Research Area
(1) Colloidal Stability & Interactions
(2) Anisotropic Nanoparticles & Liquid Crystals
(3) Microstructure-Property Relations
(4) Advanced Rheological Analysis
(1) Colloidal Stability & Interactions
Colloidal suspensions contain nano- and micro- particles dispersed in liquid, and their stable dispersion is essential for ensuring material performance. We study how surface charge, polymer additives, colloidal size, and medium conditions influence colloidal interactions. This allows us to control structure, stability, and processing behavior in nano-soft materials.
[Shim et al. Materials Horizons 2017 (link) ]
"Wide concentration liquid crystallinity of graphene oxide aqueous suspension with interacting polymers"
[Cho et al. ACS Appl. Mater. Interfaces 2024 (link)]
"Is low polydispersity always beneficial? exploring the impact of size polydispersity on the microstructure and rheological properties of graphene oxide"
(2) Anisotropic Nanoparticles & Liquid Crystals
Rod- and plate-like nanoparticles can spontaneously align and organize into liquid crystal structures. We investigate how these alignments are affected by concentration, interactions, and shear flow. This helps us design materials with alignment-dependent properties, like films and fibers.
[Shim et al. ACS Nano 2018 (link)]
"Tailored colloidal stability and rheological properties of graphene oxide liquid crystals with polymer-induced depletion attractions"
[Shim et al. Carbon 2023 (link)]
"Unifying dispersion properties of graphene oxide suspension via interlayer spacing control: insights for universal 2D colloid behavior"
(3) Microstructure-Property Relations
The mechanical, optical, and rheological properties of soft materials depend strongly on their structure. We analyze microstructures from the nano to macro scale to understand how they influence material behavior. These insights help us design functional materials for flexible, responsive, or high-performance applications.
[Shim et al. ACS Nano 2021 (link)]
"Universal alignment of graphene oxide in suspensions and fibers"
[Shim et al. Carbon 2023 (link) ]
"Continuous structural deformation of graphene oxide liquid crystal colloids under shear for hydrogel films"
[Shim et al. ACS Appl. Mater. Interfaces 2025 (link) ]
"Reversible control of rheological properties in microgel composites via nanoparticle aggregation"
(4) Advanced Rheological Analysis
Soft materials exhibit complex behaviors under stress, including yielding, strain softening/stiffening, and recovery. We use both linear and nonlinear rheological techniques to fully characterize these responses. In particular, nonlinear rheology provides crucial insights for processes involving shear forces (fiber spinning, inkjet/screen printing, and 3D printing), offering effective guidelines for material design and processing.
[Shim et al. Phys. Fluids 2023 (link)]
"Understanding the yielding behavior of graphene oxide colloids via experimental strain decomposition"
[Shim et al. J. Rheol. 2023 (link)]
"Unified interpretation of MAOS responses via experimentally decomposed material functions"
[Shim et al. J. Rheol. 2024 (link)]
"A reexamination of the Cox-Merz rule through the lens of recovery rheology"