Multiple Coordination Exchange for Room-Temperature Activation of Open Metal Sites in Metal-Organic Frameworks
Multiple Coordination Exchange for Room-Temperature Activation of Open Metal Sites in Metal-Organic Frameworks
Citing Articles
2017 {3}
· Artur Chołuj, Nicolai Nikishkin, and Michał Jan Chmielewski, "Facile post-synthetic deamination of MOFs and the synthesis of the missing parent compound of the MIL-101 family", Chem. Commun. 53, 10196-10199 (2017).
· Michael Ko, Aylin Aykanat, Merry K. Smith, and Katherine A. Mirica, "Drawing Sensors with Ball-Milled Blends of Metal-Organic Frameworks and Graphite", Sensors 17, 2192 (2017).
· Krzysztof M. Zwoliński and Michał J. Chmielewski, "TEMPO-Appended Metal-Organic Faameworks as Highly Active, Selective, and Reusable Catalysts for Mild Aerobic Oxidation of Alcohols", ACS Appl. Mater. Interfaces 9, 33956-33967 (2017).
2018 {14}
· Jungho Lim, Eun Ji Lee, Jae Sun Choi, and Nak Cheon Jeong, "Diffusion-Control in the In Situ Synthesis of Iconic Metal-Organic Frameworks within an Ionic Polymer Matrix", ACS Appl. Mater. Interfaces 10, 3793-3800 (2018).
· Junyi Yang, Xiao Feng, Guangnong Lu, Yulin Li, Chaochao Mao, Zhongliang Wen, and Wenbing Yuan, "NaCl as a solid solvent to assist the mechanochemical synthesis and post-synthesis of hierarchical porous MOFs with high I2 vapour uptake", Dalton Trans. 47, 5065-5071 (2018).
· Jae Sun Choi, Jinhee Bae, Eun Ji Lee, and Nak Cheon Jeong, "A Chemical Role for Trichloromethane: Room-Temperature Removal of Coordinated Solvents from Open Metal Sites in the Copper-Based Metal-Organic Frameworks", Inorg. Chem. 57, 5255-5231 (2018).
· Sixia Wanga, Yuan Lv, Youjin Yao, Huijun Yu, and Guang Lu, "Modulated synthesis of monodisperse MOF-5 crystals with tunable sizes and shapes", Inorg. Chem. Commun. 93, 55-60 (2018).
· Alexander C. Elder, Souryadeep Bhattacharyya, Sankar Nair, and Thomas M. Orlando, "Reactive Adsorption of Humid SO2 on Metal-Organic Framework Nanosheets", J. Phys. Chem. C 122, 10413-10422(2018).
· Xueliang Mu, Yipei Chen, Edward Lester, Tao Wu, "Optimized synthesis of nano-scale high quality HKUST-1 under mild conditions and its application in CO2 capture", Micropor. Mesopor. Mat. 270, 249-257 (2018).
· Johnson Efome, Dipak Rana, Takeshi Matsuura, and Christopher Q. Lan, "Insight Studies on Metal-Organic Framework Nanofibrous Membrane Adsorption and Activation for Heavy Metal Ions Removal from Aqueous Solution", ACS Appl. Mater. Interfaces 10, 18619-18629 (2018).
· Jinhee Bae, Eun Ji Lee, and Nak Cheon Jeong, "Metal coordination and metal activation abilities of commonly unreactive chloromethanes toward metal-organic frameworks", Chem. Commun. 54, 6458-6471 (2018).
· Angelo Kirchon, Gregory S. Day, Yu Fang, Sayan Banerjee, Osman K. Ozdemir, and Hong-Cai Zhou, "Suspension Processing of Microporous Metal-Organic Frameworks: A Scalable Route to High-Quality Adsorbents", iScience 5, 30-37 (2018).
