Synthesis and reactivity of a six-membered heterocyclic 1,3-diphosphaallene
M. K. Sharma, C. Wölper, H. Siera, G. Haberhauer, S. Schulz*
Chemical Science, 2025, 16, 1189-1196. (IF = 7.6) Link
Gallaphosphene L(Cl)GaPGaL: A novel phosphinidene transfer reagent
M. K. Sharma, H. M. Weinert, C. Wölper, S. Schulz*
Chem. Eur. J., 2024, e202400110. (IF = 4.3) Link
Syntheses and Structures of 5-Membered Heterocycles Featuring 1,2-Diphospha-1,3-Butadiene and Its Radical Anion
M. K. Sharma, H. M. Weinert, B. Li, C. Wölper, J. T. Henthorn, G. E. Cutsail III, G. Haberhauer, S. Schulz*
Angew. Chem. Int. Ed., 2023, 62, e202309466; Angew. Chem. 2023, 135, e202309466 (IF = 16.6) Link
Sharma, M. K.; Chabbra, S.; Wölper, C.; Weinert, H. M.; Reijerse, E. J.; C.; Schnegg, A.; Schulz, S. “Modulating the frontier orbitals of L(X)Ga-substituted diphosphenes [L(X)GaP]2 (X = Cl, Br) and their facile oxidation to radical cations” Chem. Sci., 2022, 13, 12643-12650. [Highlighted on the inside front cover of the issue] (IF = 7.6)
Sharma, M. K.; Dhawan, P.; Helling, C.; Wölper, C.; Schulz, S. “Bis-phosphaketenes LM(PCO)2 (M = Ga, In): A new class of reactive group 13 metal–phosphorus compounds” Chem. Eur. J., 2022, 28, e202200444 (This article was featured in ChemistryViews) (IF = 4.3)
Sharma, M. K.; Wölper, C.; Schulz, S. “Selective 1,2 addition of polar X‒H bonds to the Ga–P double bond of gallaphosphene L(Cl)GaPGaL” Dalton Trans., 2022, 51, 16121616. (IF = 4.0)
Sharma, M. K.; Wölper, C.; Haberhauer, G.; Schulz, S. “Reversible and Irreversible 2+2 Cycloaddition reactions of Heteroallenes to a Gallaphosphene” Angew. Chem. Int. Ed., 2021, 60, 21784-21788. (IF = 16.6)
Sharma, M. K.; Wölper, C.; Haberhauer, G.; Schulz, S. “Multi‐Talented Gallaphosphene for Ga−P−Ga Heteroallyl Cation Generation, CO2 Storage, and C(sp3)−H Bond Activation” Angew. Chem. Int. Ed., 2021, 60, 6784–6790. [Highlighted as Hot Paper] (IF = 16.6)
Sharma, M. K.; Ebeler, F.; Glodde, T.; Neumann, B.; Stammler, H.‐G.; Ghadwal, R. S. “Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting” J. Am. Chem. Soc., 2021, 143, 121−125. (IF = 16.6)
Sharma, M. K.; Rottschäfer, D.; Glodde, T.; Neumann, B.; Stammler, H.‐G.; Ghadwal, R. S. “An Open‐Shell Singlet SnI Diradical and H2 Splitting” Angew. Chem. Int. Ed., 2021, 60, 6414–6418. [Highlighted as Hot Paper] (IF = 16.6)
Sharma, M. K.; Rottschäfer, D.; Neumann, B.; Stammler, H.‐G.; Danés, S.; Andrada, D. M.; Gastel, van M.; Hinz, A.; Ghadwal, R. S. “Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands” Chem. Eur. J., 2021, 27, 5803–5809. (IF = 4.3)
Sharma, M. K.; Glodde, T.; Neumann, B.; Stammler, H.-G.; Ghadwal R. S. “Distannabarrelenes with three Coordinated Sn(II) atoms” Chem. Eur. J., 2020, 26, 11113–11118. [Highlighted as Hot Paper] (IF = 4.3)
Sharma, M. K.; Blomeyer, S.; Neumann, B.; Stammler, Gastel, van, M.; Hinz, A.; Ghadwal R. S. “Isolation of Singlet Carbene Derived 2-Arsa-1,3-butadiene Radical Cations and Dications” Chem. Commun., 2020, 56, 3575‒3578. (IF = 4.9)
Sharma, M. K.; Blomeyer, S.; Glodde, T.; Neumann, B.; Stammler, H.-G.; Gastel, van, M.; Hinz, A.; Ghadwal R. S. “Isolation of Singlet Carbenes Derived 2-Phospha-1,3-butadienes and their Sequential One-electron Oxidation to Radical Cations and Dications” Chem. Sci., 2020, 11, 1975‒1984. (IF = 8.4)
Mahawar, P.;ϯ Wasson, M.K.;ϯ Sharma, M. K.; Jha, C. K.; Mukherjee, G.; Vivekanandan, P.; Nagendran, S. “A Prelude to Biogermylene Chemistry” Angew. Chem., Int. Ed., 2020, 59, 21377–21381. (IF = 16.6)
Sharma, M. K.; Neumann, B.; Stammler, H.-G.; Andrada, D. M.; Ghadwal R. S. “Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom” Chem. Commun., 2019, 55, 14669‒14672. (IF = 4.9)
