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Independent Career
Independent Career
UV–Vis–NIR Magnetic Linear Dichroism: A Powerful Complement to MCD for f-Block Electronic Structure
UV–Vis–NIR Magnetic Linear Dichroism: A Powerful Complement to MCD for f-Block Electronic Structure
Sydney M. Giles, Kevin O'Neil, Ian E. Ramsier, Gina Angelo, Xin Gui, Wesley J. Transue*
Chem. Sci. 2025, ASAP
DOI 10.1039/D5SC05890B
Molecular Design for Optically Induced Magnetization: Targeting Excited State Orbital Degeneracy in Tungsten(V) Complexes
Molecular Design for Optically Induced Magnetization: Targeting Excited State Orbital Degeneracy in Tungsten(V) Complexes
Ian E. Ramsier, Alysia Mandato, Sunil Saxena, Wesley J. Transue*
J. Am. Chem. Soc. 2025, 147 (22), 18424–18430
DOI 10.1021/jacs.5c03783
Prior Works
Prior Works
Kβ X-ray Emission Spectroscopy of Cu(I)-Lytic Polysaccharide Monooxygenase: Direct Observation of the Frontier Molecular Orbital for H2O2 Activation
Kβ X-ray Emission Spectroscopy of Cu(I)-Lytic Polysaccharide Monooxygenase: Direct Observation of the Frontier Molecular Orbital for H2O2 Activation
Hyeongtaek Lim, Magdalene T. Brueggemeyer, Wesley J. Transue, Katlyn K. Meier, Stephen M. Jones, Thomas Kroll, Dimosthenis Sokaras, Bradley Kelemen, Britt Hedman, Keith O. Hodgson, Edward I. Solomon*
J. Am. Chem. Soc. 2023, 145 (29), 16015–16025
DOI 10.1021/jacs.3c04048
Fenton-like Chemistry by a Copper(I) Complex and H2O2 Relevant to Enzyme Peroxygenase C–H Hydroxylation
Fenton-like Chemistry by a Copper(I) Complex and H2O2 Relevant to Enzyme Peroxygenase C–H Hydroxylation
Bohee Kim, Magdalene T. Brueggemeyer, Wesley J. Transue, Younwoo Park, Maxime A. Siegler, Edward I. Solomon, Kenneth D. Karlin*
J. Am. Chem. Soc. 2023, 145 (21), 11735 11744
DOI 10.1021/jacs.3c02273
Particle Swarm Fitting of Spin Hamiltonians: Magnetic Circular Dichroism of Reduced and NO-bound Flavodiiron Protein
Particle Swarm Fitting of Spin Hamiltonians: Magnetic Circular Dichroism of Reduced and NO-bound Flavodiiron Protein
Wesley J. Transue, Rae Ana Snyder, Jonathan D. Caranto, Donald M. Kurtz Jr., Edward I. Solomon*
Inorg. Chem. 2022, 61 (42), 16520–16527
DOI 10.1021/acs.inorgchem.2c02234
The three-spin intermediate at the O–O cleavage and proton-pumping junction in heme–Cu oxidases
The three-spin intermediate at the O–O cleavage and proton-pumping junction in heme–Cu oxidases
Anex Jose, Andrew W. Schaefer, Antonio C. Roveda Jr., Wesley J. Transue, Wesley J. Transue, Sylvia K. Choi, Ziqiao Ding, Robert B. Gennis, Edward I. Solomon*
Science 2021, 373 (6560), 1225–1229
DOI 10.1126/science.abh3209
31P NMR Chemical Shift Tensors: Windows into Ruthenium Phosphinidene Complex Electronic Structures
31P NMR Chemical Shift Tensors: Windows into Ruthenium Phosphinidene Complex Electronic Structures
Wesley J. Transue, Yizhe Dai, Martin-Louis Y. Riu, Gang Wu, Christopher C. Cummins*
Inorg. Chem. 2021, 60 (13), 9254–9258
DOI 10.1021/acs.inorgchem.1c01099
An Azophosphine Synthetic Equivalent of Mesitylphosphaazide and Its 1,3-Dipolar Cycloaddition Reactions
An Azophosphine Synthetic Equivalent of Mesitylphosphaazide and Its 1,3-Dipolar Cycloaddition Reactions
Martin-Louis Y. Riu, Wesley J. Transue, Jan M. Rall, Christopher C. Cummins*
J. Am. Chem. Soc. 2021, 143 (20), 7635–7640
DOI 10.1021/jacs.1c03333
A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity
A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity
Mayukh Bhadra, Wesley J. Transue, Hyeongtaek Lim, Ryan E. Cowley, Jung Yoon C. Lee, Maxime A. Siegler, Patrick Josephs, Gerald Henkel, Markus Lerch, Siegfried Schindler, Adam Neuba, Keith O. Hodgson, Britt Hedman, Edward I. Solomon*, Kenneth D. Karlin*
J. Am. Chem. Soc. 2021, 143 (10), 3707–3713
DOI 10.1021/jacs.1c00260
Synthesis of an Anthracene-Based Macrocyclic Diphosphine Ligand
Synthesis of an Anthracene-Based Macrocyclic Diphosphine Ligand
Martin-Louis Y. Riu, Wesley J. Transue, Ioana Knopf, Christopher C. Cummins*
Organometallics 2020, 39 (23), 4187–4190
DOI 10.1021/acs.organomet.0c00463
