Embedded Files
[12] Reassessing Undergraduate Polymer Chemistry Laboratory Experiments for Virtual Learning Environments
[12] Reassessing Undergraduate Polymer Chemistry Laboratory Experiments for Virtual Learning Environments
M. Karayilan,* Sam McDonald, Alex Bahnick, Kacey Godwin, Yin Mei Chan, and Matthew L. Becker, Journal of Chemical Education, 2022, 99, 5, 1877-1889.
(* indicates the corresponding author)
https://pubs.acs.org/doi/abs/10.1021/acs.jchemed.1c01259 | PDF
From benchtop to desktop: Adapting chemistry laboratory experiments to virtual learning environments.
[11] Zooming in on Polymer Chemistry and Designing Synthesis of High Sulfur-Content Polymers for Virtual Undergraduate Laboratory Experiment
[11] Zooming in on Polymer Chemistry and Designing Synthesis of High Sulfur-Content Polymers for Virtual Undergraduate Laboratory Experiment
M. Karayilan,* Jafer Vakil, Daniel Fowler, Matthew L. Becker, and Charlie T. Cox, Journal of Chemical Education, 2021, 98, 6, 2062–2073.
(* indicates the corresponding author)
[10] Polymeric Materials for Eye Surface and Intraocular Applications
[10] Polymeric Materials for Eye Surface and Intraocular Applications
M. Karayilan, L. Claimen, and Matthew L. Becker, Biomacromolecules, 2021.
[9] Enhancing the Hydrogen Evolution Reaction in Neutral Water with Protic Buffer Electrolytes
[9] Enhancing the Hydrogen Evolution Reaction in Neutral Water with Protic Buffer Electrolytes
K. E. Clary, M. Karayilan, K. C. McCleary-Petersen, H. Petersen, R. S. Glass, J. Pyun, and D. L. Lichtenberger, PNAS, 2020.
[8] Influence of Processing Environment on the Surface Composition and Electronic Structure of Size-Quantized CdSe Quantum Dots
[8] Influence of Processing Environment on the Surface Composition and Electronic Structure of Size-Quantized CdSe Quantum Dots
R. C. Shallcross, A. L. Graham, M. Karayilan, N. G. Pavlopoulous, J. Meise, J. Pyun, and N. R. Armstrong J. Phys. Chem. C 2020
DOI: 10.1021/acs.jpcc.0c05622 | PDF
[7] Synthesis of Metallopolymers via Atom Transfer Radical Polymerization from a [2Fe‐2S] Metalloinitiator: Molecular Weight Effects on Electrocatalytic Hydrogen Production
[7] Synthesis of Metallopolymers via Atom Transfer Radical Polymerization from a [2Fe‐2S] Metalloinitiator: Molecular Weight Effects on Electrocatalytic Hydrogen Production
M. Karayilan, K. C. McCleary‐Petersen, M. O. Hamilton, L. Fu, K. Matyjaszewski, R. S. Glass, D. L. Lichtenberger, and J. Pyun, Macromol. Rapid Commun. 2020, 41, 1900424
Special Issue: 100 Years of Macromolecular Chemistry
DOI: 10.1002/marc.201900424
[6] Chalcogenide hybrid inorganic/organic polymer resins: Amine functional prepolymers from elemental sulfur
[6] Chalcogenide hybrid inorganic/organic polymer resins: Amine functional prepolymers from elemental sulfur
M. Karayilan, T.S. Kleine, K. J. Carothers, J. J. Griebel, K. M. Frederick, D. A. Loy, R. S. Glass, M. E. Mackay, K. Char, and J. Pyun, J. Polym. Sci. 2020 58, 35-41
Dedicated to Professor Krzysztof Matyjaszewski on the occasion of his 70th birthday
Special Issue: Special Issue in Honor of Professor Krzysztof Matyjaszewski
“Turning waste products into plastics” by Arizona Sonora News Service
[5] Water-soluble and air-stable [2Fe-2S]-metallopolymers: A new class of electrocatalysts for H2 production via water splitting
[5] Water-soluble and air-stable [2Fe-2S]-metallopolymers: A new class of electrocatalysts for H2 production via water splitting
R. S. Glass, J. Pyun, D. L. Lichtenberger, W. P. Brezinski, M. Karayilan, K. E. Clary, and D. H. Evans, Phosphorus, Sulfur, and Silicon and the Related Elements 2019, 194 (7), 701-706
DOI: 10.1080/10426507.2019.1603705
[4] Catalytic Metallopolymers from [2Fe‐2S] Clusters: Artificial Metalloenzymes for Hydrogen Production
[4] Catalytic Metallopolymers from [2Fe‐2S] Clusters: Artificial Metalloenzymes for Hydrogen Production
M. Karayilan, W. P. Brezinski, K. E. Clary, D. L. Lichtenberger, R. S. Glass, J. Pyun, Angew. Chem. Int. Ed. 2019, 58, 7537.
