Dr. Supriya Rej - Publications

40) EDA Complex-Enabled, Substituent-Controlled Switch in Anthranil Reactivity for Sequential Access to Azaaurones

Tiwari, K.; Singh, M.; Awasthi, A.; Rajpoot, R. S.; Rej, S., Tiwari, D. K. Chem. Commun. 2026, ASAP

https://doi.org/10.1039/D6CC04638J

39) Biochemical Investigation of PumG, a Key Pyridoxal 5′-Phosphate (PLP)-Dependent Aminotransferase Involved in Pseudouridimycin Biosynthesis

Henjarappa, K. P.; Ganguly, M.; Mukherjee, A.; Bhattoo, P.; Naik, Y.; Mhaske, K.; Giriraju, D.; Das, S.; Narayan, R.; Gholap, S. L.; Rej, S.; Jana, S.;* Mahanta, N.* ACS Chem. Biol. 2026, ASAP

https://doi.org/10.1021/acschembio.6c00500

38) Alkylboron and -Silicon Compounds

Semwal, K.; Rej, S.* 2026 (Book Chapter) published in "Comprehensive Organic Functional Group Transformations III (Third Edition)"

https://www.sciencedirect.com/science/chapter/referencework/abs/pii/B9780443314827001272?via%3Dihub

37) Direct Access to Sulfonamidated-1,4-Benzoquinones via Sul-fonamidation of Aryl Alcohol-Derived Quinone Monoacetals

Bangari, R.; Rajpoot, R. S.; Patel, A.; Mukherjee, A.; Rej, S.* Org. Lett., 2026, 28, 8970–8975.

https://doi.org/10.1021/acs.orglett.6c02392

36) Vinyl Silanes as Ethylene Surrogates for Arene Ethylation and Vinylation

Bangari, R.; Rej, S.* Synthesis, 2026, Just accepted.

(invited by Prof. A.T. Biju)

(as a highlight of our publication on Vinyl Silanes as Ethylene Surrogates: https://pubs.acs.org/doi/10.1021/acs.orglett.6c00144)

https://www.thieme-connect.de/products/ejournals/abstract/10.1055/a-2905-1035

35) Ru-catalyzed Additive-Controlled Spirocyclization/Alkenylation of Benzimidates with 1,4-Naphthaquinone

Mukherjee, A.; Semwal, K; Bangari, R.; Pandey, A.; Sahoo, S. K.; Rej, S. Org. Lett., 2026, 28, 6956–6961.

https://doi.org/10.1021/acs.orglett.6c01626

34) Vinylsilanes as Ethylene Surrogates: Rh(I)-Catalyzed Direct Hydroarylation of In Situ–Generated Ethylene

Bangari, R.; Mukherjee, A.; Rej, S.* Org. Lett., 2026, 28, 7065–7070.

https://pubs.acs.org/doi/10.1021/acs.orglett.6c00144

(featured on Journal's front cover: https://pubs.acs.org/toc/orlef7/28/23)

(highlighted in synfacts by Prof. Oestreich and co-workers: https://doi.org/10.1055/a-2870-9283)

33) Photochemical Skeletal Editing: Conceptual Advances in C–C and C–Heteroatom Bond Activation

Das, D.; Mukherjee, A.; Rej, S.* Green Chem., 2026, 28, 4409–4448.

https://pubs.rsc.org/en/Content/ArticleLanding/2026/GC/D5GC04607F

32) BX3-Mediated Arene Borylation: Concepts, Scope, and Mechanistic Insight (Invited Contribution)

Bangari, R.; Rajpoot, R. S.; Chatani, N.; Rej, S.* Chem. Asian J., 2026, 21, e00972.

https://aces.onlinelibrary.wiley.com/doi/10.1002/asia.202500972

31) Industrial and Flow Application of Directed C-H Bond Functionalization (Book Chapter)

Mukherjee, A.; Bangari, R.; Rej, S.* 2025, (Book Chapter). published in "Directed C‐H Bond Functionalization: Concepts and Applications".

https://onlinelibrary.wiley.com/doi/10.1002/9783527848485.ch14

30) Emerging metal-free directed C–H functionalization (Book Chapter)

Bangari, R.; Rej, S.* 2025, (Book Chapter). published in "Directed C‐H Bond Functionalization: Concepts and Applications"

https://onlinelibrary.wiley.com/doi/10.1002/9783527848485.ch10

--- Before joining IIT Dharwad ---

29) Photochemical C–H Borylation in Organic Synthesis

Rej, S.; Amos, S. G. E.; Kleij, A. ACS Catalysis, 2025,15, 1753–1770.

