Publications

 

The (o-p-o)-Terphenyl Embedded Calix[2]phyrin(2.2. 1 .1. 1 ) and Its Cu(II) Complex

Pradhan S.; Prasad C.; Das M.; Srinivasan A.

Chem. Asian J..2024, DOI:10.1002/asia.202400135.

Unveiling protonated form of 2,6-di-m-phenylpyridine embedded isosmaragdyrin analogue and its organo-Pd(ii) complex

Pradhan S.; Murugavel M.; Chitranshi S.; Kim G.; Kim D.; Das M.; Srinivasan A.

New J. Chem.2023, DOI: 10.1039/D3NJ03432A.

Advent and Features of Pyriporphyrinoids: An Overview of a

Pyridine Based Porphyrin Analogue

Das M.; Srinivasan A.

Chem. Commun.2023, DOI: 10.1039/D3CC03139J.

    Rh(I) and Organo-Rh(III) Complexes of meso-Triarylbiphenylcorrole 

Chitranshi S.;Adinarayana B.;Das M.;Anila S.;Suresh C.H.;Srinivasan A. 

Inorg.Chem.2023,62, 336−341

3-D Cryptand like Normal and Doubly N-Confused Calixbenzophyrins: Synthesis and Structural Studies

Palepu N.R.;Adinarayana B.;Murugavel M.;Garima K.;Chitranshi S.;Srinivasan A.

Org. Lett. 2021, 23, 7, 2600–2603


Tetrakis-(N-methyl-4-pyridinium)-porphyrin as a diamagnetic chemical exchange saturation transfer (diaCEST) MRI contrast agent

Chakraborty S.;Das M.;Srinivasan A.;Ghosh A.

New J. Chem., 2021,45, 1262


N-Confused Pyritriphyrin: A New Class of Triphyrin and Its Calixphyrin Analogue

Das M.;Singh D.;Chitranshi S.;Murugavel M.;Srinivasan A.

Eur.J. Org.Chem.2021,5222– 5226


Recent Advances in the Design and Syntheses of Porphyrinoids by Embedding Higher Analogues of Arene and Pyridine Units

Das M.;Adinarayana B.;Srinivasan A.

ACS Omega 2021, 6, 51, 35204–35212



PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a: Meso -fused β-β′ Dimer and its monomer analogue

Murugavel M.;Adinarayana B.;Das M.;Peruncheralathan S.;Palepu N.R.;Srinivasan A.

Chem. Commun., 2020, 56, 12809--12812


Engineering diformyl diaryldipyrromethane into a molecular keypad lock

Gowri Sreedevi K.C.;Thomas A.P.;Adinarayana B.;Srinivasan A.

New J. Chem., 2020,44, 11768



Structurally Isomerized Bis-Biphenyl Moieties Embedded in Hexaphyrin(3.1.1.3.1.1) and Octaphyrin(1.1.1.0.1.1.1.0)

Chitranshi S.;Das M.;Adinarayana B.;Cha W.Y.;Kim D.;Srinivasan A.

Org. Lett. 2020, 22, 3, 1081–1085



Isosmaragdyrin with an N3C2 core: Stabilization of Rh(I) and organo-Pt(II) complexes

Das M.;Chitranshi S.;Murugavel M.;Adinarayana B.;Suresh C.H.;Srinivasan A.

Chem. Commun., 2020,56, 3551



Bis-4,4′-biphenyl Ring Embedded Octaphyrin with Three Distinct Conformational Structures

Chitranshi S.;Adinarayana B.;Das M.;Cha W.Y.;Kim D.;Srinivasan A.

Chem.Eur.J,2019,25,12911–12915



  Di-(m- m- m)terphenyl-Embedded Decaphyrin and Its Bis-Rh(I) Complex

Das M.;Adinarayana B.;Murugavel M.;Nayak S.;Srinivasan A.

Org. Lett. 2019, 21, 8, 2867–2871


Homocarbaporphyrinoids: The m-o-m and p-o-p Terphenyl Embedded Expanded Porphyrin Analogues and Their Rh I Complexes

Adinarayana B.;Das M.;Suresh C.H.;Srinivasan A.

