and Its impact on Nanoparticle-Nanoparticle Interactions,” Journal of the American Chemical Society, 2010, 132, 14986–14994. DOI: 10.1021/ja106091q.
V. H. Grassian, “Size-dependent properties and surface chemistry of oxide-based nanomaterials in environmental processes,” A book chapter inNanoscale Materials in Chemistry: Environmental Applications, Eds. L.E. Erickson, R. T. Koodali, R. M. Richards, ACS Symposium Series 2010. DOI: 10.1021/bk-2010-1045.ch002.
2009
Elzey, S.; Larsen, R.G.; Howe, C.; Grassian, V.H. “Nanoscience and Nanotechnology: Environmental and Health Impacts” in Nanoscale Materials in Chemistry, 2nd Edition, Editors K.J. Klabunde and R. M. Richards, John Wiley and Sons, Hoboken, NJ 2009, 676-721.
Grassian, V. H. and Larsen, S.C. “Synthesis, Characterization and Environmental Applications of Nanocrystalline Zeolites” in The Oxford Handbook of Nanoscience and Nanotechnology Volume 2, University of Oxford Press, Oxford, UK 2009, 659-684.
H. Fairbrother, F. Geiger, V.H. Grassian, J. Hemminger, "Physical Chemistry of Environmental Interfaces," Journal of Physical Chemistry C, 2009, 113, 2035–2035. DOI: 10.1021/jp8097704. (Cover Article)
Cwiertny, D. M.; Hunter, G. J.; Pettibone, J. M.; Scherer, M. M. and Grassian, V. H., “Surface Chemistry and Dissolution of α-FeOOH Nanorods and Microrods: Environmental Implications of Size Dependent Interactions with Oxalate,” Journal of Physical Chemistry C, 2009, 113, 2175-2186. DOI: 10.1021/jp807336t.
Peters, T.: Elzey, S.; Johnson, R.; Park, H.; Grassian, V.H.; Maher, T.; O’Shaughnessy, P. T., “Airborne Monitoring to Distinguish Engineered Nanomaterials from Incidental Particles for Environmental Health and Safety,” Journal of Occupational & Environmental Hygiene, 2009, 6, 73-81. DOI: 10.1080/15459620802590058.
Galhotra, P.; Navea, J.; Larsen, S.C. and Grassian, V.H., “Carbon Dioxide (C16O2 and C18O2) Adsorption in Zeolite Y Materials: Effect of Cation, Adsorbed Water and Particle Size,” Energy & Environmental Science, 2009, 2, 401-409. DOI: 10.1039/B814908A.
Navea, N.G.; Stanier, C.O.; Young, M. A. and Grassian, V. H., “Heterogeneous Uptake of Octamethylcyclotetrasiolxane (D4) and Decamethylcyclopentasiloxane (D5) onto Mineral Dust Aerosol Under Variable RH Conditions,” Atmospheric Environment, 2009, 43, 4060-4069. DOI:10.1016/j.atmosenv.2009.05.012.
Navea, N.G.; Stanier, C.O.; Young, M. A. and Grassian, V. H. “Effect of Ozone and Relative Humidity on the Heterogeneous Uptake of Octamethylcyclotetrasiloxane and Decamethylcyclopentasiloxane on Model Mineral Dust Aerosol Components,” Journal of Physical Chemistry A, 2009, 113, 7030-7038. DOI: 10.1021/jp902192b.
Rubasinghege, G.; Grassian, V. H. “Photochemistry of Adsorbed Nitrate on Aluminum Oxide Particle Surfaces,” Journal of Physical Chemistry A, 2009, 113, 7818-7825. DOI: 10.1021/jp902252s.
Schmoll, L. H.; Elzey, S.; Grassian, V. H.; O’Shaughnessy, P. T.; Nanoparticle Aerosol Generation Methods from Bulk Powders for Inhalation Exposure Studies,” Nanotoxicology, 2009, 3, 265-275.
Grassian, V.H. “New Directions: Nanodust - A Source of Metals in the Atmospheric Environment?” Atmospheric Environment, 2009,43, 4666-4667. DOI: 10.1016/j.atmosenv.2009.06.032.
Baltrusaitis, J.; Jayaweera, P. M.; Grassian, V. H. “XPS Study of Nitrogen Dioxide Adsorption on Metal Oxide Particle Surfaces Under Different Environmental Conditions,” Physical Chemistry Chemical Physics 2009, 11, 8295 - 8305. DOI: 10.1039/B907584D.
Baltrusaitis, J.; Grassian, V. H. “Calcite (1014) Surface in Humid Environments,” Surface Science, 2009, 603, L99-L104. DOI: 10.1016/j.susc.2009.06.021.
Kleiber, P.D.; Grassian, V.H.; Young, M.A.; Hudson, P.K., "T-Matrix Studies of Aerosol Particle Shape Effects on IR Resonance Spectral Line Profiles and Comparison with an Experiment," Journal of Geophysical Research: Atmospheres, 2009, 114, DOI:10.1029/2009JD012710.
Hatch, C.D.; Gierlus, K.M.; Zahardis, J.; Schuttlefield, J., Grassian, V.H. “Water Uptake of Humic and Fulvic Acid: Measurements and Modeling Using Single Parameter Köhler Theory,” Environmental Chemistry 2009, 6, 380-388.
2008
Preszler Prince, A., Kleiber, P.D., Grassian, V. H., and Young, M. A., “Reactive Uptake of Acetic Acid on Calcite and Nitric Acid Reacted Calcite Aerosol in an Environmental Reaction Chamber,” Physical Chemistry Chemical Physics, 2008, 10, 142-152. DOI: 10.1039/B712915G.
Hudson, P.; Gibson, E.; Kleiber, P.D.; Young, M. A. and Grassian, V. H. “Coupled infrared extinction and size distribution measurements for several clay components of mineral dust aerosol,” Journal of Geophysical: Atmospheres, 2008, 113, D01201, doi:10.1029/2007JD008791.
Rahaman, A.; Grassian, V. H.; Margulis, C.J., “Dynamics of Water Adsorption on a Calcite Surface as a Function of Relative Humidity,” Journal of Physical Chemistry C, 2008, 112, 2109-2115. DOI: 10.1021/jp077594d.
Schuttlefield, J. and Grassian, V. H. “ATR-FTIR Spectroscopy in the Undergraduate Chemistry Laboratory. Part I: Fundamentals and Examples,” Journal of Chemical Education, 2008, 85, 279-281.DOI: 10.1021/ed085p279.
Schuttlefield, J., Larsen, S.C. and Grassian, V. H. “ATR-FTIR Spectroscopy in the Undergraduate Laboratory. Part II: Introduction of a Laboratory Experiment on Surface Adsorption,” Journal of Chemical Education, 2008, 85, 282-284. DOI: 10.1021/ed085p282.
