BCHCT-135

Volume I

Block 1: Solutions  

UNIT : 1 - Solutions-I  

"Types of Solutions; Different Modes of Expressing Concentration of Solution; Solutions of Solids in Liquids; Solutions of Gases in Liquids; Ideal Solutions, Raoult’s Law, Raoult’s Law curves, Thermodynamics of Ideal Solutions; Non-ideal Solutions, Raoult’s Law Curves; Vapour Pressure Variation with Liquid and Vapour Composition (for Ideal and Nonideal Solutions); Boiling Point Diagrams – Temperature - Composition Curves (for Ideal and Non-ideal Solutions), Distillation of Ideal Solutions, Lever Rule, Distillation of Solutions exhibiting Positive and Negative Deviations- Azeotropes. "

UNIT : 2 - Solutions-II  

Partially Miscible Liquid Systems, Critical Solution Temperatures, Effect of Impurity on Partial Miscibility of Liquids; Immiscible Liquid Pairs, Principle of Steam Distillation; Nernst Distribution Law and its Applications, Nernst Distribution Law ,Dissociation of A Solute in one of the Solvents, Association of a Solute in one of the Solvents, Solvent Extraction. 

Block 2 : Phase equilibrium  

UNIT : 3 - Phase Equilibrium-I 

Definition of the Terms; Phases, Components, Degrees of Freedom of a System; Criteria for Phase Equilibrium; Gibbs Phase Rule and its Thermodynamic Derivation; Derivation of Clausius-Clapeyron Equation and its Importance in Phase Equilibria. 

UNIT : 4 - Phase Equilibrium-II 

Application of Phase Rule to One Component Systems, Phase Diagram of Water, Phase Diagram of Sulphur; Application of Phase Rule to Two Component Systems, Phase Rule for Two Component Systems, Simple Eutectic System,(Pb-Ag system), System involving Congruent Melting Point, (FeCl3 -H2O system), System involving Incongruent Melting Point (Na-K system). 

Volume II

Block 3 : Conductance 

UNIT : 5 - Conductance-I 

Electrolytic Conductance; Molar Conductivity; Molar Conductance at Infinite Dilution, (Variation with Dilution for Strong and Weak Electrolytes); Molar Conductance for Strong electrolytes, Kohlrausch Law of Independent Migration of Ions. 

UNIT : 6 - Conductance-II  

Ionic Mobilities and Transference Number; Determination of Transference Number, Hittorf Method, Moving Boundary Method; Application of Conductivity Measurements, Determination of Degree of Ionisation of Weak Electrolytes, Determination of Solubility and Solubility Products of Sparingly Soluble Salts, Determination of Ionic Product of Water, Determination of Hydrolysis Constant of a Salt, Conductometric Titrations (Acid - base). 

Block 4 : Electrochemistry and Functional Group Organic Chemistry-II 

UNIT : 7 - Electrochemistry-I

Reversible and Irreversible Cells; Concept of EMF of a Cell, Experimental Measurement of EMF; Standard Electrode Potential, Electrochemical Series; Electrochemical Cell Representation and Cell Reaction; Types of electrodes, Metal-Metal Ion Electrodes, Gas Electrodes, Amalgam Electrode, Metal-Insoluble Salt Electrode, Membrane Electrode, Redox Electrode; Nernst Equation and its Importance; Thermodynamics of a Reversible Cell, Calculation of Thermodynamic Properties: G, H and S from EMF data; Calculation of Equilibrium Constant from EMF Data. 

UNIT : 8 - Electrochemistry-II

Types of Galvanic Cells, Chemical Cells and Concentration Cells ; Concentration Cells With Transference and Without Transference; Liquid Junction Potential and Salt Bridge; Applications of EMF Measurements, pH Determination, using Hydrogen Electrode, using Quinhydrone Electrode, Potentiometric Titrations-Qualitative treatment, (Acid-base and Oxidation-reductiononly); Electrolytic Cells, Faraday’s Law of Electrolysis; Applications of Electrolysis. 

UNIT : 9 - Carboxylic Acids 

Structure and Reactivity; Physical Properties; Preparation of Carboxylic Acids; Reactions of Carboxylic Acids, Conversion to Alkanoyl Halides, Esterification, Conversion to Amides, Hell-Vohlard-Zelinsky Reaction, Reduction, Decarboxylation. 

UNIT : 10 - Carboxylic Acid Derivatives 

Structure and Reactivity of Carboxylic Acid Derivatives; Physical Properties of Carboxylic Acid Derivatives; Carboxylic Acid Halides, Preparation of Carboxylic Acid Halides, Reactions of Carboxylic Acid Halides; Carboxylic Acid Anhydrides, Preparation of Carboxylic Acid Anhydrides, Reactions of Carboxylic Acid Anhydrides; Carboxylic Acid Esters, Preparation of Carboxylic Acid esters, Reactions of Carboxylic Acid esters, Reformatsky Reaction; Amides, Preparation of Amides, Reactions of Amides. 

UNIT : 11 - Amines 

Structure and Reactivity of Amines; Physical Properties of Amines; Preparation of Amines; from Alkyl Halides, from Gabriel’s Phthalimide Synthesis, from Hofmann Bromamide Degradation; Reactions of Amines, Hofmann elimination, Schotten-Baumann Reaction; Reaction of aliphatic amine with HNO2; Electrophilic Substitution (of Aniline), Nitration, Bromination, Sulphonation; Laboratory Detection of Amines, Carbylamine Test, Hinsberg Test. 

UNIT : 12 - Diazonium Salts 

Preparation from Aromatic Amines; Reactions of Diazonium Salts, Conversion to, Benzene, Phenol, Sandmeyer Reaction, Dyes. 

UNIT : 13 - Amino Acids and Peptides 

Structure and Physical Properties Amino Acids, Zwitter Ion, Isoelectric Point and Electrophoresis (+optical activity in brief): Synthesis of 2-Amino Acids: Gabriel’s Phthalimide Synthesis, Strecker Synthesis; Structure of Peptides; Synthesis of Peptides, Synthesis by N-protection, t-Butyloxycarbonyl (Boc) Group, Phthaloyl Group, Synthesis by C-Activating Groups; Merrifield Solid-Phase Synthesis; Lab Detection of Amino Acids, Complexation with Cu2+, Ninhydrin Test. 

UNIT : 14 - Structure of Peptides and Proteins 

Overview of Primary, Secondary, Tertiary and Quaternary Structures of Proteins; Determination of Primary Structure of Peptides and Proteins, Partial Hydrolysis, End Group Analysis, N-terminal Identification by, Degradation (i) Sanger Method (ii) Edman degradation, C-terminal Identification (with Carboxypeptidase Enzyme). 

UNIT : 15 - Carbohydrates-I 

Monosaccharides: Classification of Carbohydrates; General Properties; Structure of Glucose and Fructose; Configuration of Monosaccharides, Absolute Configuration of Glucose and Fructose, Mutarotation; Ascending and Descending of Chains in Monosaccharides. 

UNIT : 16 - Carbohydrates-I I

Disaccharrides and Polysaccharrides: Structure of Disaccharrides, Sucrose, Cellobiose, Maltose, Lactose; Structure of Polysaccharrides, Starch, Cellulose, (Excluding their Structure Elucidation). 

Ignou BSCG Program Course BCHCT 135 

Full Details About Course

Mr. Monu Kumar