Objective of the Course: This course is intended for graduate engineering students interested in specializing and advancing their research in the field of metals and alloys processing. Prior basic knowledge in materials science and thermodynamics is expected. The course aims to equip students with the ability to read and interpret binary and ternary phase diagrams. Additionally, it will enable them to predict microstructures of metals and alloys and understand the thermodynamic and kinetic aspects of crucial transformations.
Material
Bibliografia Recomendada:
1) Phase transformations in metals and alloys (DA Porter)
2) Materials Science: Volume 2 Phase Transformation and Properties (G Hu)
3) Thermodynamics Of Materials (Ragone)
4) M Hillert, Phase equilibria, phase diagrams and phase transformations: their thermodynamic basis.
5) D.R. Askeland, Ciência e engenharia dos materiais.
6) H. Saka, Introduction to Phase Diagrams in Materials Science and Engineering, World Scientific, 2020.
7) F.C. Campbell, Phase Diagrams: Understanding the Basics, ASM International, 2012
In this module, we will begin with an explanation of what constitutes and how to define a phase, accompanied by an introduction to the science of crystallography. Next, we will discuss reading phase diagrams to predict equilibrium and phase transformations in unary and binary systems. We will also introduce intermediate and intermetallic phases and the systems that contain them. Finally, we will explore concepts of interpreting basic information in ternary phase diagrams.
What is a phase?
Basics of Crystallography
Links:
Equilibria (stable and metastable) x Instability
Gibbs phase rule
Phase transformation
Solid Solutions
Binary Phase diagrams
Invariant reactions
Binary Compounds
Links
Complementary material (Articles):
In this module, we will explore the fundamentals of the thermodynamics of phase transformations in alloys. We will begin with an analysis of the thermodynamic laws governing phase transformations in alloy systems, including concepts such as Gibbs free energy and phase stability criteria. Next, we will delve into understanding the phase transformations, such as solidification, and solutions.
In this module, we will delve into the fundamental principles and mechanisms of diffusion in alloys. We will begin by exploring the driving forces behind diffusion, including concentration gradients and chemical potential differences. We will then examine the mathematical descriptions of diffusion processes, such as Fick's laws, and how these laws govern the movement of atoms in a solid solution. We will also discuss the various types of diffusion, including volume diffusion, grain boundary diffusion, and surface diffusion, and their respective roles in alloy systems. Key factors influencing diffusion rates, such as temperature, atomic size, and crystal structure, will be analyzed. Furthermore, we will investigate practical applications and implications of diffusion in materials science, such as the formation of diffusion couples, the homogenization of alloys, and the impact of diffusion on phase transformations and microstructural evolution.
Complementary material (Articles):
Interdiffusion Coefficients and Strengthening Effects of Nb, Ta, and Zr in the α2-Ti3Al Phase
Complementary material (Articles):
Interdiffusion Coefficients and Strengthening Effects of Nb, Ta, and Zr in the α2-Ti3Al Phase