Liu, Y.; Gibson, E. R.; Cain, J.P.; Wang, H.; Grassian, V. H.; Laskin, A. "Kinetics of Heterogeneous Reactions of CaCO3 Particles with HNO3 over a wide range of Humidity,” Journal of Physical Chemistry A, 2008, 112, 1561 -1571. DOI: 10.1021/jp076169h.
Mogili, P.K.; Yang, K.H.; Young, M. A.; Kleiber, P. D. and Grassian, V. H. “Extinction Spectra of Mineral Dust Aerosol Components in an Environmental Aerosol Chamber: IR Resonance Studies,” Atmospheric Environment, 2008, 42, 1752-1761. DOI: 10.1016/j.atmosenv.2007.11.026.
Cwiertny, D.M.; Baltrusaitis, J.; Hunter, G. J.; Laskin, A.; Scherer, M. M.; Grassian, V. H. “Characterization and Acid-Mobilization Study of Iron-Containing Mineral Dust Source Materials,” Journal of Geophysical: Atmospheres, 2008, 113, D05202, doi:10.1029/2007JD009332.
Cwiertny, D.M., Young, M.A. and Grassian, V. H. “Chemistry and photochemistry of mineral dust aerosol,” Annual Reviews of Physical Chemistry, 2008, 59, 27-51. DOI: 10.1146/annurev.physchem.59.032607.093630.
Curtis, D. B.; Aycibin, M.; Arnold, N.P.; Grassian, V. H.; Young, M. A.; Kleiber, P. D. "A Laboratory Investigation of Light Scattering from Representative Components of Mineral Dust Aerosol at a Wavelength of 550 nm,” Journal of Geophysical: Atmospheres, 2008, 113, DOI:10.1029/2007JD009387.
Cwiertny, D. M.; Handler, R. M.; Schaefer, M. V.; Grassian, V. H.Scherer, M. M. “Interpreting nanoscale size-effects in aggregated Fe-oxide suspensions: Reaction of Fe(II) with Goethite,” Geochimica et Cosmochimica Acta 2008, 72, 1365-1380. DOI: 10.1016/j.gca.2007.12.018.
Prather, K., Hatch, C. and Grassian, V. H. “Analysis of Atmospheric Aerosols,” Annual Reviews of Analytical Chemistry, 2008, 1, 485-514. DOI: 10.1146/annurev.anchem.1.031207.113030.
Elzey, S.; Mubayi, A.; Larsen, S.C. and Grassian, V. H. "FTIR Study of the Selective Catalytic Reduction of NO2 with Ammonia on Nanocrystalline NaY and CuY," Journal of Molecular Catalysis A: Chemical, 2008, 285, 48-57. DOI: 10.1016/j.molcata.2007.12.032.
Grassian, V.H.; O'Shaughnessy, P.T.; Adamcakova-Dodd, A.; Pettibone, J.M.; Thorne P.S. “Titanium dioxide nanoparticles: Grassian et al respond,” Environmental Health Perspectives, 2008, 116, A152-A153.
Pettibone J.B.; Elzey, S.; Grassian, V. H. “An Integrated Approach Toward Understanding the Environmental Fate, Transport, Toxicity and Health Hazards of Nanomaterials” a book chapter in Nanoscience and Nanotechnology: Environmental and Health Impacts, Ed. Vicki H. Grassian 2008, 43-68.
Hudson, P.K.; Young, M. A.; Kleiber, P.D.; and Grassian, V. H. “Coupled infrared extinction and size distribution measurements of several non-clay components of mineral dust aerosol (quartz, calcite, and dolomite)," Atmospheric Environment, 2008, 42, 5991-5999. DOI: 10.1016/j.atmosenv.2008.03.046.
Grassian, V. H. and Larsen, S.C. “Applications of Nanocrystalline Zeolites to CWA Decontamination,” V.H. Grassian, and S.C. Larsen book chapter in Nanoscience and Nanotechnology for Chemical and Biological Defense, Eds. R. Nagarajan, W. Zukas, T. A. Hatton, S. Lee, ACS Symposium Series Book (2009). Chapter DOI: 10.1021/bk-2009-1016.ch019.
Pettibone J. B.; Cwiertny, D. M.; Scherer, M. and Grassian, V.H. “Adsorption of Organic Acids on TiO2 Nanoparticles: Effects of pH, Nanoparticle Size and Nanoparticle Aggregation,” Langmuir, 2008, 24, 6659-6667. DOI: 10.1021/la7039916.
Hatch, C. D.; Gierlus, K. M.; Schuttlefield, J.D. and Grassian, V. H. “Water Adsorption and Cloud Condensation Nuclei Activity of Calcite and Calcite Coated with Model Humic and Fulvic Acids,” Atmospheric Environment, 2008,42, 5672-5684. DOI: 10.1016/j.atmosenv.2008.03.005.
Hatch C. D. and Grassian, V.H. “10th Anniversary Review: Applications of Analytical Techniques in Laboratory Studies of the Chemical and Climactic Impacts of Mineral Dust Aerosol in the Earth's Atmosphere,” Journal of Environmental Monitoring, 2008, 10, 919-934. DOI: 10.1039/B805153D.
Elzey, S.; Larsen, R.G.; Howe, C.; Grassian, V.H. “Nanoscience and Nanotechnology: Environmental and Health Impacts” in Nanoscale Materials in Chemistry, 2nd Edition, Editors K.J. Klabunde and R. M. Richards, John Wiley and Sons, Hoboken, NJ 2009, 676-721.
Grassian, V. H. and Larsen, S.C. “Synthesis, Characterization and Environmental Applications of Nanocrystalline Zeolites” in The Oxford Handbook of Nanoscience and Nanotechnology Volume 2, University of Oxford Press, Oxford, UK 2009, 659-684.
Grassian, V.H. “Surface Science of Complex Environmental Interfaces: Oxide and Carbonate Surfaces in Dynamic Equilibrium with Water Vapor,” Surface Science, 2008, 602, 2955-2962. DOI: 10.1016/j.susc.2008.07.039.
Schuttlefield, J.; Rubansinghege, G.; El-Maazawi, M.; Bone, J.; Grassian, V. H. “Photochemistry of Adsorbed Nitrate,” Journal of the American Chemical Society, 2008, 130, 12210–12211. DOI: 10.1021/ja802342m.
Grassian, V.H. “When Size Really Matters: Size-Dependent Properties and Surface Chemistry of Metal and Metal Oxide Nanoparticles in Gas and Liquid Phase Environments,” Journal of Physical Chemistry C, 2008, 112, 18303-18313. DOI: 10.1021/jp806073t.
