Publications

Mollar-Cuni, A.; Martin. S.; Guisado-Barrios, G.*; Mata, J. A.*, “Dual role of graphene as support of ligand-stabilized palladium nanoparticles and carbocatalyst for (de)hydrogenation of N-heterocycles.” Carbon., 2023, 206, 314-324.

Mollar-Cuni, A.; Ibañez-Ibañez, L. ; Guisado-Barrios, G; Mata, J. A.; Vicent, C.*, “Introducing Ion Mobility Mass Spectrometry to Identify Site-Selective C–H Bond Activation in N-Heterocyclic Carbene Metal Complexes.” J. Am. Soc. Mass. Spectrom., 2022, 33, 2291-2300.

Andrés, J. L.; Suarez, E.; Martin. M.; Sola, E.* “Mechanistic Versatility at Ir(PSiP) Pincer Catalysts: Triflate Proton Shuttling from 2-Butyne to Diene and [3]Dendralene Motifs.” Organometallics., 2022, 41, 2622-2630.

Font, P.; Valdés, H.; Guisado-Barrios, G.*; Ribas, X.* “Hemilabile MIC^N ligands allow oxidant-free Au(i)/Au(iii) arylation-lactonization of γ-alkenoic acids.” Chem. Sci., 2022, 13, 9351-9360.

Mejuto, C.; Ibáñez-Ibáñez, L.; Guisado-Barrios, G.*; Mata, J. A.* “Visible-Light-Promoted Iridium(III)-Catalyzed Aceptorless Dehydrogenation of N-heterocycles at Room Temperature.” ACS Catal., 2022, 12, 6238-6245.

Tolley, L. C.; Fernández, I. *; Bezuidenhout, D. I.*; Guisado-Barrios, G.* “Catalytic conversion of alkynes to α-vinyl sulfides mediated by carbene-linker-carbene (CXC) rhodium and iridium complexes.” Catal. Sci. Technol, 2021, 11, 516-523.

Webber, R.;  Qadir, M. I.;  Sola, E.*;  Martín, M.;  Suárez, E.;  Dupont, J.* “Fast CO2 hydrogenation to formic acid catalyzed by an Ir(PSiP) pincer hydride in a DMSO/water/ionic liquid solvent system.” Catal. Commun. 2020, 146, 106125

Mollar-Cuni, A; Borja, P.; Martin, S.; Guisado-Barrios, G.; Mata, J. A.* “A Platinum Molecular Complex Immobilised on the Surface of Graphene as Active Catalyst in Alkyne Hydrosilylation.” Eur. J. Inorg. Chem. 2020, 4254–4262.

Martin, M.; Sola, E.; "Recent advances in the chemistry of group 9—Pincer organometallics" Adv. Organometal. Chem. 2020, 73, 79–193. Elsevier, ISBN 9780128206904

Fisher, S.; Scott, M.; Tej, V.; Lee; S.; Chan, A.; Banda, I.; Gregory, A.; Berkley, K.; Tsay, C.; Rheingold, A.; Guisado-Barrios, G.; Lavallo, V. * “Strongly Coordinating Ligands to Form Weakly Coordinating yet Functional Organometallic Anions.” J. Am. Chem. Soc. 2020, 142, 1, 251–256.

Pinto, M. F.; Olivares, M.; Vivancos, M.; Guisado-Barrios, G.; Albrecht, M. *; Royo, B.* “(Di)Triazolylidene Manganese Complexes in Catalytic Oxidation of Alcohols.” Catat. Sci. Technol. 2019, 9, 2421-2425. 

Boehmer, M.; Guisado-Barrios, G.*; Kampert, F.; Tan, T.; Peris, E. *; Hahn, F. E.* “Synthesis and Catalytic Applications of Heterobimetallic Carbene Complexes Obtained via Sequential Metalation of Two Bisazolium Salts” Organometallics, 2019, 38, 2120-2131. 

 Martinez-Agramunt, V.; Eder, T.; Darmandeh, H.; Guisado-Barrios, G.; Peris, E.* “A shape-adaptable organometallic metallo-square encapsulates fullerenes and behaves as catalyst for sensitizing anthracene dimerization.” Angew. Chem. Int. Ed., 2019, 58, 5682-5686. 

Tolley, L.; Strydom, I.; Fernandes. M.; Bezuidenhout, D. I. *; Guisado-Barrios, G.* “Diverse Coordination Modes of Bidentate COC- and Tridentate CNC-Ligands Based on 1,2,3-Triazol-5-ylidenes.” ACS Omega, 2019, 4, 6360-6374. 

