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Wright State Publications
Wright State Publications
31. Synthesis, Structure, and Assessment of Metal bis(dithiolene) Adducts Containing Redox-active N-Heterocyclic Carbenes Selvakumar, J, Dilsha, S. W., Arumugam, K.,*. E. J. Orgmet. Chem Inorg. Chim. Acta, 2026, 589, 122921. https://doi.org/10.1016/j.ica.2025.122921
30. Mercury(II) Halide Complexes of Bis(tert-butylamido)cyclodiphosph(V)azane, cis-[(tBuNH)(E)P(μ-NtBu)2P(E)(NHtBu)] (E = S, Se), Troy, S. K., Sampath, K., Arumugam, K.,* P. Chandrasekaran* Acta. Cryst. E,. 2024 Oct 8;80(Pt 11):1142–1145. doi: 10.1107/S205698902400937X
29. Structural and Electrochemical Insights into Five Coordinate Cobalt bis(dithiolene) N-heterocyclic carbene Complexes, Selvakumar, J., Sampath, K., Leedy, C. L., Raska, L., and Arumugam, K.,* Inorg. Chim. Acta, 2024, 572, 122252.
28. Bis[1,3-bis(2,4,6-trimethylphenyl)imidazolium] bis(1,2-diphenylethene-1,2-dithiolato-bis[(cis-1,2-diphenylethene-1,2-dithiolato)iron(III)] dimethylformamide disolvate, Selvakumar, J., Arumugam, K.,* IUCrData, 9, (1), 2024, x231083.
27. A new ferrocene derivative blocks KRAS localization and function by oxidative modification at His95. Rehl, K. M., Selvakumar, J., Hoang, D., Arumugam, A., Gorfe, A., Cho K. J.,* Life Sci. Alliance, 6, (11), 2023. DOI: 10.26508/lsa.202302094.
26. Detailed Structural and Spectroscopic Elucidation of Ferrocenium Coupled N-heterocyclic Carbene Gold(I) Complexes Reinhard, G., Selvakumar, J., Prybil, Arambula, J. F., and Arumugam, K.*, Dalton. trans., 2022, 51, 1533-1541 DOI: 10.1039/d1dt03174k.
25. Zn Coordination and the Nature of the Halide Ancillary Ligand Dramatically Influences the Photophysical Properties of 2,3-di(pyridin-2-yl)benzo[g]quinoxaline, Lauren Loftus, Emma C. Olsen, David J. Stewart, Alexis T. Phillips, Arumugam, K., Albert Fratini, Scott T. Iacono, Thomas M. Cooper, Joy E. Haley, and Tod A. Grusenmeyer,* Inorg. Chem., 2021, 60, 16570-16583.
24. An Electrochemically Controlled Release of NHCs Using Iron Bis(dithiolene) N-heterocyclic Carbene Adducts Selvakumar, J., Simpson, S. M., Zurek, E., and Arumugam, K.,* Inorg. Chem. Front., 2021, 8, 59-71.
23. Open-Ended Metallodithiolene Complexes with the 1,2,4,5-Tetrakis(diphenylphosphino)benzene Ligand: Modular Building Elements for the Synthesis of Multimetal Complexes, Satyendra Kumar*, Malathy Selvachandran, M., Arumugam, K., Shaw, M., Wu, C., Maurer, M., Zhang, Z., Sproules, S., Mague, J. T., and Donahue J. P.,* Inorg. Chem., 2021, 60, 13177-13192.
22. Rationally Designed Redox-Active Au (I) N-Heterocyclic Carbene: An Immunogenic Cell Death Inducer S Sen, S Hufnagel, EY Maier, I Aguilar, J Selvakumar, JE DeVore, VM Lynch, Arumugam, K., Z Cui, JL Sessler, J F Arambula,* J. Am Chem. Soc., 2020, 142 (49), 20536-20541.
21. Synthesis and crystal structure of 1,1',3,3'-tetramesitylquinobis(imidazolidine)-2,2'-dithione, Selvakumar, and Arumugam, K.,* IUCrData., accepted).
20. PCT Int. Appl. (2019), WO 2019006327 A1 20190103, Naphthoquinone containing gold carbene complexes and methods of uses thereof by: Arambula, Jonathan; Arumugam, Kuppuswamy; Sessler, Jonathan L.; Bielawski, Christopher Assignee: Board of Regents, The University of Texas System, USA; Georgia Southern University; Wright State University.
19. Expanding the biological utility of bis-NHC gold(I) complexes through post synthetic carbamate conjugation, Sajal, S., Li, Y., Lynch, V., Arumugam, K., Sessler, J. L.,* and Arambula J. F.,* Chem. Comm., 2019, 55, 10627-10630. .