Pettibone, J. M.; Adamcakova-Dodd, A.; Thorne, P. S.; O’Shaughnessy, P. T.; Weydert, J. A. and Grassian, V. H. “Inflammatory Response of Mice Following Inhalation Exposure to Iron and Copper Nanoparticles,” Nanotoxicology, 2008, 2, 189 - 204. DOI: 10.1080/17435390802398291.
Roca, M.; Zahardis, J.; Bone, J.; El-Maazawi, M.; Grassian, V. H. “310 nm Irradiation of Atmospherically Relevant Concentrated Aqueous Nitrate Solutions: Nitrite Production and Quantum Yields,” Journal of Physical Chemistry A, 2008, 112, 13275-13281. DOI: 10.1021/jp809017b.
T.M. Peters, S. Elzey, R. Johnson, H. Park, V.H. Grassian, T. Maher, P. O'Shaughnessy, "Airborne Monitoring to Distinguish Engineered Nanomaterials from Incidental Particles for Environmental Health and Safety," Journal of Occupational and Environmental Hygiene, 2008, 6, 73-81. DOI: 10.1080/15459620802590058.
2007
Grassian, V. H.; Adamcakova-Dodd, A.; Pettibone, J.B.; O’Shaughnessy, P.T.; Thorne, P. S. “Inflammatory response of mice to manufactured titanium dioxide nanoparticles: comparison of size effects through different exposure routes,” Nanotoxicology, 2007, 1, 211-226. DOI: 10.1080/17435390701694295.
Schuttlefield, J.D.; Cox, D.; and Grassian, V.H. “An Investigation of Water Uptake on Clays Minerals using ATR-FTIR Spectroscopy Coupled with Quartz Crystal Microbalance Measurements,“Journal of Geophysical: Atmospheres, 2007, 112, D21303, doi:10.1029/2007JD008973.
Baltrusaitis, J., Cwiertny, D. M. and Grassian, V. H. “Adsorption of sulfur dioxide on hematite and goethite particle surfaces," Physical Chemistry Chemical Physics, 2007, 9, 5542 - 5554. DOI: 10.1039/B709167B.
Mogili, P.K.; Yang, K.H.; Young, M. A.; Kleiber, P.D. and Grassian, V. H. “Environmental aerosol chamber studies of extinction spectra of mineral dust aerosol components: Broadband IR-UV extinction spectra,” Journal of Geophysical: Atmospheres, 2007, 112, D21204, doi:10.1029/2007JD008890.
Baltrusaitis, J.; Schuttlefield, J.; Zeitler, E.; Jensen, J. and Grassian, V. H. “Surface Reactions of Carbon Dioxide at the Adsorbed Water – Iron Oxide Interface,” Journal of Physical Chemistry C, 2007, 111, 14870 -14880. DOI: 10.1021/jp051868k.
Grassian V.H.; Meyer G.; Abruña, H., Ekem Achenie, L.; Allison, T.; Brunschwig, B.; Coates, G. W.; Ferry, J.; Garcia-Garibay, M.; Gardea-Torresdey, J.; Grey, C.P.; Huchison, J.; Li, C.-J.; Liotta, C.; Minteer, S.; Mueller, K.; Ragauskas, A.; Roberts, J.; Omuwunmi, S.; Schmehl, R.; Schneider, W.; Selloni, A.; Stair, P.; Stewart, J.; Tyson, J.; Voelker, B.; White, J.M.; Wood-Black, F.; Torn, D. “Viewpoint: Chemistry for a Sustainable Future,” Environmental Science and Technology, 2007, 41, 4840-4846. DOI: 10.1021/es0725798. (Cover Article)
Preszler Prince, A., Kleiber, P.D., Grassian, V. H. and Young, M. A. “Heterogeneous Interactions of Calcite Aerosol with Sulfur Dioxide and Sulfur Dioxide-Nitric Acid Mixtures,” Physical Chemistry Chemical Physics, 2007, 9, 3432-3439. DOI: 10.1039/B703296J.
Curtis D.B.; Aycibin, M.; Young, M. A. Grassian, V. H. and Kleiber, P.D.; “Simultaneous Measurement of Light Scattering Properties and Particle Size Distribution for Aerosols: Application to Ammonium Sulfate and Quartz Aerosol Particles,” Atmospheric Environment, 2007, 41, 4748-4758. DOI: 10.1016/j.atmosenv.2007.03.020.
Preszler-Prince, A., Kleiber, P.D., Grassian, V. H. , and Young, M. A. “Heterogeneous Conversion of Calcite Aerosol by Nitric Acid,” Physical Chemistry Chemical Physics, 2007, 9, 622-634. DOI: 10.1039/B613913B.
Baltrusaitis, J; Schuttlefield, J.; Jensen, J. H. and Grassian, V. H. “FTIR Spectroscopy Combined with Quantum Chemical Calculations to Investigate Adsorbed Nitrate on Aluminum Oxide Surfaces in the Presence and Absence of Co-Adsorbed Water," Physical Chemistry Chemical Physics, 2007, 9, 4970-4980. DOI: 10.1039/B705189A.
Gibson, E. R.; Gierlus, K. M.; Hudson, P. K.; and Grassian, V. H. “Generation of Internally Mixed Insoluble and Soluble Aerosol Particles to Investigate the Impact of Heterogeneous Processing in the Atmosphere on the CCN Activity of Mineral Dust Aerosol," Aerosol Science and Technology, 2007, 41, 914-924. DOI: 10.1080/02786820701557222.
Hudson, P. K.; Schwarz, J.; Baltrusaitis, J.; Gibson, E. R. and Grassian, V. H. “Spectroscopic Studies of Atmospherically Relevant Concentrated Aqueous Nitrate Solutions,” Journal of Physical Chemistry A, 2007, 111, 544-548. DOI: 10.1021/jp0664216.
Stout, S. C.; Larsen, S. C. and Grassian, V. H. “Adsorption, Desorption and Thermal Oxidation of 2-CEES on Nanocrystalline Zeolites,” Microporous and Mesoporous Materials, 2007, 100, 77–86. DOI: 10.1016/j.micromeso.2006.10.010.
Pettibone, J. M.; Baltrusaitis, J. and Grassian, V. H., “Chemical Properties of Oxide Nanoparticles: Surface Adsorption Studies from Gas and Liquid Phase Environments” invited chapter in Synthesis, Properties and Applications of Oxide Nanomaterials, Eds. J. A. Rodriguez and M. Fernandez-Garcia, John Wiley and Sons 2007, 335-351.
