1. Copy the table from the analysis section & record your results.
CPAC 4b - Obtains accurate, precise and sufficient data for experimental and investigative procedures and records this methodically using appropriate units and conventions.
· Write down the exact burette value to 0.05cm3
· Time is recorded to the nearest second
· Data recorded includes units
· average time is recorded, to appropriate accuracy (for time, no more accurate than to a whole second due to human error issues)
2. Plot a graph of titre against time. (The titre is proportional to the concentration of iodine.)
3. Deduce the order of reaction with respect to iodine from the graph.
CPAC 5a - uses appropriate software and/or tools to process data, carry out research and report findings
Use excel to draw scatter graph (line of best fit drawn free-hand) to determine the order of reaction with respect to iodine
Carry out suitable research and writes up in own words citing relevant information, facts and figures within the text as necessary.
Research order with respect to propanone and hydrogen ions
Research potential mechanism to fit orders
CPAC 5b – Sources of information are cited demonstrating that research has taken place, supporting planning and conclusions
· Clearly identifies any material that is a direct quote as such.
· Use research to explain & support any conclusions drawn
· Compile a bibliography of texts from which material has been sourced in such a way that the reader may retrieve the information easily
Similar experiments show that the reaction is first order with respect to both propanone and to hydrogen ions. Use this information to answer the following questions.
1. What is the effect on the rate if the concentration of the hydrogen ions is doubled?
2. What is the effect on the rate if the concentration of the propanone is doubled?
3. What is the effect on the rate if the concentration of the iodine is doubled?
4. Write the overall rate expression for this reaction.
5. Two students monitored the concentration of propanone as the reaction proceeded and plotted a concentration–time graph from their results. What shape would you expect the graph to be? How would you use this graph to prove that the reaction is first order with respect to propanone?
Calculate a rate of change from a graph showing a linear relationship
The reaction between propanone and iodine in aqueous solution can be catalysed by an acid:
I2(aq) + CH3COCH3(aq) + H+ (aq) → CH3COCH2I(aq) + 2H+ (aq) + I− (aq)
The influence of the iodine on the reaction rate can be studied if the concentrations of propanone and hydrogen ions effectively remain constant during the reaction. This is achieved by using a large excess of both propanone and sulfuric acid in the starting reaction mixture.
Consult CLEAPSS Hazcards® 54, 85A,95A,98A. Perform a risk assessment using up-to-date information before this practical is carried out