[3] Nucleophilic Activation of Elemental Sulfur for Inverse Vulcanization and Dynamic Covalent Polymerizations
[3] Nucleophilic Activation of Elemental Sulfur for Inverse Vulcanization and Dynamic Covalent Polymerizations
Y. Zhang, N.G. Pavlopoulos, T.S. Kleine, M. Karayilan, R.S. Glass, K. Char, and J. Pyun, J. Polym. Sci. Part A: Polym. Chem. 2019 57, 7-12
One of the Top Downloaded Papers in 2018-2019
[2] Macromolecular Engineering of the Outer Coordination Sphere of [2Fe-2S] Metallopolymers to Enhance Catalytic Activity for Hydrogen Production
[2] Macromolecular Engineering of the Outer Coordination Sphere of [2Fe-2S] Metallopolymers to Enhance Catalytic Activity for Hydrogen Production
W. P. Brezinski, M. Karayilan, K. E. Clary, K. C. McCleary-Petersen, L. Fu, K. Matyjaszewski, D. H. Evans, D. L. Lichtenberger, R. S. Glass, and J. Pyun, ACS Macro Letters 2018 7 (11), 1383-1387
DOI: 10.1021/acsmacrolett.8b00765
[1] [FeFe]‐Hydrogenase Mimetic Metallopolymers with Enhanced Catalytic Activity for Hydrogen Production in Water
[1] [FeFe]‐Hydrogenase Mimetic Metallopolymers with Enhanced Catalytic Activity for Hydrogen Production in Water
W. P. Brezinski, M. Karayilan, K. E. Clary, S. Li, L. Fu, K. Matyjaszewski, D. H. Evans, R. S. Glass, D. L. Lichtenberger, J. Pyun, Angew. Chem. Int. Ed. 2018, 57, 11898 .
Dedicated to Professor E. J. Corey on the occasion of his 90th birthday
Patents, Patent Applications, and Invention Disclosures
Patents, Patent Applications, and Invention Disclosures
[5] Photopolymerized elastomers for all-in-one intraocular lens implants (2022)
[5] Photopolymerized elastomers for all-in-one intraocular lens implants (2022)
Becker, M. L.; Karayilan, M. | Duke University, Invention Disclosure - T-007846
[4] Biostable Polymer Brushes with Defined Viscosity and Optical Properties (2021)
[4] Biostable Polymer Brushes with Defined Viscosity and Optical Properties (2021)
Becker, M. L.; Karayilan, M. | 63/191,018
[3] Electrocatalytic Systems for the Generation of Molecular Hydrogen from Aqueous Feedstocks
[3] Electrocatalytic Systems for the Generation of Molecular Hydrogen from Aqueous Feedstocks
Pyun, J.; Glass, R. S.; Lichtenberger D. L.; Brezinski, W. P.; Clary, K. E.; Karayilan, M. | UA18-069 [Link]
[2] Enhanced Water Splitting with Protic Buffer/Electrolyte Cocatalysts (2019)
[2] Enhanced Water Splitting with Protic Buffer/Electrolyte Cocatalysts (2019)
Lichtenberger, D. L.; Pyun, J.; Glass, R. S.; Brezinski, W. P.; Clary, K. E.; Karayilan, M.; | US62/597,242 [Link]
[1] Metallopolymers for Catalytic Generation of Hydrogen (2019)
[1] Metallopolymers for Catalytic Generation of Hydrogen (2019)
Pyun, J.; Glass, R. S.; Lichtenberger D. L.; Brezinski, W. P.; Clary, K. E.; Karayilan, M. | US16/466,571 [Link]
Selected Presentations
Selected Presentations
[17] M. Karayilan, Virtual Symposium for Postdoctoral Fellows, Pennsylvania State University, Department of Chemistry (January 2022) (Invited).
[16] M. Karayilan, Virtual Postdoc Talk Competition in Polymer Research, Georgia Institute of Technology (November 2021) "Polymeric Materials with Defined Viscosity and Tunable Optical and Mechanical Properties for Intraocular Lens (IOL) Applications" (Invited). Link for the recorded presentation.