https://pubs.acs.org/doi/10.1021/acscatal.4c07169?articleRef=test

28) The [3]Dendralene Motif as an Entry into Nazarov Cyclizations by Silylium-Ion Initiation

Rej, S.; Klare, H. F. T.; Oestreich, M.* Org. Lett. 2023, 25, 426–431.

https://pubs.acs.org/doi/10.1021/acs.orglett.2c04166

27) Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by an Intramolecular Friedel‒Crafts Allylation

Rej, S.; Klare, H. F. T.; Oestreich, M.* Org. Lett. 2022, 24, 1346–1350.

https://pubs.acs.org/doi/abs/10.1021/acs.orglett.2c00011

26) Regio-Selective Transition-Metal-Free C(sp2)‒H Borylation: A Subject of Practical and Ongoing Interest in Synthetic Organic Chemistry

Rej, S.;* Chatani, N.* Angew. Chem. Int. Ed. 2022, 61, e202209539.

https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202209539

25) Origin of the Enhanced Reactivity in the ortho C–H Borylation of Benzaldehydes with BBr3

Yamazaki, K.; Rej, S.; Ano, Y.; Chatani, N.* Org. Lett., 2022, 24, 213–217.

https://pubs.acs.org/doi/abs/10.1021/acs.orglett.1c03829

24) Aluminium Complexes: Next-Generation Catalysts in Selective Hydroboration

Das, A.;* Rej, S.;* Panda, T. K.* Dalt. Trans. 2022, 51, 3027-3040.

https://pubs.rsc.org/en/Content/ArticleLanding/2022/DT/D1DT03703J

23) An Unusual Perpendicular Metallacycle Intermediate is the Origin of Branch Selectivity in the Rh (II)-Catalyzed C–H Alkylation of Aryl Sulfonamides with Vinylsilanes

Yamazaki, K.; Rej, S.; Ano, Y.; Chatani, N.* Organometallics, 2021, 40, 3935‒3942.

https://pubs.acs.org/doi/abs/10.1021/acs.organomet.1c00506

22). Pyrimidine-directed metal-free C–H borylation of 2-pyrimidylanilines: a useful process for tetra-coordinated triarylborane synthesis

Rej, S.; Das, A.; Chatani, N.* Chem. Sci., 2021, 12, 11447−11454.

https://pubs.rsc.org/en/content/articlelanding/2021/SC/D1SC02937A

21) Mechanism and Origins of Regiochemical Control in Rh(III)-Catalyzed Oxidative C-H Alkenylation and Coupling Sequence of Unprotected 1-Naphtylamines with α,β-Unsaturated Esters.

Yamazaki, K.; Rej, S.; Ano, Y.; Chatani, N.* Organometallics, 2021, 40, 1371-1378.

https://pubs.acs.org/doi/abs/10.1021/acs.organomet.1c00144

20) Effect of Sulfonamide and Carboxamide Ligands on the Structural Diversity of Bimetallic RhII −RhII Cores: Exploring the Catalytic Activity of These Newly Synthesized Rh2 Complexes.

Rej, S.; Chatani, N.* Inorg. Chem. 2021, 60, 3534−3538.

https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.1c00127

19) Transient Imine as a Directing Group for the Metal-free ortho-C-H Borylation of Benzaldehydes.

Rej, S.; Chatani, N.* J. Am. Chem. Soc., 2021, 143, 2920−2929.

https://pubs.acs.org/doi/abs/10.1021/jacs.0c13013

18) Overview of Regioselective and Stereoselective Catalytic Hydroboration of Alkynes

Rej, S.;* Das, A.;* Panda, T. K.* Adv. Synth. Catal. 2021, 363, 4818−4840.

https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.202100950

17) Strategic Evolution in Transition Metal-Catalyzed Directed C-H Bond Activation and Future Directions.

Rej, S.; Das, A.; Chatani, N.* Coord. Chem. Rev., 2020, 431, 213683.

https://www.sciencedirect.com/science/article/abs/pii/S0010854520307906

16) Rh(I)-Catalyzed Addition of the ortho C‒H Bond in Aryl Sulfonamides to Maleimides.

Ohara, N.; Rej, S.; Chatani, N.* Chem. Lett. 2020, 49, 1053‒1057.

https://www.journal.csj.jp/doi/full/10.1246/cl.200353

15) Rh(III)‐catalyzed Double Dehydrogenative Coupling of Free 1‐Naphthylamines with α,β‐Unsaturated Esters.

Rej, S.; Chatani, N.* Chem. Eur. J., 2020, 26, 11093‒11098.

https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202000706

Selected for Front species

14) Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds.