Chem.Eur.J.2019,25,4683 –4687



Protonation-Triggered Hückel and Möbius Aromatic Transformations in Nonaromatic Core-Modified [30]Hexaphyrin(2.1.1.2.1.1) and Annulated [28]Hexaphyrin(2.1.1.0.1.1)

Dash S.;Ghosh A.;Srinivasan A.;Suresh C.H.;Chandrashekar T.K.

Org. Lett. 2019, 21, 23, 9637–9641




Core-modified 48π and 42π decaphyrins: Syntheses, properties and structures

Ghosh A.;Dash S.;Srinivasan A.;Suresh C.H.;Peruncheralathan S.;Chandrashekar T.K.

Org. Chem. Front., 2019, 6,3746



Two non-identical twins in one unit cell: Characterization of 34π aromatic core-modified octaphyrins, their structural isomers and anion bound complexes

Ghosh A.;Dash S.;Srinivasan A.;Suresh C.H.;Chandrashekar T.K.

Chem. Sci., 2019, 10, 5911



  Rhodium(III) and Iridium(III) Bipyricorrole Complexes: Syntheses, Structures, and Properties

Adinarayana B.;Murugavel M.;Das M.;Palepu N.R.;Srinivasan A.

Inorg. Chem. 2018, 57, 4, 1840–1845



24π Core-Modified Nonfused Pentaphyrin with Möbius Aromaticity

Ghosh A.;Dash S.;Srinivasan A.;Sahu M.S.R.;Suresh C.H.;Chandrashekar T.K.

Chem.Eur.J.2018,24,17997–18002



Smaragdyrins and Sapphyrins Analogues

Chatterjee T.;Srinivasan A.;Ravikanth M.;Chandrashekar T.K.

                                           Chem. Rev. 2017, 117, 4, 3329–3376


Syntheses of Bipyricorroles and Their Meso-Meso Coupled Dimers

Adinarayana B.;Thomas A.P.;Satha P.;Srinivasan A.

Org. Lett. 2017, 19, 8, 1986–1989



Carbatriphyrin(3.1.1)–A Distinct Coordination Approach of BIII to Generate Organoborane and Weak C−H⋅⋅⋅B Interactions

Adinarayana B.;Thomas A.P.;Yadav P.;Mukundam V.;Srinivasan A.

Chem.Eur.J.2017,23,2993 –2997



meso-Aryl [20]π Homoporphyrin: The Simplest Expanded Porphyrin with the Smallest Möbius Topology

Anju K.S.;Das M.;Adinarayana B.;Suresh C.H.;Srinivasan A.

Angew.Chem.Int.Ed.2017,56,15667–15671



Bipyricorrole: A corrole homologue with a monoanionic core as a fluorescence ZnII sensor

Adinarayana B.;Thomas A.P.;Yadav P.;Kumar A.;Srinivasan A.

Angew.Chem.Int.Ed.2016,55,969–973




  Time-Dependent density functional theoretical investigation of photoinduced excited-State intramolecular dual proton transfer in diformyl dipyrromethanes

Pradhan R.;Harshan A.K.;Krishnavilasam Chandrika G.S.;Srinivasan A.;Lourderaj U.

J. Phys. Chem. A 2016, 120, 50, 9894–9906



π Fused Core-Modified Heptaphyrin with Möbius Aromaticity

Ghosh A.;Chaudhary A.;Srinivasan A.;Suresh C.H.;Chandrashekar T.K.

Chem.Eur.J.2016,22,3942–3946



Phenylene-bridged core-modified planar aromatic octaphyrin: Aromaticity, photophysical and anion receptor properties

Karthik G.;Cha W.Y.;Ghosh A.;Kim T.;Srinivasan A.;Kim D.;Chandrashekar T.K.

Chem.AsianJ.2016,11,1447–1453



[40]π Fused and Nonfused Core-Modified Nonaphyrins: Syntheses and Structural Diversity

Ghosh A.;Srinivasan A.;Suresh C.H.;Chandrashekar T.K.