Al-Shnanni, F.; Guisado-Barrios, G.*; Sainz, D.; Peris, E.* “Tris-Triazolium salts as anion receptors and as precursors for the preparation of cylinder-like coordination cages.” Organometallics, 2019, 38, 697-701. 

De Aguirre, A.; Diéz-González, S.; Maseras, F.*; Sola, E. * “The Acetate Proton Shuttle between Mutually Trans Ligands .” Organometallics., 2018, 37, 2645-2651. 

Guisado-Barrios, G.*; Soleilhavoup, M.; Bertrand, G.* “1H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes.” Acc. Chem. Res., 2018, 51, 3236-3244. 

Böhmer, M.; Kampert, F.; Tan, T. T. Y.; Guisado-Barrios, G.; Peris, E. *; Hahn, F. E. * “IrIII/AuI and RhIII/AuI Heterobimetallic Complexes as Catalysts for the Coupling of Nitrobenzene and Benzylic Alcohol.” Organometallics., 2018, 37, 4092-4099. 

Sola, E.* “Silicon-based Pincers: Trans Influence and Functionality" Book "Pincer Compounds: Chemistry and Applications" Elsevier. 2018, 401-411. 

Kleinhans, G.; Guisado-Barrios, G.*; Peris, E.; Bezuidenhout, D. I.* “Ruthenium(II) pincer complexes featuring an anionic
CNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinated in a meridional fashion.” Polyhedron, 2018, 143, 43-48. (Invited article) 

Strydom, I.; Guisado-Barrios, G.*; Fernández, I.; Lilles, D. C.; Peris, E.; Bezuidenhout, D. I.* “A hemilabile and cooperative N-donor functionalized 1,2,3-triazol-5-ylidene ligand for selective and base-free rhodium(I) catalyzed alkyne hydrothiolation reactions.” Chem. Eur. J., 2017, 23, 1393-1401. (Hot paper)

Suárez, E.; Plou, P.; Gusev. D.*; Martín, M.; Sola, E.* “Cationic, neutral and anionic hydrides with PSiP pincers.” Inorg. Chem., 2017, 56, 7190-7199. 

Kleinhans, G.; Hansmann, Max. M.; Guisado-Barrios, G.; Lilles, D. C.; Bertrand, G.; Bezuidenhout, D. I. * “Nucleophilic T‐Shaped (LXL)Au(I)-Pincer Complexes: Protonation  and Alkylation.” J. Am. Chem. Soc., 2016, 138, 15873–15876. (Highlighted in JACS Spotlights)

Kleinhans, G.; Guisado-Barrios, G.*; Lilles, D. C.; Bertrand, G.; Bezuidenhout, D. I.* “Rhodium(I) Oxygen Adduct as a Selective Catalyst for One-Pot Sequential Alkyne Dimerization-Hydrothiolation Tandem Reactions.” Chem. Commun., 2016, 52, 3504-3507. 

Mejuto, C.; Guisado-Barrios, G.*; Gusev, D.; Peris, E.* “First homoleptic MIC and heteroleptic NHC–MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands.” Chem. Commun., 2015, 51, 13914-13917. 

Mejuto, C.; Royo, B.; Guisado-Barrios, G.*; Peris, E.* “Rhodium, iridium and nickel complexes with a 1,3,5-triphenyl- benzene tris-MIC ligand. Study of the electronic properties and catalytic activities.” Beilstein J. Org. Chem., 2015, 11, 2584-2590. (Invited article)

Mejuto, C.; García-Eleno, M. A.; Guisado-Barrios, G.*; Spasyuk, D.; Gusev, D.; Peris, E.*  “Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties.” Org. Chem. Front., 2015, 2, 936-941.

Bezuidenhout, D. I.*; Kleinhans, G.; Guisado-Barrios, G.; Lilles, D. C.; Ung, G. I.; Bertrand, G.* “Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes” Chem. Commun., 2014, 50, 2431-2433. 

Mejuto, C.; Guisado-Barrios, G.*, Peris, E.*, “Novel Rhodium and Iridium Complexes Coordinated to C3-Symmetric Tris-NHC Ligands Based on a 1,3,5-Triphenylbenzene Core: Electronic and Catalytic Properties”,Organometallics, 2014, 33, (12), 3205-3211. 

 Segarra, C.; Guisado-Barrios, G.; Hahn, F. E. *; Peris, E.* “Hexanuclear cylinder-shaped assemblies of silver and gold from benzene-hexa-N-heterocyclic carbenes.” Organometallics, 2014, 33, (19), 5077- 5080. 