Kinetic Analysis of Amino Acid Radicals Formed in H2O2-Driven Cu(I) LPMO Reoxidation Implicate Dominant Homolytic Reactivity
Kinetic Analysis of Amino Acid Radicals Formed in H2O2-Driven Cu(I) LPMO Reoxidation Implicate Dominant Homolytic Reactivity
Stephen M. Jones, Wesley J. Transue, Katlyn K. Meier, Bradley Kelemen, Edward I. Solomon*
Proc. Natl. Acad. Sci. USA 2020, 117 (22), 11916–11922
DOI 10.1073/pnas.1922499117
Isolation of an Elusive Phosphatetrahedrane
Isolation of an Elusive Phosphatetrahedrane
Martin-Louis Y. Riu, Rebecca L. Jones, Wesley J. Transue, Peter Müller, Christopher C. Cummins*
Science Adv. 2020, 6 (13), eaaz3168
DOI 10.1126/sciadv.aaz3168
Identification of Reactive Intermediates Relevant to Dimethylgermylene Group Transfer Reactions of an Anthracene-Based Precursor
Identification of Reactive Intermediates Relevant to Dimethylgermylene Group Transfer Reactions of an Anthracene-Based Precursor
Michael B. Geeson, Wesley J. Transue, Christopher C. Cummins*
Organometallics 2019, 38 (17), 3229–3232
DOI 10.1021/acs.organomet.9b00410
Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes
Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes
Michael B. Geeson, Wesley J. Transue, Christopher C. Cummins*
J. Am. Chem. Soc. 2019, 141 (34), 13336–13340
DOI 10.1021/jacs.9b07069
As–P vs P–P Insertion in AsP3: Kinetic Control of the Formation of [AsP3NO]+
As–P vs P–P Insertion in AsP3: Kinetic Control of the Formation of [AsP3NO]+
Tobias A. Engesser, Wesley J. Transue, Philippe Weis, Christopher C. Cummins, Ingo Krossing*
Eur. J. Inorg. Chem. 2019, 2019 (21), 2607–2612
DOI 10.1002/ejic.201900267
Orthophosphate and Sulfate Utilization for C–E (E = P, S) Bond Formation via Trichlorosilyl Phosphide and Sulfide Anions
Orthophosphate and Sulfate Utilization for C–E (E = P, S) Bond Formation via Trichlorosilyl Phosphide and Sulfide Anions
Michael B. Geeson, Pablo Ríos, Wesley J. Transue, Christopher C. Cummins*
Eur. J. Inorg. Chem. 2019, 2019 (21), 2607–2612
DOI 10.1002/ejic.201900267
Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus–Sulfur Material Having the Composition P2S, a Vulcanized Red Phosphorus That Is Yellow
Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus–Sulfur Material Having the Composition P2S, a Vulcanized Red Phosphorus That Is Yellow
Wesley J. Transue, Matthew Nava, Maxwell W. Terban, Jing Yang, Matthew W. Greenberg, Gang Wu, Elizabeth S. Foreman, Chantal L. Mustoe, Pierre Kennepohl, Jonathan S. Owen, Simon J. L. Billinge, Heather J. Kulik, Christopher C. Cummins*
J. Am. Chem. Soc. 2019, 141 (1), 431–440
DOI 10.1021/jacs.8b10775
Synthetic and Spectroscopic Investigations Enabled by Modular Synthesis of Molecular Phosphaalkyne Precursors
Synthetic and Spectroscopic Investigations Enabled by Modular Synthesis of Molecular Phosphaalkyne Precursors
Wesley J. Transue, Junyu Yang, Matthew Nava, Ivan V. Sergeyev, Timothy J. Barnum, Michael C. McCarthy, Christopher C. Cummins*
J. Am. Chem. Soc. 2018, 140 (51), 17985–17991
DOI 10.1021/jacs.8b09845
Magnetic-bottle and velocity-map imaging photoelectron spectroscopy of APS– (A = C14H10 or anthracene): Electronic structure, spin–orbit coupling of APS•, and dipole-bound state of APS–
Magnetic-bottle and velocity-map imaging photoelectron spectroscopy of APS– (A = C14H10 or anthracene): Electronic structure, spin–orbit coupling of APS•, and dipole-bound state of APS–
Qin-qin Yuan, Zheng Yang, Ren-zhong Li, Wesley J. Transue, Zhi-peng Li, Ling Jiang, Niranjan Govind, Christopher C. Cummins*, Xue-Bin Wang*
Chin. J. Chem. Phys. 2018, 31 (4), 463–470
DOI 10.1063/1674-0068/31/cjcp1805114
Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity
Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity
Maximilian Joost, Matthew Nava, Wesley J. Transue, Marie-Aline Martin-Drumel, Michael C. McCarthy, David Patterson, Christopher C. Cummins*
Proc. Natl. Acad. Sci. USA 2018, 115 (23), 5866–5871
DOI 10.1073/pnas.1804035115
Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent
Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent
