By N.R. Kavin Kumar, BS-MS 2018
Mars today is a cold, desert planet with red sands of Iron oxide and planet-wide dust storms along with ice caps on the poles. But geological and geochemical evidences from the planet suggest a totally difference past – a surface which had flowing liquid water, maybe with a huge ocean covering the northern hemisphere, precipitation, active volcanos and much more – feels very much like Earth. So what lead to this dramatic change from a paradise to the current dystopian look?
Mars currently has a very thin atmosphere – about 1% as dense as Earth’s atmosphere. No large standing body of liquid water exists now because the atmospheric pressure on the Red planet averages just 600 pascals, a figure slightly below the vapour pressure of water at its melting point. Under average Martian conditions, pure water on the Martian surface would freeze or, if heated to above the melting point, would sublime to vapor.
Mars today is a cold, desert planet with red sands of Iron oxide and planet-wide dust storms along with ice caps on the poles. But geological and geochemical evidences from the planet suggest a totally difference past – a surface which had flowing liquid water, maybe with a huge ocean covering the northern hemisphere, precipitation, active volcanos and much more – feels very much like Earth. So what lead to this dramatic change from a paradise to the current dystopian look?
Mars currently has a very thin atmosphere – about 1% as dense as Earth’s atmosphere. No large standing body of liquid water exists now because the atmospheric pressure on the Red planet averages just 600 pascals, a figure slightly below the vapour pressure of water at its melting point. Under average Martian conditions, pure water on the Martian surface would freeze or, if heated to above the melting point, would sublime to vapor.
Temperature range of Earth (yellow) and Mars (red) on the phase diagram of water. Increasing temperature makes phase of water change along the red line from solid (green) to vapour (purple). Along the yellow line of Earth, water can be seen in all three phases. Source: Centre for Ice and Climate, University of Copenhagen
The presence of liquid water on the surface in the past suggests that Mars had a thicker atmosphere in the past. This indicates that it has lost its atmosphere. This idea was supported by studying Argon isotopes in the Martian atmosphere.
Every planet’s atmosphere loses a small amount of gas continuously. This happens when a gas particle attains a Kinetic energy higher than the gravitational potential and is not obstructed by any other particles on its way out into space. There are many factors that lead to this condition of atmospheric loss. From Graham’s Law of effusion, we know that rate of effusion of a gas is inversely proportional to its molar mass. When concentration of two isotopes of Argon are compared, the heavier isotope concentration will be higher as the lighter one effuses out of the atmosphere at a faster rate. By measuring the ratio of Argon-36 (lighter isotope) to Argon-38 (heavier isotope), we can find if there has been loss of atmosphere. Lower the ratio, more of the lighter isotope has been lost, which implies more of the atmosphere has been lost.
The right image clearly shows that the Argon isotope ratio in Mars is lower than Sun, Jupiter and Earth, which implies that Mars has lost most of its atmosphere over time compared to Earth.
So what lead to Mars loose its atmosphere while Earth to retain its own? The difference is the lack of a Magnetic field. A planet’s magnetic field protects the atmosphere of the planet from solar storms. Without this shield of protection, solar storms can strip off the atmosphere of a planet over the years, which is what is currently happening to the Red planet. The magnetic field of Earth is generated by its rotating solid iron core. Mars would have had a similar magnetic field long back in its history, but being a smaller planet, it lost its internal heat quicker than Earth. This lead to the shut down of its internal dynamo that was generating the magnetic field. With the magnetic field gone, the Martian atmosphere is at the mercy of the Sun’s tantrums, which is slowly taking it away as solar storms blow past the Red planet.
This image shows the ratio of the argon isotope argon-36 to the heavier argon isotope argon-38, in various measurements. The point farthest to the right designates a new (2013) measurement of the ratio in the atmosphere of Mars, made by the quadrupole mass spectrometer in the Sample Analysis at Mars (SAM) suite of instruments in NASA’s Curiosity Mars rover. For comparison, the previous measurement at Mars by the Mars Viking project in 1976 is also shown. The SAM result is at the lower end of the range of uncertainty of the Viking data, but compares well with ratios of argon isotopes from some Mars meteorites. The value determined by SAM is significantly lower than the value in the sun, Jupiter and Earth, which implies loss of the lighter isotope compared to the heavier isotope over geologic time. The argon isotope fractionation provides clear evidence of the loss of atmosphere from Mars. Source: NASA/JPL-Caltech
Sputtering in the Martian atmosphere. Source: Casey Reed / Sky & Telescope.
In the final section of this article, I would like to mention briefly about the four major methods by which gas is lost from an atmosphere –
Jeans escape – Individual particles of a gas collide with each other. Some of them attain speeds higher than the escape velocity of the planet, leading to loss of gas. This is the slowest mode of loss of gas.
Hydrodynamic escape – In this case, a large amount of thermal energy, usually through extreme ultraviolet radiation, is absorbed by the atmosphere. As molecules are heated, they expand upwards and are further accelerated until they reach escape velocity.
Photochemical escape – In the upper atmosphere, high energy UV Photons can react more readily with molecules. Photodissociation can break a molecule into smaller components and provide enough energy for those components to escape.
Sputtering – First, ultraviolet photons knock electrons out of atmospheric atoms and molecules in the upper Martian atmosphere, forming electrically charged ions. These ions are picked up by the solar wind, which is infused with the Sun’s magnetic field. As the field-carrying solar wind moves by, it drags these ions with it. Some of these ions are flung back into the upper atmosphere at high velocity. There, they collide with neutral atoms and molecules and knock them every which way, like the cue ball scatters balls in a break shot in pool. Some of the atoms are knocked upward with enough velocity to escape Mars — in other words, they’re “sputtered.” This process leads to very high rates of atmospheric loss and is the reason behind the huge loss of the Martian atmosphere.