Grassian, V. H. O’Shaughnessy, P.; Pettibone, J., Dodd, A. And Thorne, P. “Inhalation Exposure Studies of Nanoparticulate Titanium Dioxide with a Primary Particle Size of 2 to 5 nm,” Environmental Health Perspectives, 2007,115, 397-402. DOI: 10.1289/ehp.9469.
Baltrusaitis, J.; Usher, C. R. and Grassian, V. H. “Reactions of Sulfur Dioxide on Calcium Carbonate Single Crystal and Particle Surfaces at the Adsorbed Water Carbonate Interface,” Physical Chemistry Chemical Physics, 2007, 9, 3011-3024. DOI: 10.1039/B617697F.
Schuttlefied, J.; Al-Hosney, H. A.; Zachariah, A. and Grassian, V. H, “ATR-FTIR Spectroscopy to Investigate Water Uptake and Phase Transitions in Atmospherically Relevant Particles,” Applied Spectroscopy, 2007, 61, 283-292 (selected for Cover Art).
Hudson, P. K.; Gibson, E. R.; Young, M. A.; Kleiber, P.; and Grassian, V. H. “Infrared Extinction Measurements with Measured Aerodynamic and Mobility Diameters” Aerosol Science and Technology, 2007, 41, 701-710.
Hudson, P.K.; Gibson, E. R.; Young, M. A.; Kleiber, P.D. and Grassian, V. H. "A Newly Designed and Constructed Instrument for Coupled Infrared Extinction and Size Distribution Measurements of Aerosols," Aerosol Science and Technology, 2007, 41, 701-710. DOI: 10.1080/02786820701408509.
Usher, C. R.; Baltrusaitis, J.; Grassian, V. H. “Spatially Resolved Product Formation in the Reaction of Formic Acid with Calcium Carbonate (101̄4): The Role of Step Density and Adsorbed Water-Assisted Ion Mobility," Langmuir, 2007, 23, 7039-7045. DOI: 10.1021/la062866+.
2006
Gibson, E.R.; Hudson, P. K. and Grassian, V. H. “Aerosol chemistry and climate: Laboratory Studies of the Carbonate Component of Mineral Dust and its Reaction Products," Geophys. Res. Lett., 2006, 33, L13811, DOI:10.1029/2006GL026386.
Mogili, P. K.; Kleiber, P.D.; Young, M. A. and Grassian, V. H. “N2O5 Hydrolysis on the Components of Mineral Dust and Sea Salt Aerosol: Comparison Study in an Environmental Aerosol Reaction Chamber,” Atmospheric Environment, 2006, 40, 7401-7408. DOI: 10.1016/j.atmosenv.2006.06.048.
Gibson, E. R.; Hudson, P. K.; Grassian, V. H. "Physicochemical Properties of Nitrate Aerosols: Implications for the Atmosphere," Journal of Physical Chemistry A, 2006, 110, 11785-11799. DOI: 10.1021/jp063821k. (Invited Feature Article and Cover Art).
Knagge, K.; Johnson, M.; Grassian, V. H. and Larsen, S. C. “Adsorption and Thermal Oxidation of DMMP in Nanocrystalline NaY,” Langmuir, 2006, 22, 11077-11084. DOI: 10.1021/la061341e.
Mogili, P. K.; Kleiber, P.D.; Young, M. A. and Grassian, V. H. “Heterogeneous Uptake of Ozone on Reactive Components of Mineral Dust Aerosol: An Environmental Aerosol Reaction Chamber Study,” Journal of Physical Chemistry A, 2006,110, 13799-13807. DOI: 10.1021/jp063620g.
Baltrusaitis, J.; Jensen, J. and Grassian, V. H., "FTIR Spectroscopy Combined with Isotope Labeling and Quantum Chemical Calculations to Investigate Adsorbed Bicarbonate Formation Following Reaction of Carbon Dioxide with Surface Hydroxyl Groups on Fe2O3 and Al2O3,” Journal of Physical Chemistry B, 2006, 110, 12005-12016. DOI: 10.1021/jp057437j.
2005
Johnson, E. R. and Grassian, V. H. “Environmental Catalysis of the Earth’s Atmosphere: Heterogeneous Reactions on Mineral Dust Aerosol” Environmental Catalysis, Ed. Vicki H. Grassian, CRC Publishing, Boca Raton, FL, 2005.
Li, G.; Larsen, S. C. and Grassian, V. H. “Catalytic Reduction of NO2 in Nanocrystalline NaY Zeolite,” Journal of Molecular Catalysis A: Chemical,2005, 227, 25-35. DOI: 10.1016/j.molcata.2004.10.002.
Al-Abadleh, H.A.; Al-Hosney, H. A. and Grassian, V. H. “Oxide and Carbonate Surfaces as Environmental Interfaces: The Importance of Water in Surface Composition and Surface Reactivity,” Journal of Molecular Catalysis A: Chemical, 2005, 228, 47-54. DOI: 10.1016/j.molcata.2004.09.059.
Song, W.; Li, G.H.; Grassian, V.H. and Larsen, S. C., “Development of Improved Materials for Environmental Applications: Nanocrystalline NaY Zeolites, Environmental Science and Technology, 2005, 39, 1214-1220. DOI: 10.1021/es049194z.
Al-Hosney, H. A.; Grassian, V. H. “Water, Sulfur Dioxide and Nitric Acid Adsorption on Calcium Carbonate: A Transmission and ATR-FTIR Study,”Physical Chemistry Chemical Physics, 2005, 7, 1266-1276. DOI: 10.1039/B417872F.
Laskin, A.; Wietsma, T. W.; Krueger, B. J.; Grassian, V. H. “Heterogeneous Chemistry of Individual Mineral Dust Particles with Nitric Acid. A Combined CCSEM/EDX, ESEM and ICP-MS Study,” Journal of Geophysical Research: Atmospheres, 2005, 110, D10208. DOI: 10.1029/2004JD005206, 1-15.
Schuttlefield, J. and Grassian, V. H. “Is a Picture Really Worth a Thousand Words? The Role of Scanning Probe Microscopy as an Educational Tool In the Chemistry Curriculum,” The Chemist, 2005, 82(1), 4-1to 4-19.
Song, W.; Grassian, V. H. and Larsen, S. C. “High Yield Method for Nanocrystalline Zeolite Synthesis” Chemical Communications, 2005, 2951-2953. DOI: 10.1039/B501768H.
Baltrusaitis, J. and Grassian, V. H. “Surface Reactions of Carbon Dioxide at the Adsorbed Water-Iron Oxide Interface,” Journal of Physical Chemistry B, 2005, 109, 12227-12230. DOI: 10.1021/jp051868k.