Maximilian Joost, Wesley J. Transue, Christopher C. Cummins*
Chem. Sci. 2018, 9 (6), 1540–1543
DOI 10.1039/c7sc04506a
An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom
An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom
Maximilian Joost, Matthew Nava, Wesley J. Transue, Christopher C. Cummins*
Chem. Commun. 2017, 53 (83), 11500–11503
DOI 10.1039/c7cc06516g
Terminal tungsten pnictide complex formation through pnictaethynolate decarbonylation
Terminal tungsten pnictide complex formation through pnictaethynolate decarbonylation
Maximilian Joost, Wesley J. Transue, Christopher C. Cummins*
Chem. Commun. 2017, 53 (77), 10731–10733
DOI 10.1039/c7cc06841g
Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds
Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds
Wesley J. Transue, Alexandra Velian, Matthew Nava, Christopher C. Cummins*
J. Am. Chem. Soc. 2017, 139 (31), 10822–10831
DOI 10.1021/jacs.7b05464
Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX– (E = As, P, and N; X = S and O) Anions
Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX– (E = As, P, and N; X = S and O) Anions
Gao-Lei Hou, Bo Chen, Wesley J. Transue, Zheng Yang, Hansjörg Grützmacher, Matthias Driess, Christopher C. Cummins*, Weston Thatcher Borden*, Xue-Bin Wang*
J. Am. Chem. Soc. 2017, 139 (26), 8922–8930
DOI 10.1021/jacs.7b02984
Phosphinidene Reactivity of a Transient Vanadium P≡N Complex
Phosphinidene Reactivity of a Transient Vanadium P≡N Complex
Marc-André Courtemanche, Wesley J. Transue, Christopher C. Cummins*
J. Am. Chem. Soc. 2016, 138 (50), 16220–16223
DOI 10.1021/jacs.6b10545
A Joint Experimental and Computational Study of the Negative Ion Photoelectron Spectroscopy of the 1-Phospha-2,3,4-triazolate Anion, HCPN3–
A Joint Experimental and Computational Study of the Negative Ion Photoelectron Spectroscopy of the 1-Phospha-2,3,4-triazolate Anion, HCPN3–
Gao-Lei Hou, Bo Chen,* Wesley J. Transue, David A. Hrovat, Christopher C. Cummins,* Weston Thatcher Borden,* Xue-Bin Wang*
J. Phys. Chem. A 2016, 120 (31), 6228–6235
DOI 10.1021/acs.jpca.6b06343
Highly Fluorinated Ir(III)–2,2':2',2''-Terpyridine–Phenylpyridine–X Complexes via Selective C–F Activation: Robust Photocatalysts for Solar Fuel Generation and Photoredox Catalysis
Highly Fluorinated Ir(III)–2,2':2',2''-Terpyridine–Phenylpyridine–X Complexes via Selective C–F Activation: Robust Photocatalysts for Solar Fuel Generation and Photoredox Catalysis
Jonathan A. Porras, Isaac N. Mills, Wesley J. Transue, Stefan Bernhard*
J. Am. Chem. Soc. 2016, 138 (30), 9460–9472
DOI 10.1021/jacs.6b03246
A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion
A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion
Wesley J. Transue, Alexandra Velian, Matthew Nava, Marie-Aline Martin-Drumel, Caroline C. Womack, Jun Jiang, Gao-Lei Hou, Xue-Bin Wang, Michael C. McCarthy, Robert W. Field, Christopher C. Cummins*
J. Am. Chem. Soc. 2016, 138 (21), 6731–6734
DOI 10.1021/jacs.6b03910
Negative ion photoelectron spectroscopy of P2N3−: electron affinity and electronic structures of P2N3•
Negative ion photoelectron spectroscopy of P2N3−: electron affinity and electronic structures of P2N3•
Gao-Lei Hou, Bo Chen, Wesley J. Transue, David A. Hrovat, Christopher C. Cummins,* Weston Thatcher Borden,* Xue-Bin Wang*
Chem. Sci. 2016, 7 (7), 4667–4675
DOI 10.1039/c5sc04667j
Synthesis, Characterization, and Thermolysis of Dibenzo-7-dimethylgermanorbornadiene
Synthesis, Characterization, and Thermolysis of Dibenzo-7-dimethylgermanorbornadiene
Alexandra Velian, Wesley J. Transue, Christopher C. Cummins*
Organometallics 2015, 34 (19), 4644–4646
DOI 10.1021/acs.organomet.5b00529
[Ir(N^N^N)(C^N)L]+: A New Family of Luminophores Combining Tunability and Enhanced Photostability
[Ir(N^N^N)(C^N)L]+: A New Family of Luminophores Combining Tunability and Enhanced Photostability
Danielle N. Chirdon, Wesley J. Transue, Husain N. Kagalwala, Aman Kaur, Andrew B. Maurer, Tomislav Pintauer, Stefan Bernhard*
Inorg. Chem. 2014, 53 (3), 1487–1499
DOI 10.1021/ic402411g
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