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Wright State Publications
Wright State Publications
31. Mercury(II) Halide Complexes of Bis(tert-butylamido)cyclodiphosph(V)azane, cis-[(tBuNH)(E)P(μ-NtBu)2P(E)(NHtBu)] (E = S, Se), Troy, S. K., Sampath, K., Arumugam, K.,* P. Chandrasekaran* Acta. Cryst. E,. (accepted).
30. Synthesis, Structure, and Assessment of Metal bis(dithiolene) Adducts Containing Redox-active N-Heterocyclic Carbenes Selvakumar, J, Dilsha, S. W., Arumugam, K.,*. E. J. Orgmet. Chem (revision).
29. Structural and Electrochemical Insights into Five Coordinate Cobalt bis(dithiolene) N-heterocyclic carbene Complexes, Selvakumar, J., Sampath, K., Leedy, C. L., Raska, L., and Arumugam, K.,* Inorg. Chim. Acta, 2024, 572, 122252.
28. Bis[1,3-bis(2,4,6-trimethylphenyl)imidazolium] bis(1,2-diphenylethene-1,2-dithiolato-bis[(cis-1,2-diphenylethene-1,2-dithiolato)iron(III)] dimethylformamide disolvate, Selvakumar, J., Arumugam, K.,* IUCrData, 9, (1), 2024, x231083.
27. A new ferrocene derivative blocks KRAS localization and function by oxidative modification at His95. Rehl, K. M., Selvakumar, J., Hoang, D., Arumugam, A., Gorfe, A., Cho K. J.,* Life Sci. Alliance, 6, (11), 2023. DOI: 10.26508/lsa.202302094.
26. Detailed Structural and Spectroscopic Elucidation of Ferrocenium Coupled N-heterocyclic Carbene Gold(I) Complexes Reinhard, G., Selvakumar, J., Prybil, Arambula, J. F., and Arumugam, K.*, Dalton. trans., 2022, 51, 1533-1541 DOI: 10.1039/d1dt03174k.
25. Zn Coordination and the Nature of the Halide Ancillary Ligand Dramatically Influences the Photophysical Properties of 2,3-di(pyridin-2-yl)benzo[g]quinoxaline, Lauren Loftus, Emma C. Olsen, David J. Stewart, Alexis T. Phillips, Arumugam, K., Albert Fratini, Scott T. Iacono, Thomas M. Cooper, Joy E. Haley, and Tod A. Grusenmeyer, Inorg. Chem., 2021, 60, 16570-16583.
24. An Electrochemically Controlled Release of NHCs Using Iron Bis(dithiolene) N-heterocyclic Carbene Adducts Selvakumar, J., Simpson, S. M., Zurek, E., and Arumugam, K.,* Inorg. Chem. Front., 2021, 8, 59-71.
23. Open-Ended Metallodithiolene Complexes with the 1,2,4,5-Tetrakis(diphenylphosphino)benzene Ligand: Modular Building Elements for the Synthesis of Multimetal Complexes, Satyendra Kumar*, Malathy Selvachandran, M., Arumugam, K., Shaw, M., Wu, C., Maurer, M., Zhang, Z., Sproules, S., Mague, J. T., and Donahue J. P.,* Inorg. Chem., 2021, 60, 13177-13192.
22. Rationally Designed Redox-Active Au (I) N-Heterocyclic Carbene: An Immunogenic Cell Death Inducer S Sen, S Hufnagel, EY Maier, I Aguilar, J Selvakumar, JE DeVore, VM Lynch, Arumugam, K.,*, Z Cui, JL Sessler, J F Arambula, J. Am Chem. Soc., 2020, 142 (49), 20536-20541.
21. Synthesis and crystal structure of 1,1',3,3'-tetramesitylquinobis(imidazolidine)-2,2'-dithione, Selvakumar, and Arumugam, K.,* IUCrData., accepted).
20. PCT Int. Appl. (2019), WO 2019006327 A1 20190103, Naphthoquinone containing gold carbene complexes and methods of uses thereof by: Arambula, Jonathan; Arumugam, Kuppuswamy; Sessler, Jonathan L.; Bielawski, Christopher Assignee: Board of Regents, The University of Texas System, USA; Georgia Southern University; Wright State University.
19. Expanding the biological utility of bis-NHC gold(I) complexes through post synthetic carbamate conjugation, Sajal, S., Li, Y., Lynch, V., Arumugam, K., Sessler, J. L.,* and Arambula J. F.,* Chem. Comm., 2019, 55, 10627-10630. .
