Today transparent ceramics as well as single crystals are very important as laser hosts for rare earth dopant ions emmitting from Visible to Infrared spectral region. Laser gain materials, both pure and mixed compositions, are critical in determining the efficiency, wavelength range, and overall performance of laser systems. Mixed matrices are advantageous in order to obtain broader absorption and emission spectra with respect to mono composition hosts. The advantage of obtaining broader absorption spectra is in the possibility of pump the laser material efficiently with the suitable laser diode. The possibility of obtaining broader emission spectra is even of greater importance in order to achieve wide tunability range and to generate and amplify ultrashort laser pulses suitable for different applications, such as environmental monitoring, laser material processing, particle acceleration in laser excited plasma. We have focused our activity principally on both pure and mixed compositions polychristalline ceramics such as: Garnets, in pure or mixed compositions: YAG (Yttrium Aluminum Garnet), YSAG (Yttrium Scandium Aluminum Garnet), LuAG (Lutetium Aluminum Garnet), Gd-YAG (Gadolinium Yttrium Aluminum Garnet), Sesquioxides: pure Lu2O3, Y2O3, Sc2O3, and combinations thereof to achieve mixed compositions, Fluorides: CaF2.
Metasurfaces can be opportunely and specifically designed to manipulate electromagnetic wavefronts. A large variety of metasurface-based optical devices such as planar lenses, beam deflectors, polarization converters and so on, have been designed and fabricated. Of particular interest are tunable metasurfaces, which allow the modulation of the optical response of a metasurface. Response tunability can be achieved through external sources that modify the permittivity of the materials constituting the nanoatoms, the substrate, or both.
Temperature Resolved (9 K-300 K) and emission spectroscopy with high wavelength resolution is a technique used to study molecular and solid-state systems at cryogenic temperatures. By cooling samples, typically to liquid helium temperatures, it is possible to resolve fine details in absorption and emission spectra, providing insights into electronic and vibrational states with high precision. This technique is essential in chemistry and physics for investigating electronic structure, exciton dynamics, and molecular interactions in complex systems. Applications include the study of quantum dots, organic semiconductors, and defect centers in crystals. It reveals fundamental information about energy levels and electronic transitions.
Time-correlated single photon counting (TCSPC) is a technique that measures the precise time intervals between photon detection events, allowing the study of fluorescence lifetimes with picosecond resolution. A pulsed laser excites the sample, and single photons emitted by fluorescence are detected, building a time histogram that reflects the decay profile. This technique is crucial in chemistry and physics for studying molecular dynamics, energy transfer processes, and fluorescence resonance energy transfer (FRET). Applications include materials science, biological imaging, and the development of organic light-emitting diodes (OLEDs) and quantum dots. TCSPC provides insights into molecular interactions, reaction kinetics, and microenvironmental effects on fluorophores.