for i, row in df.iterrows():
df.at[i, '<HeaderName>'] = "<ValuesToPrint>"
#Using with conditional statement
for i in df.index:
df.at[i, '<HeaderName>'] = x if <something> else y
df = pd.DataFrame(np.random.uniform(50,100,size=(100, 2)), columns=list('AB'))
df = pd.DataFrame(np.random.normal(50,100,size=(100, 2)), columns=list('AB'))
df = pd.DataFrame(np.random.randint(50,100,size=(100, 2)), columns=list('AB'))