 Bratko, I.; Guisado-Barrios, G.; Favier, I.; Mallet-Ladeira, S.; Teuma, E.; Peris, E.* Gómez, M.* “Triazolium Salts as Appropriate Catalytic Scaffolds for 1,4-Additions to α, β-Unsaturated Carbonyls.” Eur. J. Org. Chem., 2014, 2160–2167.

Ruiz Botella, S.; Guisado-Barrios, G.; Mata, J. A.; Peris, E.*, “Singularities of a Bis(p-xylyl)bis(benzimidazolylidene) Ligand and the Bis-iridium and -rhodium-Related Complexes” Organometallics, 2013, 32, (21) 6613-6619. 

Guisado-Barrios, G.; Hiller, J.; Peris, E.* “Pyracene-Linked Bis- Imidazolylidene Complexes of Palladium and Some Catalytic Benefits Produced by Bimetallic Catalysts”
Chem. Eur. J. 2013, 19,  (31), 10405-10411. 

 Guisado-Barrios, G.; Muñoz, B. K.; Kamer, P. C. J. *; Lastdrager, B.; van der Marel, G.; Overhand, M. *; Vega Vazquez, M.; Martin Pastor, M. l.; “Cyclic decapeptide Gramicidin S analogues containing phosphines: Novel ligands for asymmetric catalysis.”
 Dalton Trans., 2013, 42, 1973-1978. 

Yan, X, Bouffard, J. Guisado-Barrios, G.; Donnadieu, B. Bertrand, G.* “Anionic 1,2,3-Triazole-4,5-diylidene: A 1,2-Dihapto Ligand for the Construction of Bimetallic Complexes” Chem. Eur. J., 2012, 18, 14627-14631. 

Guisado-Barrios, G.; Zhang, Y.; Harkins, A. M.; Richens, D. T.* “Low temperature reaction of [Fe(TPA)(CH3CN)2]2+ with excess 3-chloroperoxybenzoic acid in semi-frozen acetonitrile; EPR     detection of an acylperoxo iron(III) adduct. Inorg. Chem. Commun., 2012, 20, 81-85.


Guisado-Barrios, G.; Bouffard, J.; Donnadieu, B.; Bertrand, G.* "Bis(1,2,3-triazol- 5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs)",  Organometallics  2011, 30, 6017–6021.

Bouffard, J.; Keitz, B. K.; Tonner, R.; Guisado-Barrios, G.; Frenking, G.; Grubbs, R. H.*; Bertrand, G.* "Synthesis of Highly Stable 1,3- Diaryl-1H-1,2,3-triazol-5-ylidenes and Their Applications in Ruthenium- Catalyzed Olefin Metathesis", Organometallics 2011, 30, (9) 2617–2627.

Guisado-Barrios, G.; Bouffard, J.; Donnadieu, B.; Bertrand, G. * "Crystalline 1H- 1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)", Angew. Chem. Int. Ed. 2010, 49, 4759–4762. 

Guisado-Barrios, G.; Slawin, A. M. Z.; Richens, D. T.* “Iron Complexes of New Hydrophobic Derivatives of Tris(2-pyridylmethyl)amine: Synthesis, Characterization, and Catalysis of Alkane Oxygenation by H2O2.” 
J. Coord. Chem., 2010, 63, 2624-2658.

Sequaris, J. M.*; Guisado-Barrios, G.; Magarinos, M.; Moreno, C.; Burauel, P.; Hans-Dieter, N.; Vereecken, H. “Organic-carbon fractions in an agricultural topsoil assessed by the determination of the soil mineral surface área.” 
J. Plant. Nutr. Soil Sci., 2010, 173, 699-705.

Guisado-Barrios, G.; Li, Y.; Slawin, A. M. Z.; Richens, D. T.*; Gass. I. A.; Yellowlees, L. J*. “High spin d5Complexes of Tris(6- hydroxymethyl-pyridylmethyl)amin (H3L): Hepta-coordinated [Mn(H3L)]Cl2 and [Fe3L2] (ClO4)3; an Unusual Weakly Antiferromagnetically-Coupled Alkoxide-Bridged Linear Triiron (III) Complex with a Right Fe-O-Fe Angle. Dalton Trans., 2008, 4, 551-558.

Mollar-Cuni, A.; Martin. S.; Guisado-Barrios, G.*; Mata, J. A.*, “Dual role of graphene as support of ligand-stabilized palladium nanoparticles and carbocatalyst for (de)hydrogenation of N-heterocycles.” Carbon., 2023, 206, 314-324.