· Joshua D. Sosa, Timothy F. Bennett, Katherine J. Nelms, Brandon M. Liu, Roberto C. Tovar, and Yangyang Liu, "Metal-Organic Framework Hybrid Materials and Their Applications", Crystals 8, 325 (2018).
· Sunhyun Hwang, Eun Ji Lee, Dahae Song, and Nak Cheon Jeong, "High Proton Mobility with High Directionality in Isolated Channels of MOF-74", ACS Appl. Mater. Interfaces. 10, 35354-35360 (2018).
· Stefano Canossa, Paolo Pelagatti, and Alessia Bacchi, "Drinking and Breathing: Solvent Coordination-driven Plasticity of IRMOF-9", Isr. J. Chem. 58, 1131-1137 (2018).
· Ruth Antwi-Baah and Heyang Liu, "Recent Hydrophobic Metal-Organic Frameworks and Their Applications", Materials 11, 2250 (2018).
· Ning Yuan, Tamara L. Church, Erik G. Brandt, Niklas Hedin, Xiaodong Zou, and Diana Bernin, "Insights into Functionalization of Metal-Organic Frameworks Using In Situ NMR Spectroscopy", Sci. Rep. 8, 17530 (2018).
2019 {10}
· Jiandong Pang, Shuai Yuan, Jun-Sheng Qin, Christina Lollar, Ning Huang, Jialuo Li, Qi Wang, Mingyan Wu, Daqiang Yuan, Maochun Hong, and Hong-Cai Zhou, "Tuning the Ionicity of Stable Metal-Organic Frameworks through Ionic Linker Installation", J. Am. Chem. Soc. 141, 3129-3136 (2019).
· Wen-Jing Liu, Long-Zhang Dong, Run-Han Li, Yong-Jun Chen, Sheng-Nan Sun, Shun-Li Li, and Ya-Qian Lan, "Different Protonic Species on Affecting Proton-Conductivity in Hollow Sphere-Like Polyoxometalates", ACS Appl. Mater. Interfaces 11, 7030-7036 (2019).
· Jonathan Cortés-Súarez, Vanessa Celis-Arias, Hiram I. Beltrán, Adriana Tejeda-Cruz, Ilich A. Ibarra, Josué E. Romero-Ibarra, Elí Sánchez-González, and Sandra Loera-Serna, "Synthesis and Characterization of an SWCNT@HKUST-1 Composite: Enhancing the CO2 Adsorption Properties of HKUST-1", ACS Omega 4, 5275-5282 (2019).
· Dahae Song, Jinhee Bae, Hoon Ji, Min-Bum Kim, Youn-Sang Bae, Kyo Sung Park, Dohyun Moon, and Nak Cheon Jeong, "Coordinative Reduction of Metal Nodes Enhances the Hydrolytic Stability of a Paddlewheel Metal-Organic Framework", J. Am. Chem. Soc. 141, 7853-7864 (2019).
· Xiao-Lin Qi, Dong-Dong Zhou, Jing Zhang, Shuang Hu, Maciej Haranczyk, and De-Yi Wang, "Simultaneous Improvement of Mechanical and Fire-Safety Properties of Polymer Composites with Phosphonate-Loaded MOF Additives", ACS Appl. Mater. Interfaces 11, 20325-20332 (2019).
· Jose Maria Moreno, Alexandra Velty, and Urbano Diaz, "Expandable Layered Hybrid Materials Based on Individual 1D Metalorganic Nanoribbons", Materials 12, 1953 (2019).
· Lei Gan, Pol G. Fonquernie, Mark E. Light, Gantulga Norjmaa, Gregori Ujaque, Duane Choquesillo-Lazarte, Julio Fraile, Francesc Teixidor, Clara Viñas, and José G. Planas, "A Reversible Phase Transition of 2D Coordination Layers by B−H⋅⋅⋅Cu(II) Interactions in a Coordination Polymer", Molecules 24, 3204 (2019).