Li, G.; Larsen, S.C.; Grassian, V. H. “An FT-IR Study of NO2 Reduction in Nanocrystalline NaY Zeolite: Effect of Zeolite Crystal Size and Adsorbed Water,” Catalysis Letters, 2005, 103, 23-32. DOI: 10.1007/s10562-005-6498-2.
Song, W.; Woodward, J. F.; Grassian, V. H. and Larsen, S.C. “Microscopic and Macroscopic Characterization of Organosilane Functionalized Nanocrystalline NaZSM-5,” Langmuir, 2005, 21, 7009-7014. DOI: 10.1021/la050559i.
Johnson, E. R.; Sciegienka, J.; Carlos-Cuellar, S. and Grassian, V. H. “Heterogeneous Uptake of Gaseous Nitric Acid on Dolomite (CaMg(CO3)2) and Calcite (CaCO3) Particles: A Knudsen Cell Study Using Multiple, Single and Fractional Particle Layers,” Journal of Physical Chemistry A,2005, 109, 6901-6911. DOI: 10.1021/jp0516285.
Li, G.; Jones, C.A.; Grassian, V. H. and Larsen, S.C, "Selective Catalytic Reduction of NO2 with Urea in Nanocrystalline NaY Zeolite," Journal of Catalysis, 2005, 234, 401-413. DOI: 10.1016/j.jcat.2005.06.025.
Krueger, B. J.; Ross, J. and Grassian, V. H. “Formation of Microcrystals, Micropuddles and Other Spatial Inhomogenieties in Surface Reactions Under Ambient Conditions: An Atomic Force Microscopy Study of Water and Nitric Acid Adsorption on MgO(100) and CaCO3(1014),” Langmuir,2005, 21, 8793-8801. DOI: 10.1021/la051378j.
Al-Hosney, H. A.; Carlos-Cuellar, S.; Baltrusaitis, J. and Grassian, V.H. “Heterogeneous Uptake and Reactivity of Formic Acid on Calcium Carbonate Particles: A Knudsen Cell Reactor, FTIR and SEM Study,” Physical Chemistry Chemical Physics, 2005, 7, 3587-3595. DOI: 10.1039/B510112C. (Cover Article).
Song, W.; Grassian, V. H.; Larsen, S.C. “Fiber and Film Formation by Self-Assembly of Colloidal Silicalite-1 and Copper Coated Silicalite-1 Nanocrystals,” Microporous and Mesoporous Materials, 2005, 88, 77-83. DOI: 10.1016/j.micromeso.2005.08.023.
Alwy, H., Li, G.; Grassian, V. H. and Larsen, S.C. “Development of Nanocrystalline Zeolites as Environmental Catalysts,” invited chapter inNanotechnology and the Environment, (Ed. B. Karn) ACS Symposium Series 890, American Chemical Society, Washington DC, 2005, 277-283. DOI: 10.1021/bk-2005-0890.ch038.
2004
Larsen, S. C. and V. H. Grassian “Environmental Catalysts based on Nanocrystalline Zeolites” a book chapter in the Encyclopedia of Nanoscience and Nanotechnology, Eds. J. A. Schwarz, C. I. Contescu. K. Putyera, Marcell Dekker Publishing, Co., NY, 2004, 1137 – 1145 (Invited Chapter).
Song, W., Justice, R. E., Jones, C. A., Grassian, V. H., Larsen, S.C. “Size-dependent Properties of Nanocrystalline Silicalite Synthesized with Systematically Varied Crystal Sizes,” Langmuir, 2004, 20, 4696-4702. DOI: 10.1021/la049817m.
Al-Hosney, H. A. and Grassian, V. H. “Carbonic Acid: An Important Intermediate in the Surface Chemistry of Calcium Carbonate,” Journal of American Chemical Society, 2004, 126, 8068-8069. DOI: 10.1021/ja0490774.
Grassian, V. H. “An Integrated Environmental Chemical Sciences Degree Program,” Chemical Educator, 2004, 9, 384 – 388. DOI: 10.133/s000897040842a.
Krueger, B. J., Grassian, V. H. , Laskin, A. and J. Cowin “Heterogeneous Chemistry of Individual Mineral Dust Particles from Different Dust Source Regions: The Importance of Particle Mineralogy,” Atmospheric Environment, 2004, 38, 6253-6261. DOI: 10.1016/j.atmosenv.2004.07.010.
Song, W., Kanthasamy, R., Grassian, V.H. Larsen, S.C. “Hexagonal, Hollow, Aluminum-Containing ZSM-5 Tubes Prepared from Mesoporous Silica Templates,” Chemical Communications, 2004, 1920-1921. DOI: 10.1039/B406753C.
Song, W., Justice, R. E., Jones, C. A., Grassian, V.H. and Larsen, S. C., "Synthesis, Characterization and Adsorption Properties of Nanocrystalline ZSM-5," Langmuir, 2004, 20, 8301-8306. DOI: 10.1021/la049516c.
Tang, T., G.R. Carmichae1, J.H. Seinfeld, D. Dabdub, R.J. Weber, B. Huebert, A.D. Clarke, S.A. Guazzotti, D.A. Sodeman, K.A. Prather, I. Uno, J.-H. Woo, J.J. Yienger, D.G. Streets, P.K. Quinn, J.E. Johnson, C.-H. Song, V.H. Grassian, A. Sandu, R.W. Talbot and J.E. Dibb, "Three-dimensional Simulations of Inorganic Aerosol Distributions in East Asia During Spring 2001," Journal of Geophysical Research: Atmospheres,2004, 109, D19S23, DOI:10.1029/2003JD004201.
2003
Grassian, V. H. and Larsen, S.C. “Photooxidation of Hydrocarbons in Cation-Exchanged Zeolites” A chapter in Handbook of Photochemistry and Photobiology, Volume 3, 451-494, 2003 Ed. H.S. Nalwa, American Scientific Publishers (Invited Review Article).
Al-Abadleh, H. A. and Grassian, V. H., “FT-IR Study of Water Adsorption on Aluminum Oxide Surfaces,” Langmuir, 2003, 19, 341-347. DOI: 10.1021/la026208a.
Li, G H., Xu, M., Grassian, V. H. and Larsen, S. C. “Photooxidation of Cyclohexane and Cyclohexene in Zeolite Y,” Journal Molecular Catalysis A,2003, 194, 169-180.
Krueger, B. J., Grassian, V. H., Laskin, A. and Cowin, J. P., “The Transformation of Solid Atmospheric Particles into Liquid Droplets through Heterogeneous Chemistry: Laboratory Insights into the Processing of Calcium Containing Mineral Dust Aerosol in the Troposphere,” Geophysical Research Letters, 2003 30, 1148. DOI 10.1029/2002GL016563.