Chem.Eur.J.2016,22,11152–11155


  AIEE phenomenon: Tetraaryl vs. triaryl pyrazoles

Mukherjee S.;Salini P.S.;Srinivasan A.;Peruncheralathan S.

Chem. Commun., 2015,51, 17148




  A 6,11,16-Triarylbiphenylcorrole with an adj-CCNN Core: Stabilization of an Organocopper(III) Complex

Adinarayana B.;Thomas A.P.;Suresh C.H.;Srinivasan A.

Angew.Chem.Int.Ed.2015,54,10478–10482


Exploring anagostic interactions in 5,15-porphodimethene metal complexes

Derry Holaday M.G.;Tarafdar G.;Kumar A.;Reddy M.L.P.;Srinivasan A.

Dalton Trans., 2014, 43,7699




Chemodosimetric cyanide sensing in a 5,15-porphodimethene Pd(ii) complex

Holaday M.G.D.;Tarafdar G.;Adinarayana B.;Reddy M.L.P.;Srinivasan A.

Chem. Commun., 2014,50, 10834



  Photoenolization via excited state double proton transfer induces “turn on” fluorescence in diformyl diaryl dipyrromethane

Gowri Sreedevi K.C.;Thomas A.P.;Aparna K.H.;Pradhan R.;Reddy M.L.P.;Lourderaj U.;Srinivasan A.

Chem. Commun., 2014,50, 8667


  Fused core-modified planar antiaromatic 32π heptaphyrins: unusual synthesis and structural diversity

Karthik G.;Srinivasan A.;Suresh C.H.;Chandrashekar T.K.

Chem. Commun., 2014,50, 12127




  Meso -aryl core-modified fused sapphyrins: Syntheses and structural diversity

Karthik G.;Srinivasan A.;Chandrashekar T.K.

Org. Lett. 2014, 16, 13, 3472–3475



Photophysical properties of bridged core-modified hexaphyrins: Conjugational perturbation of thiophene bridges

Lim J.M.;Ganesan K.;Sung Y.M.;Srinivasan A.;Chandrashekar T.K.;Kim D.

Chem. Commun., 2014, 50, 4358-4360



Meso-Tetrakis(3,5-dihydroxyphenyl)N-confused porphyrin: Influence of polar protic and aprotic solvents in tautomeric existence, exchange and morphology

Thomas A.P.;Sreedevi K.C.G.;Adinarayana B.;Ramakrishnan S.;Srinivasan A.

RSC Advances, 2013, 3, 16967



Syntheses of normal, expanded, strapped and N-confused calixbenzophyrins from a single starting material

Salini P.S.;Anju K.S.;Reddy M.L.P.;Srinivasan A.

Chem. Commun., 2013,49, 5769


Conformational change from a twisted figure-eight to an open-extended structure in doubly fused 36π core-modified octaphyrins triggered by protonation: Implication on photodynamics and aromaticity

Karthik G.;Lim J.M.;Srinivasan A.;Suresh C.H.;Kim D.;Chandrashekar T.K.

Chem. Eur. J.2013,19, 17011 – 17020




Calix[2]thia[4]phyrin: An expanded calixphyrin with aggregation-induced enhanced emission and anion receptor properties

Karthik G.;Krushna P.V.;Srinivasan A.;Chandrashekar T.K.

J. Org. Chem. 2013, 78, 17, 8496–8501



  Core-modified meso-aryl hexaphyrins with an internal thiophene bridge: Structure, aromaticity, and photodynamics

Karthik G.;Sneha M.;Raja V.P.;Lim J.M.;Kim D.;Srinivasan A.;Chandrashekar T.K.

Chem. Eur. J.2013,19, 1886 – 18901886


In vitro demonstration of apoptosis mediated photodynamic activity and NIR nucleus imaging through a novel porphyrin

Karunakaran S.C.;Babu P.S.S.;Madhuri B.;Marydasan B.;Paul A.K.;Nair A.S.;Rao K.S.;Srinivasan A.;Chandrashekar T.K.;Rao C.M.;Pillai R.;Ramaiah D.