· Eun Ji Lee, Jinhee Bae, Kyung Min Choi, and Nak Cheon Jeong, "Exploiting Microwave Chemistry for Activation of Metal-Organic Frameworks", ACS Appl. Mater. Interfaces 11, 35155-35161 (2019).
· Jose A. Villajos, Noëmie Jagorel, Stefan Reinsch, and Franziska Emmerling, "Increasing Exposed Metal Site Accessibility in a Co-MOF-74 Material With Induced Structure-Defects", Front. Mater. 6, 230 (2019).
· Jing Tang, Shenhui Li, Yueying Chu, Yuqing Xiao, Jun Xu, and Feng Deng, "Host-Guest Interaction Between Methanol and Metal-Organic Framework Cu3-xZnx(btc)2 as Revealed by Solid-State NMR", J. Phys. Chem. C 123, 24062-24070 (2019).
2020 {5}
· Christian Schneider, Matthias Mendt, Andreas Pöppl , Valentina Crocellà, and Roland A. Fischer, "Scrutinizing the Pore Chemistry and the Importance of Cu(I) Defects in TCNQ-Loaded Cu3(BTC)2 by a Multitechnique Spectroscopic Approach", ACS Appl. Mater. Interfaces 12, 1024-1035 (2020).
· Sajid Bashir, Sai Raghuveer Chava, Daqiang Yuan, Srinath Palakurthi, and Jingbo Liu, "Metal-organic frameworks and exemplified cytotoxicity evaluation (Book Chapter)", Metal-Organic Frameworks for Biomedical Applications (Editors: Masoud Mozafari), Chapter 16, pp. 347-381 (2020) (Woodhead Publishing).
· Ülkü Kökçam-Demir, Anna Goldman, Leili Esrafili, Maniya Gharib, Ali Morsali, Oliver Weingart, and Christoph Janiak, "Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications", Chem. Soc. Rev. 49, 2751-2798 (2020).
· Hye in Song, Jinhee Bae, Eun Ji Lee, Kent Ozan Kirlikovali, Omar K. Farha, and Nak Cheon Jeong, "Vibrational Paddlewheel Cu-Cu Node in Metal-Organic Frameworks: Probe of Nonradiative Relaxation", J. Phys. Chem. C 124, 13187-13195 (2020).
· Tingting Zhou, Shiyu Chen, Xiaoxia Wang, Changsheng Xie, and Dawen Zeng, "Catalytic Activation of Cobalt Doping Site in ZIF-71 Coated ZnO Nanorod Arrays for Enhancing Gas-sensing Performance to Acetone", ACS Appl. Mater. Interfaces 12, 48948-48956 (2020).
2021 {8}
· John Luke Woodliffe, Rebecca S. Ferrari, Ifty Ahmed, and Andrea Laybourn, "Evaluating the purification and activation of metal-organic frameworks from a technical and circular economy perspective", Coord. Chem. Rev. 428, 213578 (2021).
· Ricardo Peralta, Michael Huxley, Rosemary Young, Oliver Michael Linder-Patton, Jack D. Evans, Christian J. Doonan, and Christopher J. Sumby, "MOF matrix isolation: Cooperative conformational mobility enables reliable single crystal transformations", Faraday Discuss. 225, 84-99 (2021).
· Alexandre M. Viana, Diana Julião, Fátima Mirante, Rui G. Faria, Baltazar de Castro, Salete S. Balula, and Luís Cunha-Silva, "Straightforward Activation of Metal-Organic Framework UiO-66 for Oxidative Desulfurization Processes", Catal. Today 362, 28-34 (2021).
· Meaghan M. Deegan, Alexandra M. Antonio, Garrett A. Taggart, Eric D. Bloch, "Manipulating solvent and solubility in the synthesis, activation, and modification of permanently porous coordination cages", Coord. Chem. Rev. 430, 213679 (2021).
