Publications
S. Y. Kim, H. N. Lim,* "Methyl Pyruvate Oxime as a Carbonyl Synthon: Synthesis of Ureas, Carbamates, Thiocarbamates, and Anilides" Org. Lett. 2024, 26, 3850-3854.
S. E. Lee, Y. Kim, Y. H. Lee,* H. N. Lim,* "C-C Bond Cleavage-Induced C- to N-Acyl Transfer for Synthesis of Amides" Org. Lett. 2024, 26, 3646-3651.
J. M. Bak, M. Song, I. Shin,* H. N. Lim,* "A deconstruction–reconstruction strategy to access 1-naphthol derivatives: application to the synthesis of aristolactam scaffolds" Org. Biomol. Chem. 2023, 21, 8936-8941.
C. Y. Lee, S. E. Lee, H.N. Lim,* "A Strategic Synthesis of Fluoroethers via Ring-Opening Fluorinative Beckmann Fragmentation" Org. Lett. 2023, 25, 6534-6538.
W. P. Hong, H. N. Lim,* I. Shin,* "Recent progress and perspectives in photo-induced organic reactions of acylsilanes" Org. Chem. Front. 2023, 10, 819-836.
S. Kim, S. Y. Lim, K. Kwak, H. N. Lim*, H.-S. Yeom* "One-Pot Synthesis of 2-Sulfonamidobenzo[b]thiophenes Enabled by a Mild Protonative Activation of Ynamides" Synthesis 2022, 54, 5451-5460. *Collected in Organic Chemistry Portal for synthesis of benzothiophenes
I. Shin, H. N. Lim*, W. P. Hong* "1,4-Azaborines: Origin, Modern Synthesis, and Applications as Optoelectronic Materials" Synthesis 2022, 54, 570-588. *Invited contribution
S. J. Hong, C. J. Yoon, H. N. Lim,* H.-S. Yeom* "Step-Economical Route to 2-Amido-3-bromobenzo[b]thiophenes via Ynamide Formation and Selectfluor-Mediated Oxidative Bromocyclization" Eur. J. Org. Chem. 2021, 5609-5617.
J. W. Song, H. N. Lim* "Synthesis of Carbamoyl Fluorides via a Selective Fluorinative Beckmann Fragmentation" Org. Lett. 2021, 23, 5394-5399.
D. Kim, H. N. Lim* “An Expedient Synthesis of Cyanoformates via DAST-mediated C‒C Bond Cleavage of α-Oximino-β-ketoesters” Tetrahedron Lett. 2021, 24, 153116. *Special issue in honor of Prof. Guangbin Dong for the 2021 Tetrahedron Young Investigator Award in Organic Synthesis
*Highlighted in Synfacts 2021, 17, 0990.
J.-S. Kim*, B. G. Kim, I. Y. Lee, H. N. Lim “Simple Screening of Cellulose Biosynthesis Inhibitors through Response Patterns of Seedling of Specific Seeds” Weed Turf. Sci. 2020, 9, 331-343. (link)
W. P. Hong, I. Shin*, H. N. Lim* “Recent Advances in One-Pot Modular Synthesis of 2-Quinolones” Molecules 2020, 25, 5450.
D. Kim, H. N. Lim* “Synthesis of Acyl Fluorides via DAST-Mediated Fluorinative C–C Bond Cleavage of Activated Ketones”, Org. Lett. 2020, 22, 7465-7469. *Selected as ACS Editors’ Choice Article. *Recommended in Faculty Opinions *Collected in Organic Chemistry Portal *Most read in last 12 months (2021)
A. R. Kim, H. N. Lim* “One-pot copper-catalyzed three-component reaction: a modular approach to functionalized 2-quinolones”, RSC Advances 2020, 10, 7855-7866.
H. N. Lim, D. Xing, G. Dong “Transition-Metal-Catalyzed Ketone α-Alkylation and Alkenylation with Simple Alkenes and Alkynes via a Dual Activation Strategy”, Synlett 2019, 30, 674-685.
B. H. Ahn, I. Y. Lee, H. N. Lim* “Step-economical synthesis of 3-amido-2-quinolones by dendritic copper powder-mediated one-pot reaction”, Org. Biomol. Chem. 2018, 16, 7851-7860.
S. -H. Lee, H. N. Lim et al. “Mosquitocidal activity of penfluridol as juvenile hormone antagonist”, J. Asia Pac. Entomol. 2018, 21, 130-133. (link)
Z.-Q. Rong, H. N. Lim, G. Dong “Intramolecular Acetyl Transfer to Olefins via Catalytic C-C Bond Activation of Unstrained Ketones”, Angew. Chem. Int. Ed. 2018, 57, 475-479.