ACS Chem. Biol. 2013, 8, 1, 127–132




    Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: Turn on emission with volatile ketones and esters

Salini P.S.;Derry Holaday M.G.;Reddy M.L.P.;Suresh C.H.;Srinivasan A.

Chem. Commun., 2013,49, 2213



4,4,9,9-Tetraphenyl pyrroloindolizine: A structural analogue of calix[2]pyrrole

Sreedevi K.C.G.;Thomas A.P.;Ramakrishnan S.;Salini P.S.;Holaday M.G.D.;Reddy M.L.P.;Srinivasan A.

Org. Biomol. Chem., 2012, 10, 3600



Meso-tetrakis(p-sulfonatophenyl)N-confused porphyrin tetrasodium salt: A potential sensitizer for photodynamic therapy

Thomas A.P.;Saneesh Babu P.S.;Asha Nair S.;Ramakrishnan S.;Ramaiah D.;Chandrashekar T.K.;Srinivasan A.;Radhakrishna Pillai M.

J. Med. Chem. 2012, 55, 11, 5110–5120



  Ansa-ferrocene-incorporated calixpyrroles and calixphyrins: Syntheses and spectral/structural characterization

Ramakrishnan S.;Anju K.S.;Thomas A.P.;Gowri Sreedevi K.C.;Salini P.S.;Derry Holaday M.G.;Suresh E.;Srinivasan A.

Organometallics 2012, 31, 11, 4166–4173



Influence of calix[2]-p-benzo[4]pyrrole on the electrochemical properties of poly(ethylene oxide)-based electrolytes for lithium batteries

Stephan A.M.;Prem Kumar T.;Angulakshmi N.;Salini P.S.;Sabarinathan R.;Srinivasan A.;Thomas S.

Journal of Applied Polymer Science, 2011, 120, 2215-2221



  Confusion and neo-confusion: Corrole isomers with an NNNC core

Fujino K.;Hirata Y.;Kawabe Y.;Morimoto T.;Srinivasan A.;Toganoh M.;Miseki Y.;Kudo A.;Furuta H.

Angew. Chem. Int. Ed.2011,50, 6855 –6859

 



   Calix[2]-m-benzo[4]phyrin with aggregation-induced enhanced-emission characteristics: Application as a HgII chemosensor

Salini P.S.;Thomas A.P.;Sabarinathan R.;Ramakrishnan S.;Sreedevi K.C.G.;Reddy M.L.P.;Srinivasan A.

Chem. Eur. J.2011,17, 6598 – 66016598



Meso-aryl triphyrin(2.1.1)

Anju K.S.;Ramakrishnan S.;Srinivasan A.

Org. Lett. 2011, 13, 9, 2498–2501



Porphyrins: Syntheses and Reactions

Anand V.G.;Srinivasan A.;Chandrashekar T.K.



5,5-Diaryldipyrromethanes: Syntheses and anion binding properties

Gowri Sreedevi K.C.;Thomas A.P.;Salini P.S.;Ramakrishnan S.;Anju K.S.;Derry Holaday M.G.;Reddy M.L.P.;Suresh C.H.;Srinivasan A.

Tetrahedron Letters,2011,52,5995-5999



 

Fused core-modified meso-aryl expanded porphyrins

Chandrashekar T.K.;Prabhuraja V.;Gokulnath S.;Sabarinathan R.;Srinivasan A.

Chem. Commun., 2010, 46, 5915–5917



  Calix[n]metallocenyl[m]phyrins (n = 1, 2 and m = 2, 4): Aryl vs. alkyl

Ramakrishnan S.;Anju K.S.;Thomas A.P.;Suresh E.;Srinivasan A.

Chem. Commun., 2010, 46, 4746–4748



9,10,19,20-Tetraarylporphycenes

Anju K.S.;Ramakrishnan S.;Thomas A.P.;Suresh E.;Srinivasan A.

Org. Lett. 2008, 10, 24, 5545–5548



Synthesis of N-confused tetraphenylporphyrin rhodium complexes having versatile metal oxidation states

Srinivasan A.;Toganoh M.;Niino T.;Osuka A.;Furuta H.