Sharma, M. K.; Blomeyer, S.; Neumann, B.; Stammler, H.-G.; Gastel, van, M.; Hinz, A.; Ghadwal R. S. “Crystalline Divinyldiarsene Radical Cations and Dications” Angew. Chem., Int. Ed., 2019, 58, 17599‒17603. (IF = 16.6)
Sharma, M. K.; Rottschäfer, D.; Blomeyer, S.; Neumann, B.; Stammler, H.-G.; Gastel, van, M.; Hinz, A.; Ghadwal R. S. “Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework” Chem. Commun., 2019, 55, 10408‒10411. (IF = 4.9)
Rottschäfer, D.; Sharma, M. K.; Neumann, B.; Stammler, H.-G.; Andrada, D. M.; Ghadwal R. S. “A Modular Access to Divinyldiphosphenes with a Strikingly Small HOMO-LUMO Energy Gap” Chem. Eur. J., 2019, 25, 8127‒8134. (IF = 4.3)
Sharma, M. K.; Blomeyer, S.; Neumann, B.; Stammler, H.-G.; Ghadwal R. S. “Crystalline Divinyldiarsenes and Cleavage of the As=As Bond” Chem. Eur. J., 2019, 25, 8249‒8253. (IF = 4.3)
Sinhababu, S.;ϯ Sharma, M. K.;ϯ Mahawar, P.; Kaur, S.; Singh, V. K.; Paliwal, A.; Yadav, D.; Kashyap, H. K.; Nagendran, S. “Germylene Stabilized Group 12 Metal Complexes and their Reactivity with Chalcogens” Dalton Trans., 2019, 48, 16366‒16376. (ϯ = contributed equally) (IF = 4.0)
Sharma, M. K.; Sinhababu, S.; Mahawar, P.; Mukherjee, G.; Pandey, B.; Rajaraman, G.; Nagendran, S. “Donor–acceptor-stabilized germanium analogs of acid chloride, ester, and acyl pyrrole compounds: synthesis and reactivity” Chem. Sci., 2019, 10, 4402‒4411. [Highlighted on the back cover of the issue] (IF = 8.4)
Sinhababu, S.; Singh, D.; Sharma, M. K.; Siwatch R. K.; Nagendran, S. “Ge(II) cation catalyzed hydroboration of aldehydes and ketones” Dalton Trans., 2019, 48, 4094‒4100. (IF = 4.0)
Yadav, D.; Singh, D.; Sarkar D., Sinhababu, S.; Sharma, M. K.; Nagendran, S. “Reactivity studies on aminotroponiminatogermylene stabilized Ruthenium(II) complexes” J. Organomet. Chem., 2019, 888, 37‒43. (IF = 2.3)
Sharma, M. K.; Ansari, M.; Mahawar, P.; Rajaraman, G.; Nagendran, S. “Expanding the limits of catalysts with low-valent main-group elements for the hydroboration of aldehydes and ketones using [L†Sn(II)][OTf] (L† = aminotroponate; OTf = triflate)” Dalton Trans., 2019, 48, 664‒672. (IF = 4.0)
Sharma, M. K.; Sinhababu, S.; Yadav, D.; Mukherjee, G.; Rajaraman, G.; Nagendran, S. “Pseudohalogenogermylenes vs Halogenogermylenes: Difference in their Complexation Behaviour towards Group 6 Metal Carbonyls” Chem. Asian J., 2018, 13, 1357–1365. (IF = 4.1)
Sharma, M. K.; Singh, D.; Mahawar, P.; Yadav, R.; Nagendran, S. “Catalytic Cyanosilylation Using Germylene Stabilized Platinum(II) Dicyanide” Dalton Trans., 2018, 47, 5943‒5947. (IF = 4.0)
Sharma, M. K.; Sinhababu, S.; Mukherjee, G.; Rajaraman, G.; Nagendran, S. “A cationic aluminium complex: an efficient mononuclear main-group catalyst for the cyanosilylation of carbonyl compounds” Dalton Trans., 2017, 46, 7672‒7676. (IF = 4.0)
Sinhababu, S.; Yadav, D.; Karwasara, S.; Sharma, M. K.; Mukherjee, G.; Rajaraman, G.; Nagendran, S. “The Preparation of Complexes of Germanone from a Germanium μ-Oxo Dimer” Angew. Chem., Int. Ed., 2016, 55, 7742-7746. (IF = 16.6)
Siwatch, R, K.; Karwasara, S.; Sharma, M. K.; Mondal, S. G.; Mukherjee, G.; Rajaraman, G.; Nagendran, S. “Reactivity of LGe–NR2 and LGe(E)–NR2 over LGe–Cl and LGe(E)–Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN)” Organometallics, 2016, 35, 429–438. (IF = 2.8)
Dalal, A.; Kamboj, R. C.; Kumar, D.; Sharma, M. K.; Nagendran S. Acta Cryst. E: Cryst. Commun., 2015, 71, o556-o557. (IF = 0.4)
Karwasara, S.; Sharma, M. K.; Tripathi, R.; Nagendran, S. “Synthesis and Reactivity of N-Aminotroponiminatogermylenepyrrole and Its Derivatives” Organometallics, 2013, 32, 3830‒3836. (IF = 2.8)