· Xiaowu Liang, Pengfei Wang, Congli Li, Min Yuan, Qi Shi, and Jinxiang Dong, "The activation of Co-MOF-74 with open metal sites and their corresponding CO/N2 adsorptive separation performance", Microporous and Mesoporous Mater. 320, 111109 (2021).
· Jinhee Bae, Chang Yeon Lee, and Nak Cheon Jeong, "Weak Coordination Bond of Chloromethane: A Unique Way to Activate Metal Node Within an Unstable Metal-Organic Framework DUT-34", Bull. Korean Chem. Soc. 42, 658-666 (2021).
· Vahid Ashouri, Kourosh Adib, Mehdi Rahimi Nasrabadi, and Masoumeh Ghalkhani, "Preparation of the extruded UiO-66-based Metal-Organic Framework for the diazinon removal from the real samples", J. Mol. Struct. 1240, 130607 (2021).
· Yunseung Kuk and Kang Min Ok, "Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties", CrystEngComm 23, 3701-3709 (2021).
2022 {8}
· Jose A. Villajos, "Experimental Volumetric Hydrogen Uptake Determination at 77 K of Commercially Available Metal-Organic Framework Materials", J. Carbon Res. 8, 5 (2022).
· Jinhee Bae, Sun Ho Park, Dohyun Moon, and Nak Cheon Jeong, "Crystalline hydrogen bond of water molecules confined in a metal-organic framework", Commun. Chem. 5, 51 (2022). See also: Research Square, DOI:10.21203/rs.3.rs-1039370/v1.
· Jiachun Zhao, Yixin Wang, Jia Zhang, Yang Yue, Qiang Liu, and Guangren Qian, "Accessibility control of Cu sites to enhance adsorption capacity of ultra-low-concentration methyl mercaptan", Chemosphere 305, 135511 (2022).
· Zahra Afravi, Valiollah Nobakht, Nahid Pourreza, Matineh Ghomi, Damian Trzybiński, and Krzysztof Woźniak, "Design of a Sensitive Fluorescent Zn-Based Metal–Organic Framework Sensor for Cimetidine Monitoring in Biological and Pharmaceutical Samples", ACS Omega 7, 22221-22231 (2022).
· Okpara Sergeant Bull, Ibiso Bull, Gloria Kelechi Amadi, Chikwem Obaalologhi Odu, and Eyu Okpa, "A Review on Metal- Organic Frameworks (MOFS), Synthesis, Activation, Characterisation, and Application", Orient. J. Chem. 38, 490-516 (2022).
· Byeongchan Lee, In-Hyeok Park, and Jinhee Park, "Bridging and Fixing Metal–Organic Cages", ACS Mater. Lett. 4, 2388-2393 (2022).
· Sun Ho Park, Ricardo A. Peralta, Dohyun Moon, and Nak Cheon Jeong, "Dynamic weak coordination bonding of chlorocarbons enhances the catalytic performance of a metal–organic framework material", J. Mater. Chem. A 10, 23499-23508 (2022).
· Ricardo A. Peralta, Pengbo Lyu, Alfredo López-Olvera, Juan L. Obeso, Carolina Leyva, Nak Cheon Jeong, Ilich A. Ibarra, and Guillaume Maurin, "Switchable Metal Sites in Metal–Organic Framework MFM-300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics", Angew. Chem. Int. Ed. 61, e202210857 (2022).
2023 {10}
· Pham Thi Phan, Jeongsoo Hong, Ngo Tran, and Thi Hoa Le, "The Properties of Microwave-Assisted Synthesis of Metal–Organic Frameworks and Their Applications", Nanomaterials 13, 352 (2023).
· Byeongchan Lee, Dohyun Moon, and Jinhee Park, "Solvent-mediated single-crystal-to-single-crystal transformation of metal–organic cage self-assembly", Bull. Korean Chem. Soc. 44, 55-59 (2023).
