Colloidal gels and thixotropy
Food and health | Energy and electronics | Manufacturing
Monash Impact 2030 | Thriving communities
Yogurt, paint, toothpaste and many battery slurries are colloidal gels, i.e., networks of sticky microscopic particles that hold their shape at rest and flow when stirred. We use coarse-grained simulations to connect what happens at each bond, whether two particles can slide, roll or twist against each other, to the yield stress, ageing and thixotropy of the whole gel. Our simulations of depletion gels show that attraction and cluster formation alone do not explain the yield stress, and that constraints on the relative rotation of bonded particles are needed as well. We have since built a contact model for rough colloids in which bumpy surfaces lock together even when they are only lightly pressed, and we are using it to study how gels age, recover after shearing and remember their shear history. In addition, with colleagues at Edinburgh and MIT, we study how these rolling constraints change the structure of depletion gels.
Applications. Paints, foods, cosmetics, pharmaceuticals, battery slurries.
Partners. MIT, University of Edinburgh, Australian Synchrotron.