Rej, S.; Ano, Y.; Chatani, N.* Chem. Rev. 2020, 120, 1788‒1887.

https://pubs.acs.org/doi/abs/10.1021/acs.chemrev.9b00495

13) Rh(II)-catalyzed branch-selective C–H alkylation of aryl sulfonamides with vinylsilanes

Rej, S.; Chatani, N. Chem. Sci., 2020, 11, 389-395.

https://pubs.rsc.org/en/Content/ArticleLanding/2019/SC/C9SC04308J#!divAbstract

12) Rhodium(I)-Catalyzed Mono-Selective C-H Alkylation of Benzenesulfonamides with Terminal Alkenes

Rej, S.; Chatani, N. Chem. Commun., 2019, 55, 10503‒10506.

https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C9CC05219D#!divAbstract

Selected for front cover picture

11) Ruthenium(II)-Catalyzed Alkylation of C‒H Bonds in Aromatic Amides with Vinylsilanes

Wang, C.; Rej, S.; Chatani, N. Chem. Lett., 2019, 48, 1185‒1187.

https://www.journal.csj.jp/doi/full/10.1246/cl.190483

10) Rhodium-Catalyzed Alkylation of C‒H Bonds in Aromatic Amides with Unactivated 1-Alkenes and Styrenes: The Possible Generation of Carbene Intermediates from Alkenes

Yamaguchi, T.; Natsui, S.; Shibata, K.; Yamazaki, K.; Rej, S.; Ano, Y.; Chatani, N. Chem. Eur. J., 2019, 25, 6915‒6919.

https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201901300

9) Rh-Catalyzed Removable Directing Group Assisted sp2 or sp3-C-H Bond Functionalization.

Rej, S.; Chatani, N. Angew. Chem., Int. Ed., 2019, 58, 8304‒8329.

https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201808159

8) Rhodium(I)-Catalyzed C8-Alkylation of 1-Naphthylamide Derivatives with Alkenes through a Bidentate Picolinamide Chelation System

Rej, S.; Chatani, N. ACS Catal., 2018, 8, 6699‒6706.

https://pubs.acs.org/doi/10.1021/acscatal.8b01675

7) Organosilicon Reducing Reagents for Stereoselective Formations of Silyl Enol Ethers from α-Halo Carbonyl Compounds

Paramanik, S.; Rej, S.; Kando, S.; Tsurugi, H.; Mashima, K. J. Org. Chem., 2018, 83, 2409‒2417.

https://pubs.acs.org/doi/abs/10.1021/acs.joc.7b03005

6) Multiply-bonded dinuclear complexes of early-transition metals as minimum entities of metal cluster catalysts

Rej, S.; Tsurugi, H.; Mashima, K. Coordination chemistry reviews, 2018, 355, 223‒239.

https://www.sciencedirect.com/science/article/abs/pii/S0010854517303053

5) Dehalogenation of vicinal dihalo compounds by 1,1’-bis(trimethylsilyl)-1H,1’H-4,4’-bipyridinylidene for giving alkenes and alkynes in a salt-free manner

Rej, S.; Pramanik, S. Tsurugi, H.; Mashima, K. Chem. Commun., 2017, 53, 13157‒13160.

https://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C7CC07377A#!divAbstract

4) Mixed Ligated Tris(amidinate)dimolybdenum Complexes as Catalysts for Radical Addition of CCl4 to 1‑Hexene: Leaving Ligand Lability Controls Catalyst Activity.

Rej, S.; Majumder, M.; Kando, S.; Sugino, Y.; Tsurugi, H.; Mashima, K. Inorg. Chem. 2017, 56, 634-644.

https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b02525

3) Group 1 and group 2 metal complexes supported by bidentate bulky iminopyrrolyl ligand: synthesis, structural diversity, and ε-caprolactone polymerization study.

Kottalanka, R.K.; Harinath, A.; Rej, S.; Panda, T. K. Dalton Trans. 2015, 44, 19865-19879.

https://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT03222A#!divAbstract

2) Syntheses and solid state structures of zinc (II) complexes with Bi-dentate N-(Aryl)imino-acenapthenone (Ar-BIAO) ligands.

Anga, S.; Rej, S.; Naktode, K.; Pal, T.; Panda, T. K. J. Chem. Sci. 2015, 127, 103-113.

https://link.springer.com/article/10.1007/s12039-014-0756-z

1) Modelling of Transition State in Grignard Reaction of Rigid N-(Aryl)imino-Acenapthenone (Ar-BIAO): A Combined Experimental and Computational Study.

Anga, S.; Dasgupta, S.; Rej, S.; Mallik, B. S.; Panda, T. K. Australian J. Chem. 2014, 68, 931-938.

https://www.publish.csiro.au/CH/CH14399

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