Mauban is politically subdivided into 40 barangays. Each barangay consists of puroks and some have sitios. 

• Bagong Bayan 

• Daungan

• Lual Poblacion

• Mabato 

• Rizaliana 

• Sadsaran 

• Abo-abo

• Alitap

• Baao

• Balaybalay

• Bató

• Cagbalete I

• Cagbalete II

• Cagsiay I

• Cagsiay II

• Cagsiay III

• Concepción

• Liwayway

• Lucutan

• Lual Rural

• Luya-luya

• Macasin

• Polo

• Remedios I

• Remedios II

• Rosario

• San Gabriel (formerly Tubog[6])

• San Isidro

• San José

• San Lorenzo

• San Miguel

• San Rafael

• San Roque

• San Vicente

• Santa Lucía

• Santo Ángel

• Santo Niño

• Santol

• Soledad

• Tapucan