· Andrew Nosakhare Amenaghawon, Chinedu Lewis Anyalewechi, Osarieme Uyi Osazuwa, Ehiaghe Agbovhimen Elimian, Steve Oshiokhai Eshiemogie, Peter Kayode Oyefolu, and Heri Septya Kusuma, "A comprehensive review of recent advances in the synthesis and application of metal-organic frameworks (MOFs) for the adsorptive sequestration of pollutants from wastewater", Sep. Purif. Technol. 311, 123246 (2023).
· Olaniran K. Akeremale, Odunayo T. Ore, Ajibola A. Bayode, Hamza Badamasi, Johnson Adedeji Olusola, and Solomon S. Durodola, "Synthesis, characterization, and activation of metal organic frameworks (MOFs) for the removal of emerging organic contaminants through the adsorption-oriented process: A review", Results Chem. 5, 100866 (2023).
· Alexander J. R. Thom, Gemma F. Turner, Zachary H. Davis, Martin R. Ward, Ignas Pakamorė, Claire L. Hobday, David R. Allan, Mark R. Warren, Iain D. H. Oswald, Russell E. Morris, Stephen A. Moggach, Sharon E. Ashbrook, and Ross S. Forgan, "Pressure-induced postsynthetic cluster anion substitution in a MIL-53 topology scandium metal-organic framework", Chem. Sci. 14, 7716-7724 (2023). See also: ChemRxiv-2022-wmrjp.
· Maria-Anna Gatou, Ioanna-Aglaia Vagena, Nefeli Lagopati, Natassa Pippa, Maria Gazouli, and Evangelia A. Pavlatou, "Functional MOF-Based Materials for Environmental and Biomedical Applications: A Critical Review", Nanomaterials 13, 2224 (2023).
· Sheng Qiang Zheng, Siew Shee Lim, Chuan Yi Foo, Choon Yian Haw, Wee Siong Chiu, Chin Hua Chia, and Poi Sim Khiew, "Solvothermal synthesis of nanostructured nickel-based metal–organic frameworks (Ni-MOFs) with enhanced electrochemical performance for symmetric supercapacitors", J. Mater. Sci. 58, 11894-11913 (2023).
· Jose Antonio Villajos, Martin Bienert, Nikita Gugin, Franziska Emmerling, and Michael Maiwald, "A database to select affordable MOFs for volumetric hydrogen cryoadsorption considering the cost of their linkers", Mater. Adv. 4, 4226-4237 (2023).
· Pablo S. Gauna, Andrés A. García Blanco, Deicy Barrera, Jhonny Villarroel-Rocha, Juan P. Hinestroza, Mutsumi Kimura, Manuela L. Kim, Eugenio H. Otal, and Karim Sapag, "Influence of defect engineering on the hydrogen and methane adsorption capacity in HKUST-1 – like structure MOF", Adsorption 29, 351-361 (2023).
· Asong Byun, Dohyun Moon, Byeongchan Lee, and Jinhee Park, "Amorphous porous Fe-BTC prepared via the post-synthetic metal-ion metathesis of HKUST-1", J. Mater. Chem. A 11, 24591-24597 (2023).
2024 {8}
· Meghan G. Sullivan, Heshali K. Welgama, Matthew R. Crawley, Alan E. Friedman, and Timothy R. Cook, "Phase-Pure Zirconium Metal–Organic Polyhedra Enabled by a Ligand Substitution Strategy", Chem. Mater. 36, 567-574 (2024).
· Liuxuan Yang, Ke Wang, Ling Guo, Xiao Hu, and Meiling Zhou, "Unveiling the potential of HKUST-1: synthesis, activation, advantages and biomedical applications", J. Mater. Chem. B 12, 2670-2690 (2024).
· Zeqing Liu, Lingmei Dai, Dehua Liu, and Wei Du, "Enhanced Stability and Performance of Immobilized Lipase Using Hydrophobically Modified Single-Crystalline Ordered Macro–Microporous CuBTC as a Carrier Material", ACS Sustainable Chem. Eng. 12, 3909-3920 (2024).