Carlos-Cuellar, S, Christensen, A.P., Burrichter, C., Li, P. and Grassian, V. H. “Heterogeneous Uptake Kinetics of Volatile Organic Compounds on Oxide Surfaces Using a Knudsen Cell Reactor: Adsorption of Acetic Acid, Formaldehyde and Methanol on α-Fe2O3, α-Al2O3, and SiO2,” Journal of Physical Chemistry A, 2003, 107, 4250-4261. DOi: 10.1021/jp0267609.
Michel, A. E., Usher, C. R. and Grassian, V. H. “Reactive Uptake of Ozone on Mineral Oxides and Mineral Dusts,” Atmospheric Environment,2003, 37, 3201-3211. DOI: 10.1016/S1352-2310(03)00319-4.
Krueger, B. J., Grassian, V. H., Iedema, M. J., Cowin, J. P. and Laskin, A. “Probing Heterogeneous Chemistry of Individual Atmospheric Particles Using Scanning Electron Microscopy,” Analytical Chemistry, 2003, 75, 5170-5179. DOI: 10.1021/ac034455t.
Al-Abadleh, H. A. and Grassian, V. H., “Phase Transitions in Thin Magnesium Nitrate Films: A Transmission FT-IR Study of the Deliquescence and Efflorescence of Nitric Acid Reacted Magnesium Oxide Interfaces,” Journal of Physical Chemistry B, 2003, 107, 10829-10839. DOI: 10.1021/jp0275692.
Usher, C. R., Michel, A. E. Stec,, D. and Grassian, V. H., “Laboratory Studies of Ozone Uptake on Processed Mineral Dust,” Atmospheric Environment, 2003, 37, 5337-5347. DOI: 10.1016/j.atmosenv.2003.09.014.
Al-Abadleh, H.A. Krueger, B.J., Ross, J. L. and Grassian, V. H., “Phase Transitions in Calcium Nitrate Thin Films,” Chemical Communications,2003, 2796-2797. DOI: 10.1039/B308632A.
Al-Abadleh, H. A. and V. H. Grassian “Oxide Surfaces as Environmental Interfaces,” Surface Science Reports, 2003, 52, 63-161. DOI: 10.1016/j.surfrep.2003.09.001. (Invited Review Article).
Usher, C. R., Michel, A. and Grassian, V. H. “Reactions on Mineral Dust,” Chemical Reviews, 2003, 103, 4883-4940. DOI: 10.1021/cr020657y. (Invited Review Article).
2002
Li, P., Al-Abadleh, H. A. and Grassian, V. H. "Measuring Heterogeneous Uptake on Solid Particle Surfaces with a Knudsen Cell Reactor: Complications Due to Surface Saturation and Gas Diffusion," Journal of Physical Chemistry A, 2002, 106, 1210-1219. DOI: 10.1021/jp011828q.
Grassian, V. H. “Chemical Reactions of Nitrogen Oxides on the Surface of Oxide, Carbonate, Soot and Mineral Dust Particles: Implications for the Chemical Balance of the Troposphere,” Journal of Physical Chemistry A, 2002, 106, 860-877. DOI: 10.1021/jp012139h. (Invited Feature Article).
Usher, C. R., Al-Hosney, H., Carlos-Cuellar, S., and Grassian, V. H., “A Laboratory Study of the Heterogenous Uptake and Oxidation of Sulfur Dioxide on Mineral Dust Particles,” Journal of Geophysical Research: Atmospheres, 2002, 107, 4713. DOI 10.1029/2002JD002051.
Michel, A. E.; Usher, C. R. and Grassian, V. H. “Heterogeneous and Catalytic Uptake of Ozone on Mineral Oxides and Dust: A Knudsen Cell Investigation” Geophysical Research Letters, 2002, 29, 10-1 to 10-4. DOI 10.1029/2001GL014304.
Preszler Prince, A., J. Wade, J., Grassian, V. H., Kleiber,P. and Young, M. A., “Heterogeneous Reactions of Soot Aerosols with Nitrogen Dioxide and Nitric Acid Studied in an Atmospheric Chamber,” Atmospheric Environment, 2002, 36, 5729-5740. DOI: 10.1016/S1352-2310(02)00626-X.
2001
Grassian, V. H. "Heterogeneous Uptake and Reaction of Nitrogen Oxides and Volatile Organic Compounds on the Surface of Atmospheric Particles Including Oxide, Carbonate, Soot and Mineral Dust: Implications for the Chemical Balance of the Troposphere," International Reviews of Physical Chemistry 2001, 20, 467-548. DOI: 10.1080/01442350110051968. (Invited Review Article).
Goodman, A. L.; Li, P.; Usher, C.R.. and Grassian, V. H. "Heterogeneous Reaction of Sulfur Dioxide on Aluminum and Magnesium Oxide Particles," Journal of Physical Chemistry A, 2001, 105, 6109-6120. DOI: 10.1021/jp004423z.
Goodman, A. L.; Bernard, E.B. and Grassian, V. H. "A Spectroscopic Study of Nitric Acid and Water Adsorption on Oxide Particles: Enhanced Nitric Acid Uptake Kinetics in the Presence of Adsorbed Water," Journal of Physical Chemistry A, 2001, 105, 6443-6457. DOI: 10.1021/jp003722l.
Underwood, G. M., Li, P., Al-Abadleh, H. and Grassian V.H. “A Knudsen Cell Study of the Heterogeneous Reactivity of Nitric Acid on Oxide and Mineral Dust Particles," Journal of Physical Chemistry A, 2001, 105, 6609-6620. DOI: 10.1021/jp002223h.
Larsen, R. G., Saladino, A. C., Hunt, T. A., Mann, J. E., Xu, M., Grassian, V. H. and Larsen, S. R. "A Kinetic Study of the Thermal and Photochemical Partial Oxidation of Cyclohexane with Molecular Oxygen in Zeolite Y," Journal of Catalysis, 2001, 204, 440-449. DOI: 10.1006/jcat.2001.3403.
2000
H. Al-Abadleh and V.H. Grassian, “Heterogeneous reaction of NO2 on hexane soot: A Knudsen cell and FT-IR study,” Journal of Physical Chemistry A, 2000, 104, 11926-11933. DOI: 10.1021/jp002918i.
A.L. Goodman, G.M. Underwood, V.H. Grassian, “A laboratory study of the heterogeneous reaction of nitric acid on calcium carbonate particles, ”Journal of Geophysical Research: Atmospheres, 2000, 105, 29053-29064. DOI: 10.1029/2000JD900396.
