Record the pH of the solution after the second addition of ethanoic acid
2. Use the pH of your solution to calculate [H+ ].
3. Calculate a value of Ka for ethanoic acid.
4. Compare this value to your researched data value.
Use logarithms in relation to quantities that range over several orders of magnitude.
Change the subject of an equation.
Substitute numerical values into algebraic equations using appropriate units for physical quantities.
CPAC 4b – Obtains accurate, precise and sufficient data for experimental and investigative procedures and records this methodically using appropriate units and conventions.
· Record information in a table’s or appropriately
· Titre value is recorded to 0.05cm3
· pH is recorded to 2dp's
· [H+] ions is calculated to at least 4 sig fig
· Ka is calculated to 3 sig fig
The ionisation of an acid is shown by:
HA(aq) ⇌ H+ (aq) + A– (aq)
Because there is an equilibrium set up, an equilibrium constant, Ka, can be written: Ka = – + [H ][A ] / [HA]
The Ka value is an indication of acid strength. The larger the value of the Ka, the stronger the acid.
The Ka of a weak acid can be measured by titrating a known volume of the acid against sodium hydroxide using phenolphthalein as an indicator. A further equal volume of acid is then added, and the pH of the resulting solution is measured. Because effectively half of the acid has been titrated:
[H+ ] = [HA] = [A– ]
[A– ] and [HA] can be cancelled in the Ka expression
And so Ka = [H+ ]
The pH value of the combined solutions can be converted to [H+ ] to give a Ka value
CPAC 5b – Sources of information are cited demonstrating that research has taken place, supporting planning and conclusions
· Clearly identifies any material that is a direct quote as such.
· Use research to discuss how their results compare to published data:
· Use research to support any conclusions drawn
· Compiles a bibliography of texts from which material has been sourced in such a way that the reader may retrieve the information easily.
5. What are some of the sources of uncertainty in this experiment?
6. What can you do to overcome them?
1. Folic acid behaves as a weak acid – it can be represented as HA. Write the equation for the ionisation of a weak acid HA in water. Write the terms conjugate acid and conjugate base under the relevant formulae for an acid–base pair in your equation. (2)
2.
(a) Write the expression for the acidity constant Ka for the ionisation of folic acid. (1)
(b) If Ka = 5.0 x 10−3 mol dm−3 , calculate pKa. (1)
(c) Calculate the pH of a 0.10 mol dm−3 solution of this acid. (2)
Consult CLEAPSS Hazcards®38A,91A, 32. Perform a risk assessment using up-to-date information before this practical is carried out