The geometry of del Pezzo surface is full of wonderful and mysterious symmetries. Especially, we consider the correspondence between special divisor classes so called the lines of del Pezzo surface and the vertices of Gosset polytopes. Therefrom we can explain various mysterious symmetries. In this talk, we introduce special divisor classes according to the geometry of Gosset polytopes and explain the correspondences between these divisors and subpolytopes. Moreover, we apply the correspondence to study the configuration of lines of del Pezzo surfaces.