TLDR;
What's the problem?
There is not time-scales associated to the Paleoproterozoic oxygen oases, at least until now.
Why is this important?
This is important, because it is believed that oxygen oases ultimately lead the Great Oxidation Episode.
How do we address this problem?
We measured sulfur and molybdenum isotopes in black shales from the in the Kuruman Formation.
What's the outcome?
We conclude that the oxygen oases were indeed stable in time (>20 Myr). Also, it was possible that oxygen rich waters could contract and expand at much faster paces (<2 Myr).
Summary
The Great Oxidation Episode (GOE) is a major reorganization process that took place during the Neoarchean and Paleoproterozoic periods, and unfortunately, its exact temporal evolution is entirely clear yet. To that end, we analyze Δ33S and δ98Mo data from the Kuruman Formation to gain insights into its timing and nature. Our results show that atmospheric oxygen fluctuations exceeding the 10-7 present atmospheric levels threshold occurred within approximately ~2 Myr. Conversely, shallow oxygen-rich waters persisted for at least ~15 Myr, while deeper waters remained ferruginous and/or euxinic. These findings highlight the GOE's extensive duration and localized nature, comprising multiple events within specific time frames and geographical boundaries. Our study advances understanding of the GOE's temporal dynamics, contributing to comprehension of Earth's atmospheric and marine evolution. Finally, the relationship between the GOE and Paleoproterozoic glaciations requires further exploration, but it is clear that the final stage of the GOE closely followed these glaciations.
This project was presented in:
Senger, M.H. and Bindeman, I. 2024. Surface conditions at 2.47 Ga as constrained by triple oxygen isotope system. Goldschmidt Conference 2024, Chicago, USA, 18-23 August.
Senger, M.H.; Davies, J.F.H.L.; Marin-Carbonne, J.; Greber, N.D.; Schaltegger, U. 2023. Multi-step increase of atmospheric oxygen between ~2.5-2.4 Ga. Goldschmidt Conference 2023, Lyon, France, 10-14 July.
Senger, M.H.; Greber, N.D.; Davies, J.F.H.L.; Schaltegger, U. 2022. Molybdenum isotopes in the ~2.48 Ga-old Kuruman Formation, South Africa. Swiss Geoscience Meetings 2022, Lausanne, Switzerland, 21-22 November.
Senger, M.H.; Greber, N.D.; Davies, J.F.H.L.; Ulyanov, A.; Schaltegger, U. 2022. Elemental survey of a drillcore piercing the Kuruman iron formation, South Africa. 12th South American Symposium on Isotope Geology, Santiago, Chile, 3-6 July.
Senger, M.H.; Marin-Carbonne, J.; Davies, J.F.H.L.; Mason, P.R.D.; Bouvier, A.S.; Schaltegger, U. 2022. S-cycle characterization in the Paleoproterozoic Kuruman iron formation, Transvaal Supergroup, South Africa. Goldschmidt Conference 2022, Honolulu, USA, 10-15 July. https://doi.org/10.46427/gold2022.12829
University of Arizona
Department of Earth Sciences
1040 E. 4th Street
Tucson, AZ 85721, USA