A.G. Panov, R.G. Larsen, N.I. Totah, S.C. Larsen, V.H. Grassian, “Photooxidation of toluene and p-xylene in cation-exchanged zeolites X, Y, ZSM-5, and beta: the role of zeolite physicochemical properties in product yield and selectivity,” Journal of Physical Chemistry B, 2000, 104, 5706-5714. DOI: 10.1021/jp000831r.
M. El-Maazawi, A.N. Finken, A.B. Nair, V.H. Grassian, “Adsorption and Photocatalytic Oxidation of Acetone on TiO2: An in Situ Transmission FT-IR Study,” Journal of Catalysis, 2000, 191, 138-146. DOI: 10.1006/jcat.1999.2794.
G.M. Underwood, P. Li, C.R. Usher, V.H. Grassian, “Determining accurate kinetic parameters of potentially important heterogeneous atmospheric reactions on solid particle surfaces with a Knudsen cell reactor,” Journal of Physical Chemistry A, 2000, 104, 819-829. DOI: 10.1021/jp9930292.
S.R. Carlo and V.H. Grassian, “Temperature-programmed desorption and reflectance absorption infrared spectroscopy of H2O: HBr thin films of varying stoichiometry from <1:1 to 5:1,” Journal of Physical Chemistry B, 2000, 104, 86-92. DOI: 10.1021/jp992451f.
1999
A.L. Goodman, G.M. Underwood, V.H. Grassian, “Heterogeneous reactions of NO2: Characterization of gas-phase and adsorbed products from the reaction, 2NO2(g)+ H2O(a) → HONO(g) + HNO3(a) on hydrated silica particles,” Journal of Physical Chemistry A, 1999, 103, 7217-7223. DOI: 10.1021/jp9910688.
G.M. Underwood, T.M. Miller, V.H. Grassian, “Transmission FT-IR and Knudsen cell study of the heterogeneous reactivity of gaseous nitrogen dioxide on mineral oxide particles,”Journal of Physical Chemistry A, 1999, 103, 6184-6190. DOI: 10.1021/jp991586i.
P. Li, Y. Xiang, V.H. Grassian, S.C. Larsen, “CO adsorption as a probe of acid sites and the electric field in alkaline earth exchanged zeolite beta using FT-IR and ab initio quantum calculations,” Journal of Physical Chemistry B, 1999, 103, 5058-5062. DOI: 10.1021/jp9902093
Y. Xiang, S.C. Larsen, V.H. Grassian, “Photooxidation of 1-alkenes in zeolites: a study of the factors that influence product selectivity and formation,” Journal of the American Chemical Society, 1999, 121, 5063-5072. DOI: 10.1021/ja984477a.
1998
T.M. Miller and V.H. Grassian, “Heterogeneous chemistry of NO2 on mineral oxide particles: Spectroscopic evidence for oxide‐coordinated and water‐solvated surface nitrate,” Geophysical Research Letters, 1998, 25, 3835-3838. DOI: 10.1029/1998GL900011.
A.L. Goodman, T.M. Miller, V.H. Grassian, “Heterogeneous reactions of NO2 on NaCl and Al2 O3 particles,” Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 1998, 16, 2585-2590. DOI: 10.1116/1.581386.
M.D. Driessen, T.M. Miller, V.H. Grassian, “Photocatalytic oxidation of trichloroethylene on zinc oxide: characterization of surface-bound and gas-phase products and intermediates with FT-IR spectroscopy,” Journal of Molecular Catalysis A: Chemical, 1998, 131, 149-156. DOI: 10.1016/S1381-1169(97)00262-8.
M.D. Driessen and V.H. Grassian, “Adsorption and reaction of ethyl fragments on reduced and oxidized silica-supported copper particles,”Langmuir, 1998, 14, 1411-1418. DOI: 10.1021/la970721k.
M.D. Driessen and V.H. Grassian, “Photooxidation of trichloroethylene on Pt/TiO2,” Journal of Physical Chemistry B, 1998, 102, 1418-1423. DOI: 10.1021/jp9724075.
M.D. Driessen, A.L. Goodman, T.M. Miller, G.A. Zaharias, V.H. Grassian, “Gas-phase photooxidation of trichloroethylene on TiO2 and ZnO: Influence of trichloroethylene pressure, oxygen pressure, and the photocatalyst surface on the product distribution,” Journal of Physical Chemistry B, 1998, 102, 549-556. DOI: 10.1021/jp972351e.
1997
K.B. Myli, S.C. Larsen, V.H. Grassian, “Selective photooxidation reactions in zeolites X, Y and ZSM-5,” Catalysis Letters, 1997, 48, 199-202. DOI: 10.1023/A:1019008027598.
T.M. Miller and V.H. Grassian, “A mechanistic study of nitrous oxide adsorption and decomposition on zirconia,” Catalysis Letters, 1997, 46, 213-221. DOI: 10.1023/A:1019058232683.
S.R. Carlo and V.H. Grassian, ”RAIRS and TPD study of the direct photopolymerization of styrene thin films in ultrahigh vacuum,” Langmuir,1997, 13, 2307-2313. DOI: 10.1021/la960979v.
M.D. Driessen and V.H. Grassian, ”A comprehensive study of the reactions of methyl fragments from methyl iodide dissociation on reduced and oxidized silica-supported copper nanoparticles,” Journal of the American Chemical Society, 1997, 119, 1697-1707. DOI: 10.1021/ja9633833.
1996
J.D. Graham, J.T. Roberts, L.D. Anderson, V.H. Grassian, “The 367 nm photochemistry of OClO thin films and OClO adsorbed on ice,” Journal of Physical Chemistry, 1996, 100, 19551-19558. DOI: 10.1021/jp962054u.
M.D. Driessen and V.H. Grassian, “Methyl spillover on silica-supported copper catalysts from the dissociative adsorption of methyl halides," Journal of Catalysis, 1996, 161, 810-818. DOI: 10.1006/jcat.1996.0244.
K.C. McGee, M.D. Driessen, V.H. Grassian, “Infrared Study of the Adsorption and Reaction of MethylChloride and Methyl Iodide on Silica-Supported Pt Catalysts,” Journal of Catalysis, 1996, 159, 69-82. DOI: 10.1006/jcat.1996.0065.
1995
K.C. McGee, M.D. Driessen, V.H. Grassian, “Ethyl chloride decomposition on oxide-supported platinum catalysts,” Journal of Catalysis, 1995,157, 730-739. DOi: 10.1006/jcat.1995.1339.
T.M. Miller and V.H. Grassian, “Adsorption and decomposition of nitrous oxide on zirconia nanoparticles,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1995, 105, 113-122. DOI: 10.1016/0927-7757(95)03299-7.
