Kang Laboratory

Publications

15. Kang, T.†; Apolinar, O.†; Engle, K. M.; “Ni- and Pd-Catalyzed Enantioselective 1,2-Dicarbofunctionalization of Alkenes.” Synthesis 2024, 1, 1–15. (†Authors contributed equally)

14. Tran, V. T.†; Kim, N.†; Rubel, C. Z.; Wu, X.; Kang, T.; Jankins, T. C.; Li, Z.-Q.; Joannou, M. V.; Ayers, S.; Gembicky, M.; Bailey, J.; Sturgell, E. J.; Sanchez, B. B.; Chen, J. S.; Lin, S.; Eastgate, M. D.; Wisniewski, S. R.; Engle, K. M. “Structurally Diverse Bench-Stable Nickel(0) Pre-Catalysts: A Practical Toolkit for In Situ Ligation Protocols." Angew. Chem. Int. Ed. 2023, 62, e202211794. (†Authors contributed equally)

13. Kang, T.; Fu, Y.; Matsuura, R.; Liu, A. L.; Jankins, T. C.; Rheingold, A. L.; Bailey, J. B.; Gembicky, M.; Liu, P.; Engle, K. M. “Synthesis and Characterization of Post-β-Carbon-Elimination Organopalladium Complexes.” Organometallics 2023, 42, 11–15.

12. Apolinar, O.†; Kang, T.†; Alturaifi, T. M.; Bedekar, P. G.; Rubel, C. Z.; Derosa, J.; Sanchez, B. B.; Wong, Q. N.; Sturgell, E. J.; Chen, J. S.; Wisniewski, S. R.; Liu, P.; Engle, K. M. “Three-Component Asymmetric Ni-Catalyzed 1,2-Dicarbofunctionalization of Unactivated Alkenes via Stereoselective Migratory Insertion." J. Am. Chem. Soc. 2022, 144, 19337–19343. (†Authors contributed equally)

11. Li, Z.-Q.; Cao, Y.; Kang, T.; Engle, K. M. “Electrophilic Sulfur Reagent Design Enables Directed syn-Carbosulfenylation of Unactivated Alkenes.” J. Am. Chem. Soc. 2022, 144, 7189–7197.

10. Kang, T.; González, J. M.; Li, Z.-Q.; Foo, K.; Cheng, P. T. W.; Engle, K. M. “Alkene Difunctionalization Directed by Free Amines: Diamine Synthesis via Nickel-Catalyzed 1,2-Carboamination.” ACS Catal. 2022, 12, 3890–3896.

9. Kang, T.; Kim, N.; Cheng, P. T.; Zhang, H.; Foo, K.; Engle, K. M. “Nickel-Catalyzed 1,2-Carboamination of Alkenyl Alcohols." J. Am. Chem. Soc. 2021, 143, 13962–13970.

8. Gao, Y.; Yazdani, S.; Kendrick, A., IV; Junor, G. P.; Kang, T.; Grotjahn, D. B.; Bertrand, G.; Jazzar, R.; Engle, K. M. “Cyclic(Alkyl)(Amino)Carbene Ligands Enable Cu-Catalyzed Markovnikov Protoborylation and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes.” Angew. Chem. Int. Ed. 2021, 60, 19871–19878.

7. Wethman, R.; Derosa, J. Tran, V. T.; Kang, T.; Apolinar, O.; Abraham, A.; Kleinmans, R.; Wisniewski, S. R.; Coombs, J . R.; Engle, K. M. “An Under-Appreciated Source of Reproducibility Issues in Cross-Coupling: Solid-State Decomposition of Primary Sodium Alkoxides in Air.” ACS Catal. 2021, 11, 502–508.

6. Kang, T.; Erbay, T. G.; Xu, K. L.; Gallego, G. M.; Burtea, A.; Nair, S. K.; Patman, R. L.; Zhou R.; Sutton, S. C.; McAlpine, I. J.; Liu, P.; Engle, K. M. “Multifaceted Substrate–Ligand Interactions Promote the Copper-Catalyzed Hydroboration of Benzylidenecyclobutanes and Related Compounds.” ACS Catal. 2020, 10, 13075–13083.

5. Derosa, J.; Apolinar, O.; Kang, T.; Tran, V. T.; Engle, K. M. “Recent Developments in Nickel-Catalyzed Intermolecular Dicarbofunctionalization of Alkenes.” Chem. Sci. 2020, 11, 4287–4296.

4. Derosa, J.†; Kang, T.†; Tran, V. T.; Wisniewski, S. R.; Karunananda, M. K.; Jankins, T. C.; Xu, K. L; Engle, K. M. “Nickel-Catalyzed 1,2-Diarylation of Alkenyl Carboxylates A Gateway to 1,2,3-Trifunctionalized Building Blocks." Angew. Chem. Int. Ed. 2020, 59, 1201–1205. (†Authors contributed equally)

3. Medina, J. M.†; Kang, T.†; Erbay, T. G.; Shao, H.; Gallego, G. M.; Yang, S.; Tran-Dubé, M.; Richardson, P. F.; Derosa, J.; Helsel, R.; Patman, R. L.; Wang, F.; Ashcroft, C. P.; Braganza, J. F.; McAlpine, I.; Liu, P.; Engle, K. M. "Cu-Catalyzed Hydroboration of Benzylidenecyclopropanes: Reaction Optimization, (Hetero)Aryl Scope, and Origins of Pathway Selectivity." ACS Catal. 2019, 9, 11130–11136. (†Authors contributed equally)

2. Hwang, J.†; Kang, T.†; Lee, J.; Choi, B.-S.; Han, S. "Design, Synthesis, and Biological Evaluation of C7-Functionalized DMXAA Derivatives as Potential Human-STING Agonists." Org. Biomol. Chem. 2019, 17, 1869. (†Authors contributed equally)

1. Kang, T.; Jo, D.; Han, S. "Six-Step Total Synthesis of Azaspirene." J. Org. Chem. 2017, 82, 9335.

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