17. Synthesis and molecular structure of biologically significant bis(1,3-dimesityl-4,5-naphthoquinoimidazol-2-ylidene)gold(I) complexes with chloride and dichloridoaurate counter-ions, Selvakumar J., Miles, M. H., Grossie D. A., and Arumugam, K.,* Acta Cryst. (2019). C75, 462-468. [Link]
16. Dual Targeting of the Cancer Antioxidant Network with Naphthoquinone Fused Gold(I) N-heterocyclic Carbene Complexes, McCall, R., Miles, M., Kocerha, J., Sittaramane, V., Burney, B., Patel, Z., Sideman, J. K., Grossi, A. D., Sessler, L. J., Arumugam, K.,* and Arambulaa, F. J.,*Chem. Sci., 2017, Advance Article. (chosen by Chemical Science as HOT ARTICLE for the month of July, 2017). [Link]
15. Structural and Spectroscopic Characterization of Five Coordinate Iron and Cobalt bis(dithiolene)-trimethylphosphine Complexes, Selby-Karney, T., Grossi A. D., Arumugam K., Wright, E., P. Chandrasekaran, Journal of Molecular Structure, 2017, 1141, 477-483. [Link]
14. Targeting Antioxidant Pathways with Ferrocenylated N-heterocyclic Carbene Supported Gold(I) Complexes in A549 Lung Cancer Cells Arambula, J. F,* McCall, R., Sidoran, K., Magda, D., Mitchell, N., Bielawski, C., Lynch, V., Sessler, J. and Arumugam, K.,* Chem. Sci., 2016, 7, 1245-1256. [Link]
Graduate and Postdoctoral Publications
Graduate and Postdoctoral Publications
13. 1,6-Enyne Cyclizations Catalyzed by N-Heterocyclic Carbene Supported Gold Complexes: Deconvoluting Sterics and Electronics Arumugam, K.; Varghese, B.; Brantley, J. N.; Konda, S.; Lynch, V. M.; Bielawski, C. W. Eur. J. Org. Chem. 2014, 493-497. [Link]
12. Metal-centered oxidations facilitate the removal of ruthenium-based olefin metathesis catalysts Rosen, E. L.; Varnado Jr, C. D.; Arumugam, K.; Bielawski, C. W. J. Organomet. Chem. 2013, 745, 201-205. [Link]
10. Synthesis and Electronic Insights in to Cationic [(Fc-NHC)2IrLn][IrLnCl2] (Ln = COD, CO) Complexes; Arumugam, K.; Chang. J.; Bielawski, C. W. Organometallics 2013, 32, 4334. [Link]
9. Redox‐Switchable Ring‐Closing Metathesis: Catalyst Design, Synthesis, and Study; Arumugam, K.; Varnado, D. C.; Sproules, S.; Lynch, V. M.; Bielawski, C. W. Chemistry-A European Journal 2013, 19, 10866. [Link]
Chemistry Views, July 24, 2013
8. Structures of the Dithiolene Ligand and Tetrathiafulvalene Precursor Molecules 4,5-Di(bromomethyl)-1,3-dithiol-2-one and 4,5-Di(methylphosphonic acid)-1,3-dithiol-2-one; Arumugam, K.; Clark, D. S.; Mague, J. T.; Donahue, J. P. Acta Cryst. 2011, C67, o446. [Link]
7. Structurally Characterized Cationic Silver(I) and Ruthenium(II) Carbene Complexes of 1,2,3-Triazol-5-ylidenes. Cai, J.; Yang, X.; Arumugam, K.; Bielawski, C. W.; Sessler, J. L. Organometallics, 2011, 30, 5033–5037. [Link]
6. Long Range Spin Coupling: A Tetraphosphine-Bridged Palladium Dimer. Arumugam. K.; Mohamed, C. S.; Mague, J. T.; Bill, E.; Sproules, S.; Donahue, J. P. Inorg. Chem. 2011, 50, 2995–3002. [Link]
5. Synthesis and Properties of 1,2,4,5-Benzenetetrathiolate-Linked Group(VII) Metal Complexes. Arumugam. K.; Mohamed, C. S.; Perumalreddy, C.; Villgrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P. Inorg. Chem. 2009, 48 10591–10607. [Link]
4. Synthesis, Structures and Properties of Mixed Dithiolene-Carbonyl and Dithiolene-Phosphine Complexes of Tungsten. Perumalreddy, C.; Arumugam, K.; Upul, J.; Lisa, M. P.; Joel, T. M.; Donahue, J. P. Inorg. Chem. 2009, 48, 2103–2113. [Link]
3. A Convergent Approach to the Synthesis of Multimetallic Dithiolene Complexes. Arumugam, K.; Yu, R.; Villgrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P. Inorg. Chem. 2008, 47, 5570-5572. [Link]
2. Reversible, Electrochemically Controlled Binding of Phosphine to Iron and Cobalt Bis(dithiolene) Complexes. Yu, R.; Arumugam, K.; Manepalli, A.; Tran, Y.; Schmehl, R.; Jacobsen, H.; Donahue, J. P. Inorg. Chem. 2007, 46, 5131-5133. [Link]
1. Preparation and Isolation of Dithiolene Thiophosphoryl Molecules as Stable, Protected Forms of Dithiolene Ligands. Arumugam, K.; Bollinger, J.; Fink, M.; Donahue, J. P. Inorg. Chem. 2007, 46, 3283-3288. [Link]
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