M.D. Driessen and V.H. Grassian, “Spectroscopic evidence for methyl spillover on silica-supported copper catalysts,” Langmuir, 1995, 11, 4213-4216. DOI: 10.1021/la00011a009.
M.D. Driessen and V.H. Grassian, “Oxidation of methyl to methoxy group on oxidized Cu/SiO2,” Journal of Physical Chemistry, 1995, 99, 16519-16522. DOI: 10.1021/j100045a006.
K.B. Myli, S.R. Coon, V.H. Grassian, “Photon-induced reactions of aromatics adsorbed on rough and smooth silver surfaces,” Journal of Physical Chemistry, 1995, 99, 16407-16415. DOI: 10.1021/j100044a031.
S.R. Coon, K.B. Myli, V.H. Grassian, “Photoproduct characterization and dynamics in the 248 nm photolysis of CH3I thin films on Ag (111),”Journal of Physical Chemistry, 1995, 99, 16416-16424. DOI: 10.1021/j100044a032.
T.M. Miller and V.H. Grassian, “Environmental catalysis: adsorption and decomposition of nitrous oxide on zirconia,” Journal of the American Chemical Society, 1995, 117, 10969-10975. DOI: 10.1021/ja00149a020.
K.B. Myli and V.H. Grassian, “Adsorption and Reaction of Trifluoromethyl Iodide on Ni (111),” Journal of Physical Chemistry, 1995, 99, 5581-5587. DOI: 10.1021/j100015a048.
K.B. Myli and V.H. Grassian, “Atomic iodine desorption from single crystal nickel surfaces,” Langmuir, 1995, 11, 849-852. DOI: 10.1021/la00003a028.
K.B. Myli and V.H. Grassian, “Reactions of Trifluoromethyl Iodide on Ni (100)” Journal of Physical Chemistry, 1995, 99, 1498-1504. DOI: 10.1021/j100005a021.
V.H. Grassian, “The Chemistry of Metal CVD,” Journal of the American Chemical Society, 1995, 117, 3316-3316. DOI: 10.1021/ja00116a600.
1994-1983
D.D. Armentrout, V.H. Grassian, “Vibrational Spectroscopy of CFx (x= 2 and 3) Groups Adsorbed on Pt (111),” Langmuir, 1994, 10, 2071-2076. DOI: 10.1021/la00019a009.
K.B. Myli, V.H. Grassian, “Effect of Surface Roughness on the Photodissociation Threshold of Chlorobenzene and 3-Chloropyridine Adsorbed on Silver,” Journal of Physical Chemistry, 1994, 98, 6237-6240. DOI: 10.1021/j100076a001.
K.C. McGee, A.T. Capitano, V.H. Grassian, “Effect of adsorption on a Fermi resonance,” Langmuir, 1994, 10, 632-634. DOI: 10.1021/la00015a007.
W. Turney, Y.M. Hung, S.G. Starcevich, P.S. Cardinahl, V.H. Grassian, K.A. Singmaster, “Pulsed laser-assisted chemical vapor deposition of tungsten, molybdenum, and vanadium thin films,” Chemistry of Materials, 1992, 6, 1192-1199. DOI: 10.1021/cm00024a017.
V.H. Grassian, E.R. Bernstein, H.V. Secor, J.I. Seeman, “Spectroscopy and structure of jet-cooled α-methylstyrene,” Journal of Physical Chemistry, 1990, 94, 6691-6695. DOI: 10.1021/j100380a032.
H.S. Im, V.H. Grassian, E.R. Bernstein, “Supersonic jet studies of fluorene clustered with water, ammonia, and piperidine,” Journal of Physical Chemistry, 1990, 94, 222-227. DOI: 10.1021/j100364a036.
V.H. Grassian, E.R. Bernstein, H.V. Secor, J.I. Seeman, “Conformational study of jet-cooled styrene derivatives: demonstration of the planarity of nonsterically hindered styrenes,” Journal of Physical Chemistry, 1989, 93, 3470-3474. DOI: 10.1021/j100346a022.
V.H. Grassian, J.A. Warren, E.R. Bernstein, H.V. Secor, “Conformational changes upon S1← S0 excitation in 4‐dimethylaminobenzonitrile and some of its chemical analogs,” Journal of Chemical Physics, 1989, 90, 3994-3999. DOI: 10.1063/1.455809.
J.I. Seeman, H.V. Secor, P.J. Breen, V.H. Grassian, E.R. Bernstein, “A study of nonrigid aromatic molecules. Observation and spectroscopic analysis of the stable conformations of various alkylbenzenes by supersonic molecular jet laser spectroscopy,” Journal of the American Chemical Society, 1989, 111, 3140-3150. DOI: 10.1021/ja00191a005.
J.I. Seeman, V.H. Grassian, E.R. Bernstein, “Observation and geometry assignment of conformations of styrenes in the ground and first excited singlet state," Journal of the American Chemical Society, 1988, 110, 8542-8543. DOI: 10.1021/ja00233a039.
V.H. Grassian, G.C. Pimentel, “The structures of cis‐and trans‐dichloroethenes adsorbed on Pt (111),” Journal of Chemical Physics, 1988, 88, 4478-4483. DOI: 10.1063/1.453806.
V.H. Grassian, G.C. Pimentel, “Photochemical reactions of cis‐and trans‐1, 2‐dichloroethene adsorbed on Pd (111) and Pt (111),” Journal of Chemical Physics, 1988, 88, 4484-4491. DOI: 10.1063/1.453807.
V.H. Grassian, E.L. Muetterties, “Vibrational electron energy loss spectroscopic study of benzene, toluene, and pyridine adsorbed on palladium (111) at 180 K,” Journal of Physical Chemistry, 1987, 91, 389-396. DOI: 10.1021/j100286a028.
V.H. Grassian, E.L. Muetterties, “Electron energy loss and thermal desorption spectroscopy of pyridine adsorbed on platinum (111),” Journal of Physical Chemistry, 1986, 90, 5900-5907. DOI: 10.1021/j100280a088.
T.M. Gentle, V.H. Grassian, D.G. Klarup, E.L. Muetterties, “Catalytic chemistry of palladium surfaces under ultrahigh-vacuum conditions,” Journal of the American Chemical Society, 1983, 105, 6766-6767. DOI: 10.1021/ja00360a063.
G.W. Brady, D.B. Fein, H. Lambertson, V.H. Grassian, D. Foos, C.J. Benham, "X-Ray Scattering from the Superhelix in Circular DNA,"Proceedings of the National Academy of Sciences, 1983, 80, 741-744.
V.H. Grassian, G.W. Brady, C.J. Benham, "X-Ray Conformational Study of DNA Duplex in Solution," Biopolymers, 1983, 22, 1523-1544. DOI: 10.1002/bip.360220608.