Inorg. Chem. 2008, 47, 23, 11305–11313



  N-confused and N-fused meso-aryl sapphyrins

Gupta I.;Srinivasan A.;Morimoto T.;Toganoh M.;Furuta H.

Angew.Chem.Int.Ed.2008,47, 4563 –4567



  ansa-metallocene-based cyclic[2]pyrroles

Ramakrishnan S.;Srinivasan A.

Org. Lett. 2007, 9, 23, 4769–4772



  Spectroelectrochemical behavior of N-confused dioxohexaphyrins

Mayer I.;Nakamura K.;Srinivasan A.;Furuta H.;Toma H.E.;Araki K.

Journal of Porphyrins and Phthalocyanines,2005,9,813-820



Confusion approach to porphyrinoid chemistry

Srinivasan A.;Furuta H.

Acc. Chem. Res. 2005, 38, 1, 10–20


A lipophilic hexaporphyrin assembly supported on a stannoxane core

Chandrasekhar V.;Nagendran S.;Azhakar R.;Kumar M.R.;Srinivasan A.;Ray K.;Chandrashekar T.K.;Madhavaiah C.;Verma S.;Priyakumar U.D.;Sastry G.N.

J. Am. Chem. Soc. 2005, 127, 8, 2410–2411




Doubly N-confused pentaphyrins

Srinivasan A.;Ishizuka T.;Maeda H.;Furuta H.

Angew.Chem.Int.Ed.2004,43,2951–2955



Doubly N-fused pentaphyrin

Srinivasan A.;Ishizuka T.;Furuta H.

Angew.Chem.Int.Ed.2004,43, 876 –876



Doubly N-confused hexaphyrin: A novel aromatic expanded porphyrin that complexes bis-metals in the core

Srinivasan A.;Ishizuka T.;Osuka A.;Furuta H.

J. Am. Chem. Soc. 2003, 125, 4, 878–879


In Vitro and in Vivo Investigations on the Photodynamic Activity of Core-modified Expanded Porphyrin - Ammonium Salt of 5,10,15,20-tetrakis-(meso-p-sulfonato phenyl)-25,27,29-trithia Sapphyrin

Parmeswaran D.;Pushpan S.K.;Srinivasan A.;Kumar M.R.;Chandrashekar T.K.;Ganesan S.

Photochemistry and Photobiology, 2003, 78, 487-495




  Dynamic behavior and strategy for the complete 1H and 13C assignments for meso-aryl expanded heptaphyrins

Joshi B.S.;Anand V.G.;Pushpan S.K.;Srinivasan A.;Chandrashekar T.K.;Roy R.

Journal of Porphyrins and Phthalocyanines, 2002, 6, 410-422


The first bis-Rh(I) metal complex of N-confused porphyrin

Srinivasan A.;Furuta H.;Osuka A.

Chem. Commun., 2001, 1, 1666–1667



N-confused expanded porphyrin: First example of a modified sapphyrin with an inverted n-confused pyrrole ring

Pushpan S.K.;Srinivasan A.;Anand V.G.;Venkatraman S.;Chandrashekar T.K.;Joshi B.S.;Roy R.;Furuta H.

J. Am. Chem. Soc. 2001, 123, 21, 5138–5139



Characterization of a new meso-aryl rubyrin isomer: [26]Hexaphyrin (1.1.1.0.1.0) with an inverted heterocyclic ring

Pushpan S.K.;Anand V.R.G.;Venkatraman S.;Srinivasan A.;Gupta A.K.;Chandrashekar T.K. 

Tetrahedron Letters, 2001, 42, 3391-3394





Inverted meso-aryl porphyrins with heteroatoms; characterization of thia, selena, and oxa N-confused porphyrins

Pushpan S.K.;Srinivasan A.;Anand V.R.G.;Chandrashekar T.K.;Subramanian A.;Roy R.;Sugiura K.;Sakata Y.

J. Org. Chem. 2001, 66, 1, 153–161



Core modified meso-aryl sapphyrins and rubyrins: Structural and anion receptor properties

Srinivasan A.;Anand V.R.G.;Pushpan S.K.;Chandrashekar T.K.;Suguira K.I.;Sakata Y.