[15] M. Karayilan, K. McCleary-Petersen, R. Glass, D. Lichtenberger, J. Pyun, Virtual 24th Annual Green Chemistry & Engineering Conference (2020) "Biomimetic [2Fe-2S]-Metallopolymers for Enhanced Electrocatalytic Hydrogen Evolution from Aqueous Feedstock" Session: Leaving Organic Solvents Behind: Chemistry in Aqueous Media (oral presentation)
[14] M. Karayilan, University of California San Diego, Department of Chemistry (2019), San Diego, CA "[FeFe]-Hydrogenase Mimetic Metallopolymers: Artificial Enzymes for Hydrogen Generation from Water" (invited)
[13] B. Wimbish, K. McCleary-Petersen, M. Karayilan, J. Pyun, Annual Biomedical Research Conference for Minority Students (ABRCMS) (2019) Anaheim, CA "Biomimetic Metallopolymers Produced via Controlled Radical Polymerization for Electrocatalytic H2 Generation"
[12] M. Hamilton, J. Kiselka, M. Karayilan, R. Glass, J. Pyun, D. Lichtenberger, 258th ACS National Meeting & Exposition (2019) San Diego, CA "Electrochemical and computational investigation of aromatically bridged [2Fe-2S] clusters for electrocatalytic hydrogen production"
[11] K. Clary, M. Karayilan, R. Glass, J. Pyun, D. Lichtenberger, 258th ACS National Meeting & Exposition (2019) San Diego, CA "Synthetic [2Fe2S] Biomimietics in Metallopolymers as Hydrogen Evolution Electrocatalysts"
[10] M. Karayilan, W. Brezinski, K. Clary, K. McCleary-Petersen, D. Lichtenberger, R. Glass, J. Pyun, 257th ACS National Meeting & Exposition (2019) Orlando, FL "Macromolecular Engineering of Electrocatalytic Metallopolymers via ATRP: Artificial Enzymes for Water Splitting" (oral and poster presentations)
[9] J. Pyun, M. Karayilan, K. Clary, D. Lichtenberger, R. Glass, 257th ACS National Meeting & Exposition (2019) Orlando, FL "Artificial enzymes via ATRP from [2Fe-2S] metallopolymers for H2 production via water splitting"
[8] M. Karayilan, National Graduate Research Polymer Conference (2018) Minneapolis, MN "Metallopolymers with [FeFe]-Hydrogenase Active Site Mimetics via ATRP: Artificial Enzymes for Water Splitting" (oral presentation)
[7] W. Brezinski, M. Karayilan, K. Clary, K. Matyjaszewski, D. Evans, D. Lichtenberger, R. Glass, J. Pyun, 255th ACS National Meeting & Exposition (2018) New Orleans, LA "[Fe-Fe]-Hydrogenase Mimetic Metallopolymers: Water Solubility, Enhanced Rates, and Aerobic Stability in Hydrogen Evolution Catalysts via Polymer Support"
[6] M. Karayilan, W. Brezinski, D. Lichtenberger, R. Glass, J. Pyun, 255th ACS National Meeting & Exposition (2018) New Orleans, LA "Synthesis of [FeFe]-Hydrogenase Mimetic Metallopolymers via ATRP for Robust and O2 Resistant H2-Evolution Catalysts" (poster presentation)
[5] R. Glass, W. Brezinski, M. Karayilan, K. Clary, D. Lichtenberger, J. Pyun, 28th International Symposium on the Organic Chemistry of Sulfur, ISOCS-28 (2018) Tokyo Institute of Technology, Tokyo, Japan "Hydrogen Generation in Water with a [2Fe-2S] Metallocatalyst"
[4] M. Karayilan, Department of Chemistry and Biochemistry Seminar (2017) University of Arizona "Imitating and Improving Nature for Harvesting Green Energy: [2Fe-2S]-Based Metallopolymers" (oral presentation)
[3] W. Brezinski, M. Karayilan, D. Lichtenberger, R. Glass, J. Pyun, 254th ACS National Meeting & Exposition (2017) Washington, DC "[Fe-Fe]-Hydrogenase Mimetic Metallopolymers from ATRP with ong-lived Electrocatalytic Activity"
[2] M. Karayilan, C. Erkey, 247th ACS National Meeting & Exposition (2014) Dallas, TX "Investigations of Processing Parameters that Affect Transparency of Silica Aerogels for Thermal Insulation Systems" (oral presentation)
[1] M. Karayilan, C. Erkey, IUPAC 2013; 44th World Chemistry Congress (2013) Istanbul, Turkey "Effects of Sol-gel Parameters on Physical Properties of Silica Aerogels" (oral presentation)
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