17. Synthesis and molecular structure of biologically significant bis(1,3-dimesityl-4,5-naphthoquinoimidazol-2-ylidene)gold(I) complexes with chloride and dichloridoaurate counter-ions, Selvakumar J., Miles, M. H., Grossie D. A., and Arumugam, K.,* Acta Cryst. (2019). C75, 462-468. [Link]
16. Dual Targeting of the Cancer Antioxidant Network with Naphthoquinone Fused Gold(I) N-heterocyclic Carbene Complexes, McCall, R., Miles, M., Kocerha, J., Sittaramane, V., Burney, B., Patel, Z., Sideman, J. K., Grossi, A. D., Sessler, L. J., Arumugam, K.,* and Arambulaa, F. J.,* Chem. Sci., 2017, Advance Article. (chosen by Chemical Science as HOT ARTICLE for the month of July, 2017). [Link]
15. Structural and Spectroscopic Characterization of Five Coordinate Iron and Cobalt bis(dithiolene)-trimethylphosphine Complexes, Selby-Karney, T., Grossi A. D., Arumugam K., Wright, E., P. Chandrasekaran, Journal of Molecular Structure, 2017, 1141, 477-483. [Link]
14. Targeting Antioxidant Pathways with Ferrocenylated N-heterocyclic Carbene Supported Gold(I) Complexes in A549 Lung Cancer Cells Arambula, J. F,* McCall, R., Sidoran, K., Magda, D., Mitchell, N., Bielawski, C., Lynch, V., Sessler, J. and Arumugam, K.,* Chem. Sci., 2016, 7, 1245-1256. [Link]
Graduate and Postdoctoral Publications
Graduate and Postdoctoral Publications
13. 1,6-Enyne Cyclizations Catalyzed by N-Heterocyclic Carbene Supported Gold Complexes: Deconvoluting Sterics and Electronics Arumugam, K.; Varghese, B.; Brantley, J. N.; Konda, S.; Lynch, V. M.; Bielawski, C. W. Eur. J. Org. Chem. 2014, 493-497. [Link]
12. Metal-centered oxidations facilitate the removal of ruthenium-based olefin metathesis catalysts Rosen, E. L.; Varnado Jr, C. D.; Arumugam, K.; Bielawski, C. W. J. Organomet. Chem. 2013, 745, 201-205. [Link]
10. Synthesis and Electronic Insights in to Cationic [(Fc-NHC)2IrLn][IrLnCl2] (Ln = COD, CO) Complexes; Arumugam, K.; Chang. J.; Bielawski, C. W. Organometallics 2013, 32, 4334. [Link]
9. Redox‐Switchable Ring‐Closing Metathesis: Catalyst Design, Synthesis, and Study; Arumugam, K.; Varnado, D. C.; Sproules, S.; Lynch, V. M.; Bielawski, C. W. Chemistry-A European Journal 2013, 19, 10866. [Link]
Chemistry Views, July 24, 2013
8. Structures of the Dithiolene Ligand and Tetrathiafulvalene Precursor Molecules 4,5-Di(bromomethyl)-1,3-dithiol-2-one and 4,5-Di(methylphosphonic acid)-1,3-dithiol-2-one; Arumugam, K.; Clark, D. S.; Mague, J. T.; Donahue, J. P. Acta Cryst. 2011, C67, o446. [Link]
7. Structurally Characterized Cationic Silver(I) and Ruthenium(II) Carbene Complexes of 1,2,3-Triazol-5-ylidenes. Cai, J.; Yang, X.; Arumugam, K.; Bielawski, C. W.; Sessler, J. L. Organometallics, 2011, 30, 5033–5037. [Link]
6. Long Range Spin Coupling: A Tetraphosphine-Bridged Palladium Dimer. Arumugam. K.; Mohamed, C. S.; Mague, J. T.; Bill, E.; Sproules, S.; Donahue, J. P. Inorg. Chem. 2011, 50, 2995–3002. [Link]
5. Synthesis and Properties of 1,2,4,5-Benzenetetrathiolate-Linked Group(VII) Metal Complexes. Arumugam. K.; Mohamed, C. S.; Perumalreddy, C.; Villgrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P. Inorg. Chem. 2009, 48 10591–10607. [Link]
4. Synthesis, Structures and Properties of Mixed Dithiolene-Carbonyl and Dithiolene-Phosphine Complexes of Tungsten. Perumalreddy, C.; Arumugam, K.; Upul, J.; Lisa, M. P.; Joel, T. M.; Donahue, J. P. Inorg. Chem. 2009, 48, 2103–2113. [Link]
3. A Convergent Approach to the Synthesis of Multimetallic Dithiolene Complexes. Arumugam, K.; Yu, R.; Villgrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P. Inorg. Chem. 2008, 47, 5570-5572. [Link]
2. Reversible, Electrochemically Controlled Binding of Phosphine to Iron and Cobalt Bis(dithiolene) Complexes. Yu, R.; Arumugam, K.; Manepalli, A.; Tran, Y.; Schmehl, R.; Jacobsen, H.; Donahue, J. P. Inorg. Chem. 2007, 46, 5131-5133. [Link]
1. Preparation and Isolation of Dithiolene Thiophosphoryl Molecules as Stable, Protected Forms of Dithiolene Ligands. Arumugam, K.; Bollinger, J.; Fink, M.; Donahue, J. P. Inorg. Chem. 2007, 46, 3283-3288. [Link]
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