J. Chem. Soc., Perkin Trans. 2000, 2, 1788–1793



Structural diversity in rubyrins: X-ray structural characterisation of planar and inverted rubyrins

Narayanan S.J.;Srinivasan A.;Sridevi B.;Chandrashekar T.K.;Senge M.O.;Sugiura K.I.;Sakata              Y.

Eur. J. Org. Chem.2000,2357-22360



Structural characterization of meso aryl sapphyrins

Srinivasan A.;Anand V.G.;Jeyaprakash Narayanan S.;Pushpan S.K.;Ravi Kumar M.;Chandrashekar T.K.;Sugiura K.I.;Sakata Y.

J. Org. Chem. 1999, 64, 23, 8693–8697



Novel heteroatom containing rubyrins

Srinivasan A.;Pushpan S.K.;Ravikumar M.;Chandrashekar T.K.;Raja R.

Tetrahedro,1999, 55,6671-6680



meso-Aryl sapphyrins with heteroatoms; synthesis, characterization, spectral and electrochemical properties

Srinivasan A.;Pushpan S.K.;Kumar M.R.;Mahajan S.;Chandrashekar T.K.;Roy R.;Ramamurthy P.

J. Chem. Soc., Perkin Trans., 1999,2, 961–968



Photodynamic activity on human erythrocytes by a newly synthesized sensitizer - trithia sapphyrin sulfonate: A preliminary report

Parmeswaran D.;Ganesan S.;Thanigaivelu K.;Pushpan S.;Srinivasan A.;Ravi Kumar M.;Chandrasekar T.K.

Proceedings of SPIE - The International Society for Optical Engineering,1999,3592, 94-100

 



One pot synthesis of core modified expanded porphyrins

Pushpan S.K.;Narayanan J.S.;Srinivasan A.;Mahajan S.;Chandrashekar T.K.;Roy R.

 Tetrahedron Lett.,1998, 39,9249-9252

 



One step synthesis of sapphyrin and N-confused porphyrin using dipyrromethane

Narayanan S.J.;Sridevi B.;Srinivasan A.;Chandrashekar T.K.;Roy R.

Tetrahedron Lett.,1998,39,7389-7392


  Ground and excited state dynamics of core-modified normal and expanded porphyrins

Srinivasan A.;Ravi Kumar M.;Pandian R.P.;Mahajan S.;Simi Pushpan K.;Sridevi B.;Jayaprakash Narayanan S.;Chandrashekar T.K.

Journal of Porphyrins and Phthalocyanines,1998,2,305-314

 




Spectral, magnetic and electrochemical properties of metal oxa- and oxathia-porphyrins

Sridevi B.;Narayanan S.J.;Srinivasan A.;Chandrashekar T.K.;Subramanian J

J. Chem. Soc., Dalton Trans., 1998,1979–1984



Synthesis of meso-substituted core modified expanded porphyrins; Effect of acid catalysts on the cyclization

Srinivasan A.;Mahajan S.;Pushpan S.K.;Ravikumar M.;Chandrashekar T.K.

Tetrahedron Lett.,1998,39,1961-1964



  Spectroscopic and electrochemical studies on oxaporphyrins and oxathiaporphyrins

Sridevi B.;Jeyaprakash Narayanan S.;Srinivasan A.;Reddy M.V.;Chandrashekar T.K.

Journal of Porphyrins and Phthalocyanines,1998,2,69-78

 



Tetrathia- and tetraoxarubyrins: Aromatic, core-modified, expanded porphyrins

Srinivasan A.;Reddy V.R.M.;Jeyaprakash Narayanan S.;Sridevi B.;Pushpan S.K.;Ravikumar M.;Chandrashekar T.K.

Angew. Chem. 1997,109,2707-2710


     Improved synthesis of meso substituted 21-Oxa and 2l-Thia tetra phenyl porphyrins

Srinivasan A.;Sridevi B.;Reddy M.V.R.;Narayanan S.J.;Chandrashekar T.K.

Tetrahedron Lett.,1997,38,4149-4152









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