· Byeongchan Lee, Bogyeong Go, Byunghyuck Jung, Jinhee Park, "Unlocking High Porosity: Post-Synthetic Solvothermal Treatment of Cu-Paddlewheel Based Metal–Organic Cages", Small 20, 2308393 (2024).
· Wanting Hui, Zixin Li, Shouchun Ma, HongYan Liu, Yanqiu Zhang, Wenqi Ding, Yaodan Cao, Tongjie Yao, and Jie Wu, "Maximize coordinately unsaturated metal sites via removal of compact MOF external surface: Enhanced Fenton-like performance inside yolk@shell nanoreactor", Chem. Eng. J. 497, 154667 (2024).
· Hamed Shooshtari Gugtapeh, Mona Abbasi, Mahdi Hasanzadeh Moghadam, and Milad Rezaei, "Solvent-Exchange-Assisted Activation of Cu-1,4-Benzene Dicarboxylate Metal-Organic Framework for Use as a Bifunctional Water Splitting Electrocatalyst", Electrochimica Acta 508, 145224 (2024).
· Manoj Kumar Sarangi, Goutam Rath, and Dong Kee Yi, "Metal organic framework based nanozymes explored with their environmental pollution control strategies", Inorg. Chem. Commun. 170, 113334 (2024).
· Samar S. Mohammed, "Synthesis and Characterization of Advanced Metal-Organic Frameworks (MOFs)", J. Med. Genet. Clin. Biol. 1, 18-34 (2024).
2025 {4}
· Hochul Woo and Adam J. Matzger, "Competitive Guest Binding in a Metal–Organic Framework with Coordinatively Unsaturated Metals", ACS Mater. Lett. 7, 450-456 (2025).
· Mariana L. Díaz Ramírez, Sun Ho Park, Marcos Rivera-Almazo, Erika Medel, Ricardo A. Peralta, Ilich A. Ibarra, Rubicelia Vargas, Jorge Garza, and Nak Cheon Jeong, "Gas-flow activation of MOFs: unlocking efficient catalysis through dynamic bonding", Chem. Sci. 16, 2581-2588 (2025).
· Kayhaneh Berijani and G. Reza Vakili-Nezhaad, "The performance of MOFs and rich structure types of stable Zr-MOFs in storing clean energy: Hydrogen", J. Energy Storage 30, 115928 (2025).
· Aparna Kushwaha and Abhinav Kumar, "MOFs and MOF derivatives for electrocatalytic hydrogen evolution reaction: Designing strategies, syntheses and future prospects", Int. J. Hydrogen Energy 150, 150148 (2025).
2026 {4}
· Soon Hyeong So, Seung Yong Lee, Hohyung Kang, Hyegi Min, Hee‐Tae Jung, Kyu Hyoung Lee, and Dae Woo Kim, "Metal-organic frameworks for gas sensors: comprehensive review from principal, fabrication to application", Int. J. Extrem. Manuf. 8, 012001 (2026).
· Rui Jie, Yang Gao, Haiyan Qi, Jinzhi Yu, Chenyu Qi, and Wanting Hui, "Electromagnetic-wave assisted rapid synthesis of MOF with coordination unsaturated metal sites for enhanced activity in Fenton-like reaction", Appl. Catal. A: Gen. 710, 120696 (2026).
· Bettina Baumgartner, Anna Wach, Xinwei Ye, Evelyn Ploetz, and Bert M. Weckhuysen, "Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective", Adv. Mater., accepted (2025).
· Neekita Thakur and Archana Thakur, "Magnesium Metal‒Organic Framework as a Dual, Turn-Off Fluorescent Sensor for Organic Solvents and Heavy Metal Ions", J. Inorg. Organomet. Polym. Mater., accepted (2025).