Prior to Independent
H. N. Lim, G. Dong “Catalytic Cage Formation via Controlled Dimerization of Norbornadienes: An Entry to Functionalized HCTDs (Hepta-cyclo[6.6.0.02,6.03,13.04,11.05,9. 010,14]tetradecanes)”, Org. Lett. 2016, 18, 1104-1107.
F. Mo, H. N. Lim, G. Dong “Bi-functional Ligand-assisted Catalytic Ketone α-Alkenylation with Internal Alkynes: Controlled Synthesis of Enones and Mechanistic Studies”, J. Am. Chem. Soc. 2015, 137, 15518−15527.
H. N. Lim, G. Dong “Catalytic Intramolecular Ketone Alkylation with Olefins via Dual Activation”, Angew. Chem. Int. Ed. 2015, 54, 15294-15298.
Z. Huang, H. N. Lim, F. Mo, M. C. Young, G. Dong "Transition Metal Catalyzed Ketone-Directed or Mediated C−H Functionalization". Chem. Soc. Rev. 2015, 44, 7764-7786.
K. A. Parker, H. N. Lim Strategies and Tactics in Organic Synthesis, 2014, 51-78. “Chapter 3 - The Mysterious Case of the Kingianins”
H. N. Lim, K. A. Parker “Intermolecular Radical Cation Diels-Alder (RCDA) Reaction of Bicyclooctadienes: Biomimetic Formal Total Synthesis of Kingianin A and Total Syntheses of Kingianins D, F, H, and J”, J. Org. Chem. 2014, 79, 919-926. *Highlighted by Organic Chemistry Portal; Org. Chem. Highlights, 2014, Dec. 22
H. N. Lim, K. A. Parker “Total Synthesis of Kingianin A”, Org. Lett. 2013, 15, 398-401. *Highlighted by Nature Chemical Biology (Research Highlight), 2013, 9, 138. *Highlighted by Organic Letters. JOC. JACS virtual issue on “Terpenoid- and Shikimate-Derived Natural Products Total Synthesis.” Org. Lett. 2013, 15, 3181-3198. *Highlighted by Synfacts, 2013, 9, 356.
H. N. Lim, K. A. Parker “Total Synthesis of the Potent Androgen Receptor Antagonist (−)-Arabilin: A Strategic, Biomimetic [1,7]-Hydrogen Shift”, J. Am. Chem. Soc. 2011, 133, 20149-20151.; correction J. Am. Chem. Soc. 2012, 134, 4449. *Highlighted by Synfacts, 2012, 8, 242.
Y.-G. Kim, H. N. Lim, K.-J. Lee “A New Route to Allyl Thiols and Allyl Thiocarbamates from Baylis-Hillman Adducts”, J. Heterocycl. Chem. 2009, 46, 23-27.
S.-H. Ahn, H. N. Lim, K.-J. Lee, “Application of the Acetate of Baylis-Hillman Adducts of Salicylalde-hydes in the Synthesis of Methyl 2-Oxo-2,3-dihydrobenzo[b]oxepine-4-carboxylates”, J. Heterocycl. Chem. 2008, 45, 1701-1706.
H. N. Lim, Y. S. Song, K.-J. Lee “Synthesis of Methyl 2-Amino-3H-1-benzaepine-4-carboxylates and 2-(Cyanomethyl)-2,3-dihydro-1H-indole-2-carboxylates from Morita-Baylis-Hillman Acetates of 2-(Acyl-amino)benzaldehydes”, Synthesis 2007, 3376-3384.
H. N. Lim, S.-H. Ji, K.-J Lee “Synthesis of 2-(9-Fluorenyl)acrylic Acid Derivatives via Intramolecular Friedel-Crafts Reaction of Morita-Baylis-Hillman Adducts of 2-Biphenylcarboxaldehydes”, Synthesis, 2007, 2454-2460.
W. P. Hong, H. N. Lim, H. W. Park, K.-J. Lee “Synthesis of Methyl (E)-2-Cyanomethyl-cinnamates Derived from Baylis-Hillman Acetates and Conversion into Several 4-Hydroxy-2-naphthoic Acids and Benzylidenesuccinimides”, Bull. Korean Chem. Soc. 2005, 26, 655-657.
Patents
이속사졸린 고리를 포함하는 피리딘계 화합물 및 제초제로서의 이의 용도 KR 10-2014320
펜플루리돌을 함유하는 살충제 조성물 KR 10-1860377
Pyridine-based compound including isoxazoline ring and use thereof as herbicide US patent